Difference between revisions of "Cobalt yellow"

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== Synonyms and Related Terms ==
 
== Synonyms and Related Terms ==
  
potassium cobaltinitrite; Pigment Yellow 40; CI 77357; aureolin; Kobaltgelb (Deut.); jaune de cobalt (Fr.); auroline (Fr.); giallo di cobalto (It.); amarillo de cobalto (Esp.); aureolina (Esp.); Aureolin (Deut.); Primulin (Deut.); kitrino toy kobaltioy (Gr.); giallo di cobalto (aureolina) (It.); aureoline (Ned.); amarelo de cobalto (Port.); potassium hexanitrocobaltate; cobalt potassium nitrite; cobaltic potassium nitrite; Fischer's yellow;
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potassium cobaltinitrite; Pigment Yellow 40; CI 77357; aureolin; Kobaltgelb (Deut.); jaune de cobalt (Fr.); auréoline (Fr.); giallo di cobalto (It.); amarillo de cobalto (Esp.); aureolina (Esp.); Aureolin (Deut.); Primulin (Deut.); kitrino toy kobaltioy (Gr.); giallo di cobalto (aureolina) (It.); aureoline (Ned.); amarelo de cobalto (Port.); potassium hexanitrocobaltate; cobalt potassium nitrite; cobaltic potassium nitrite; Fischer's yellow;
  
 
[[[SliderGallery rightalign|CobaltylUCL.jpg~Raman|AureolinRoberson.jpg~FTIR|AureolinRoberson.jpg~FTIR|PIG342.jpg~XRD|f342sem.jpg~SEM|f342edsbw.jpg~EDS]]]
 
[[[SliderGallery rightalign|CobaltylUCL.jpg~Raman|AureolinRoberson.jpg~FTIR|AureolinRoberson.jpg~FTIR|PIG342.jpg~XRD|f342sem.jpg~SEM|f342edsbw.jpg~EDS]]]
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== Additional Information ==
 
== Additional Information ==
  
M.Cornman, "Cobalt Yellow", ''Artists Pigments'', Volume 1, R. Feller (ed.), Cambridge University Press; Cambridge, 1986. Pigments Through the Ages: [http://webexhibits.org/pigments/indiv/overview/coyellow.html Cobalt yellow]
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° M.Cornman, "Cobalt Yellow", ''Artists Pigments'', Volume 1, R. Feller (ed.), Cambridge University Press; Cambridge, 1986. ° Pigments Through the Ages: [http://webexhibits.org/pigments/indiv/overview/coyellow.html Cobalt yellow]
  
 
== Additional Images ==
 
== Additional Images ==
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== Authority ==
 
== Authority ==
  
* Ralph Mayer, Ralph Mayer, ''A Dictionary of Art Terms and Techniques'', Harper and Row Publishers, New York, 1969 (also 1945 printing)  Comment: introduced as a paint pigment by Saint-Evre in Paris 1852
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* Ralph Mayer, ''A Dictionary of Art Terms and Techniques'', Harper and Row Publishers, New York, 1969 (also 1945 printing)  Comment: introduced as a paint pigment by Saint-Evre in Paris 1852
  
 
* ''The Dictionary of Art'', Grove's Dictionaries Inc., New York, 1996  Comment: "Pigments"
 
* ''The Dictionary of Art'', Grove's Dictionaries Inc., New York, 1996  Comment: "Pigments"
  
* R. J. Gettens, G.L. Stout, R. J. Gettens, G.L. Stout, ''Painting Materials, A Short Encyclopaedia'', Dover Publications, New York, 1966  Comment: Introduced as artists pigment in 1861 by Winsor & Newton; ref. index = 1.72-1.76
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* R. J. Gettens, G.L. Stout, ''Painting Materials, A Short Encyclopaedia'', Dover Publications, New York, 1966  Comment: Introduced as artists pigment in 1861 by Winsor & Newton; ref. index = 1.72-1.76
  
* Susan E. Schur, Susan E. Schur, Conservation Terminology: A review of Past & Current Nomenclature of Materials, ''Technology and Conservation'', Spring (p.34-39); Summer (p.35-38); Fall (p.25-36), 1985  Comment: appeared commercially in the 1860s
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* Susan E. Schur, Conservation Terminology: A review of Past & Current Nomenclature of Materials, ''Technology and Conservation'', Spring (p.34-39); Summer (p.35-38); Fall (p.25-36), 1985  Comment: appeared commercially in the 1860s
  
* Website address 1, Website address 1  Comment: Pigments through the Ages:  http://webexhibits.org/pigments/indiv/overview/coyellow.html  - gives chemical name as Cobalt(II) aluminum nitrite  - states unchanged in acids but will turn black in sodium sulfide and brown in caustic soda
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* Website address 1  Comment: Pigments through the Ages:  http://webexhibits.org/pigments/indiv/overview/coyellow.html  - gives chemical name as Cobalt(II) aluminum nitrite  - states unchanged in acids but will turn black in sodium sulfide and brown in caustic soda
  
* Reed Kay, Reed Kay, ''The Painter's Guide To Studio Methods and Materials'', Prentice-Hall, Inc., Englewood Cliffs, NJ, 1983
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* Reed Kay, ''The Painter's Guide To Studio Methods and Materials'', Prentice-Hall, Inc., Englewood Cliffs, NJ, 1983
  
