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Material Name: calcite
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Description
The most common crystalline form of calcium carbonate. Calcite is widely distributed throughout the world as chalk, limestone, and marble. Major deposits were formed from ancient sea beds and hard water deposits (e.g., stalactites). Iceland is famous for producing large clear birefractive calcite crystals that are used in optical systems (Iceland spar). In addition to clear colorless crystals, calcite may also appear white or pale shades of other colors depending on the crystal size and the presence of impurities. Marble is limestone that has been metamorphosed to form compact crystals of calcite. Calcite has been gathered or mined since Paleolithic times. In the form of chalk, calcite was powdered for use as a pigment and as an ingredient in the manufacture of steel, cement, and glass. Limestone and marble are used for sculpture and buildings.

Synonyms and Related Terms
calcium carbonate; marble; limestone; Iceland spar; dogtooth spar; dog-tooth spar; nailhead spar; satin spar; calcareous spar; calc spar; calcspar; calcite (It., Fr., Port.); Kalzit, Calcit (Deut.); calcita (Esp.); calciet (Ned.); calcium salt of carbonic acid; Pigment White 18; CI 7720

CompositionCaCO3
CAS471-34-1
Mohs Hardness3.0
Molecular Weightmol. wt. = 100.09
Density2.71-2.72
Refractive Index1.486; 1.658; (1.566)

Other Properties
Rhombohedral crystal system. Perfect cleavage in three directions. Fracture = conchoidal. High birefringence. Can doubly refract light. Aged surfaces of calcite may fluorescs purple or blue in ultraviolet light; freshly cleaved surfaces are white to yellow. Reacts with acids to evolve carbon dioxide. Luster = vitreous. Streak = white.

Hazards and Safety
International Chemical Safety Card

Additional Information
° R. Gettens, E. West Fitzhugh, R.Feller, "Calcium Carbonate Whites", Artists Pigments, Vol. 2., A. Roy ed. Oxford University Press, Oxford, 1993.
° Mineralogy Database: Calcite

Last updated on: 7/5/2009 10:16:58 AM


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Calcite



Calcite



Plane polarized light micrograph of calcite



IR spectrum of calcite (Egyptian limestone)


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