Difference between revisions of "Cuprammonium hydroxide"

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== Description ==
 
== Description ==
  
Copper dissolved in concentrated ammonia resulting in the formation of a copper ammonia complex copper.   
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Copper hydroxide dissolved in concentrated ammonia results in the formation of a copper ammonia complex copper.  Discovered in 1857 by E. Schweizer, the dark blue solution is capable of dissolving cellulose. cotton, silk and linen.  It has been used as a reagent test solution for wool, since wool does not dissolve.  But more commonly, the reagent is used to dissolve cellulose. When a solution of cellulose in cuprammonium hydroxide is diluted with water or treated with dilute sulphuric acid, the cellulose is regenerated or reprecipitated. By using a spinnerette, filaments of this regenerated cellulose can be produced. See [[cuprammonium rayon]].
Since the earliest (1857) as the Germans found E. Schweizer, also said Schweitzer reagent (Schweizer's reagent). The solvent dark blue solution, the Department of Qingyanghuatong dissolved in concentrated ammonia rather the system, it is generally recognized that following the formation of ammonia complex copper Cu (OH) 2 +4 NH3Cu (NH3) 4 (OH) 2 above ammonia production of copper complexes, the price is two alkali; while pressing for-dissociation ammonia complexes, the price is two alkali; while pressing for dissociation-Cu (NH3) 4 (OH) 2Cu (NH< SUB>3) 42 +2 + OH-. Ammonia copper complexes have excess ammonia in the presence of very stable, but not isolated; When the ammonia concentration is lowered, mainly [Cu (NH3) 4 (OH) k2] exist; the appropriate solution increases the concentration of ammonia, which can be increased solvent dissolved cellulose capacity. The use of cellulose solvent dissolved by the textile fibers, called ammonium copper fiber.
 
  
 
== Synonyms and Related Terms ==
 
== Synonyms and Related Terms ==
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* NIH: [https://pubchem.ncbi.nlm.nih.gov/compound/Cuprammonium-hydroxide-solution Compound information]
 
* NIH: [https://pubchem.ncbi.nlm.nih.gov/compound/Cuprammonium-hydroxide-solution Compound information]
  
==Physical and Chemical Properties==
 
 
==Resources and Citations==
 
==Resources and Citations==
 
* Textile Library: [http://textilelibrary.weebly.com/cuprammonium-rayon-mfg-process.html#:~:text=Cuprammonium%20hydroxide%20solution%20is%20a%20solvent%20for%20cellulose.,filaments%20of%20this%20regenerated%20cellulose%20can%20be%20produced. Cuprammonium rayon]
 
* Textile Library: [http://textilelibrary.weebly.com/cuprammonium-rayon-mfg-process.html#:~:text=Cuprammonium%20hydroxide%20solution%20is%20a%20solvent%20for%20cellulose.,filaments%20of%20this%20regenerated%20cellulose%20can%20be%20produced. Cuprammonium rayon]
  
 
[[Category:Materials database]]
 
[[Category:Materials database]]

Revision as of 12:06, 14 July 2022

Description

Copper hydroxide dissolved in concentrated ammonia results in the formation of a copper ammonia complex copper. Discovered in 1857 by E. Schweizer, the dark blue solution is capable of dissolving cellulose. cotton, silk and linen. It has been used as a reagent test solution for wool, since wool does not dissolve. But more commonly, the reagent is used to dissolve cellulose. When a solution of cellulose in cuprammonium hydroxide is diluted with water or treated with dilute sulphuric acid, the cellulose is regenerated or reprecipitated. By using a spinnerette, filaments of this regenerated cellulose can be produced. See Cuprammonium rayon.

Synonyms and Related Terms

cupram; cuam; Schweitzer reagent; Schweizer's reagent

Risks

Resources and Citations

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