* Richard S. Lewis, Richard S. Lewis, ''Hawley's Condensed Chemical Dictionary'', Van Nostrand Reinhold, New York, 10th ed., 1993
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* Richard S. Lewis, ''Hawley's Condensed Chemical Dictionary'', Van Nostrand Reinhold, New York, 10th ed., 1993
  
 
* ''The Merck Index'', Martha Windholz (ed.), Merck Research Labs, Rahway NJ, 10th edition, 1983  Comment: entry 2493
 
* ''The Merck Index'', Martha Windholz (ed.), Merck Research Labs, Rahway NJ, 10th edition, 1983  Comment: entry 2493
  
* Michael McCann, Michael McCann, ''Artist Beware'', Watson-Guptill Publications, New York City, 1979
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* Michael McCann, ''Artist Beware'', Watson-Guptill Publications, New York City, 1979
  
* Book and Paper Group, Book and Paper Group, ''Paper Conservation Catalog'', AIC, 1984, 1989
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* Book and Paper Group, ''Paper Conservation Catalog'', AIC, 1984, 1989
  
* Random House, Random House, ''Webster's Encyclopedic Unabridged Dictionary of the English Language'', Grammercy Book, New York, 1997
+
* Random House, ''Webster's Encyclopedic Unabridged Dictionary of the English Language'', Grammercy Book, New York, 1997
  
  
  
 
[[Category:Materials database]]
 
[[Category:Materials database]]

Revision as of 07:43, 24 July 2013

Aureolin

Description

A brilliant, transparent yellow pigment commonly known by the name aureolin. Cobalt yellow is composed of potassium cobaltinitrite. It was discovered by N.W. Fischer in Germany in 1848. Cobalt yellow was introduced as an artists' pigment in 1852 (Saint-Evre) and began selling commercially in the U.S. in 1861. Aureolin is a permanent pigment, but may discolor to brown when mixed with indigo in the presence of hydrogen sulfide. Because of its poor hiding power, cobalt yellow is most often used in watercolor and tempera paints, for oil-based glazes and as a colorant in glass.

Synonyms and Related Terms

potassium cobaltinitrite; Pigment Yellow 40; CI 77357; aureolin; Kobaltgelb (Deut.); jaune de cobalt (Fr.); auréoline (Fr.); giallo di cobalto (It.); amarillo de cobalto (Esp.); aureolina (Esp.); Aureolin (Deut.); Primulin (Deut.); kitrino toy kobaltioy (Gr.); giallo di cobalto (aureolina) (It.); aureoline (Ned.); amarelo de cobalto (Port.); potassium hexanitrocobaltate; cobalt potassium nitrite; cobaltic potassium nitrite; Fischer's yellow;

Raman

CobaltylUCL.jpg

FTIR

AureolinRoberson.jpg

FTIR

AureolinRoberson.jpg

XRD

PIG342.jpg

SEM

F342sem.jpg

EDS

F342edsbw.jpg


Other Properties

Slightly soluble in water. Insoluble in ethanol, ether and carbon disulfide. Soluble in acids producing a pink solution. Decomposes in alkalis evolving nitrogen oxide fumes.

Fine, dendritic crystals. Yellow in transmitted light. Isotropic in polarized light.

Composition K3[Co(NO2)6].3H2O
CAS 13782-01-9
Density 1.8
Molecular Weight mol. wt. = 452.26
Refractive Index 1.72 - 1.76

Hazards and Safety

Ingestion may cause poisoning with decreased blood pressure, headaches, nausea, vomiting and cyanosis.

Additional Information

° M.Cornman, "Cobalt Yellow", Artists Pigments, Volume 1, R. Feller (ed.), Cambridge University Press; Cambridge, 1986. ° Pigments Through the Ages: Cobalt yellow

Additional Images


Authority

  • Ralph Mayer, A Dictionary of Art Terms and Techniques, Harper and Row Publishers, New York, 1969 (also 1945 printing) Comment: introduced as a paint pigment by Saint-Evre in Paris 1852
  • The Dictionary of Art, Grove's Dictionaries Inc., New York, 1996 Comment: "Pigments"
  • R. J. Gettens, G.L. Stout, Painting Materials, A Short Encyclopaedia, Dover Publications, New York, 1966 Comment: Introduced as artists pigment in 1861 by Winsor & Newton; ref. index = 1.72-1.76
  • Susan E. Schur, Conservation Terminology: A review of Past & Current Nomenclature of Materials, Technology and Conservation, Spring (p.34-39); Summer (p.35-38); Fall (p.25-36), 1985 Comment: appeared commercially in the 1860s
  • Reed Kay, The Painter's Guide To Studio Methods and Materials, Prentice-Hall, Inc., Englewood Cliffs, NJ, 1983
  • Richard S. Lewis, Hawley's Condensed Chemical Dictionary, Van Nostrand Reinhold, New York, 10th ed., 1993
  • The Merck Index, Martha Windholz (ed.), Merck Research Labs, Rahway NJ, 10th edition, 1983 Comment: entry 2493
  • Michael McCann, Artist Beware, Watson-Guptill Publications, New York City, 1979
  • Book and Paper Group, Paper Conservation Catalog, AIC, 1984, 1989
  • Random House, Webster's Encyclopedic Unabridged Dictionary of the English Language, Grammercy Book, New York, 1997

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