Difference between revisions of "Calcium acetate"

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== Description ==
 
== Description ==
  
A white powder prepared by treating [http://cameo.mfa.org/materials/fullrecord.asp?name=acetic acid acetic acid] with [http://cameo.mfa.org/materials/fullrecord.asp?name=calcium carbonate calcium carbonate] or [http://cameo.mfa.org/materials/fullrecord.asp?name=lime lime]. Calcium acetate is a water-soluble compound that has been used for aqueous and nonaqueous neutralization and alkalization of paper (AIC Book and Paper Catalog). However, during the neutralization process, calcium acetate is converted to calcium carbonate with the release of acetic acid. Any residual calcium acetate will continue to release acetic acid. Calcium acetate has also been used to reintroduce calcium ions into weathered glass (Corvaia, et. al 1996). Calcium acetate is used commercially as a mordant in dyeing and printing textiles, for liming rosin, for curing and tanning skins, and as a metallic soap.
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A white powder prepared by treating [[acetic acid]] with [[calcium carbonate]] or [[lime]]. Calcium acetate is a water-soluble compound that has been used for aqueous and nonaqueous neutralization and alkalization of paper (AIC Book and Paper Catalog). However, during the neutralization process, calcium acetate is converted to calcium carbonate with the release of acetic acid. Any residual calcium acetate will continue to release acetic acid. Calcium acetate has also been used to reintroduce calcium ions into weathered glass (Corvaia, et. al 1996). Calcium acetate is used commercially as a mordant in dyeing and printing textiles, for liming rosin, for curing and tanning skins, and as a metallic soap.
 
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[[[SliderGallery rightalign|calcium acetate.jpg~Chemical structure]]]
 
== Synonyms and Related Terms ==
 
== Synonyms and Related Terms ==
  
 
calcium diacetate; lime acetate; acetate of lime; vinegar salts; gray acetate; brown acetate
 
calcium diacetate; lime acetate; acetate of lime; vinegar salts; gray acetate; brown acetate
  
[[[SliderGallery rightalign|calcium acetate.jpg~Chemical structure]]]
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== Risks ==
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* Combustible. 
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* ThermoFisher: [https://www.fishersci.com/store/msds?partNumber=AC211052500&productDescription=CALCIUM+ACETATE+HYDRATE%2C+250GR&vendorId=VN00032119&countryCode=US&language=en SDS]
  
== Other Properties ==
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==Physical and Chemical Properties==
  
Rod-shaped crystals. Soluble in water (pH = 7.6 for 0.2M solution).  Slightly soluble in methanol. Insoluble in ethanol, acetone, benzene.
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* Rod-shaped crystals.  
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* Soluble in water (pH = 7.6 for 0.2M solution).   
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* Slightly soluble in methanol. Insoluble in ethanol, acetone, benzene.
  
 
{| class="wikitable"
 
{| class="wikitable"
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|-
 
|-
 
! scope="row"| Melting Point
 
! scope="row"| Melting Point
| > 160
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| > 160 C
 
|-
 
|-
 
! scope="row"| Density
 
! scope="row"| Density
| about 1.5
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| about 1.5 g/ml
 
|-
 
|-
 
! scope="row"| Molecular Weight
 
! scope="row"| Molecular Weight
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|}
 
|}
  
== Hazards and Safety ==
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==Resources and Citations==
 
 
Combustible. 
 
 
 
Mallinckrodt Baker: [http://www.jtbaker.com/msds/englishhtml/c0266.htm MSDS]
 
 
 
== Additional Information ==
 
 
 
C.Corvaia, I.MacLeod, C.Harley "Conservation of Glass Recovered from Shipwreck Sites" ICOM preprints, 1996 Edinburgh, vol.II p.819-825.
 
  
== Authority ==
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* C.Corvaia, I.MacLeod, C.Harley "Conservation of Glass Recovered from Shipwreck Sites" ICOM preprints, 1996 Edinburgh, vol.II p.819-825.
  
* Thomas Gregory, Thomas Gregory, ''The Condensed Chemical Dictionary'', Reinhold Publishing, New York, 3rd ed., 1942
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* Thomas Gregory, ''The Condensed Chemical Dictionary'', Reinhold Publishing, New York, 3rd ed., 1942
  
* G.S.Brady, G.S.Brady, ''Materials Handbook'', McGraw-Hill Book Co., New York, 1971  Comment: p. 133
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* G.S.Brady, ''Materials Handbook'', McGraw-Hill Book Co., New York, 1971  Comment: p. 133
  
 
* ''The Merck Index'', Martha Windholz (ed.), Merck Research Labs, Rahway NJ, 10th edition, 1983  Comment: entry 1683
 
* ''The Merck Index'', Martha Windholz (ed.), Merck Research Labs, Rahway NJ, 10th edition, 1983  Comment: entry 1683
  
* Matt Roberts, Don Etherington, Matt Roberts, Don Etherington, ''Bookbinding and the Conservation of Books: a Dictionary of Descriptive Terminology'', U.S. Government Printing Office, Washington DC, 1982
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* Matt Roberts, Don Etherington, ''Bookbinding and the Conservation of Books: a Dictionary of Descriptive Terminology'', U.S. Government Printing Office, Washington DC, 1982
  
* Book and Paper Group, Book and Paper Group, ''Paper Conservation Catalog'', AIC, 1984, 1989
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* Book and Paper Group, ''Paper Conservation Catalog'', AIC, 1984, 1989
  
  
  
 
[[Category:Materials database]]
 
[[Category:Materials database]]

Latest revision as of 15:31, 11 May 2022

Description

A white powder prepared by treating Acetic acid with Calcium carbonate or Lime. Calcium acetate is a water-soluble compound that has been used for aqueous and nonaqueous neutralization and alkalization of paper (AIC Book and Paper Catalog). However, during the neutralization process, calcium acetate is converted to calcium carbonate with the release of acetic acid. Any residual calcium acetate will continue to release acetic acid. Calcium acetate has also been used to reintroduce calcium ions into weathered glass (Corvaia, et. al 1996). Calcium acetate is used commercially as a mordant in dyeing and printing textiles, for liming rosin, for curing and tanning skins, and as a metallic soap.

Chemical structure

Calcium acetate.jpg

Synonyms and Related Terms

calcium diacetate; lime acetate; acetate of lime; vinegar salts; gray acetate; brown acetate

Risks

  • Combustible.
  • ThermoFisher: SDS

Physical and Chemical Properties

  • Rod-shaped crystals.
  • Soluble in water (pH = 7.6 for 0.2M solution).
  • Slightly soluble in methanol. Insoluble in ethanol, acetone, benzene.
Composition C4H6CaO4
CAS 62-54-4
Melting Point > 160 C
Density about 1.5 g/ml
Molecular Weight mol. wt. = 158.17

Resources and Citations

  • C.Corvaia, I.MacLeod, C.Harley "Conservation of Glass Recovered from Shipwreck Sites" ICOM preprints, 1996 Edinburgh, vol.II p.819-825.
  • Thomas Gregory, The Condensed Chemical Dictionary, Reinhold Publishing, New York, 3rd ed., 1942
  • G.S.Brady, Materials Handbook, McGraw-Hill Book Co., New York, 1971 Comment: p. 133
  • The Merck Index, Martha Windholz (ed.), Merck Research Labs, Rahway NJ, 10th edition, 1983 Comment: entry 1683
  • Matt Roberts, Don Etherington, Bookbinding and the Conservation of Books: a Dictionary of Descriptive Terminology, U.S. Government Printing Office, Washington DC, 1982
  • Book and Paper Group, Paper Conservation Catalog, AIC, 1984, 1989