Difference between revisions of "Copper resinate"

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== Description ==
 
== Description ==
  
The common name for a transparent green glaze containing copper salts of resin acids. Examples of copper resinate layers have been seen on manuscripts dating to the 8th century but it was most commonly used in 15th - 17th c. paintings. Several recipes for copper resinate indicate it is a mixture of [[verdigris]] in [[Venice turpentine]] while others describe it as a mixture of verdigris in an oil/resin medium. Current preparation techniques melt natural resins then mix in reactive copper salts such as [[copper acetate]], [[copper hydroxide]], [[copper oxide]], or [[copper carbonate]] (Kuhn 1993).
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The common name for a transparent green glaze containing copper salts of resin acids. Examples of copper resinate layers have been seen on manuscripts dating to the 8th century but it was most commonly used in 15th - 17th c. paintings. Several recipes for copper resinate indicate it is a mixture of [[verdigris]] in [[Venice turpentine]] while others describe it as a mixture of verdigris in an oil/resin medium. Current preparation techniques melt natural resins then mix in reactive copper salts such as [[copper acetate]], [[copper hydroxide]], [[Copper oxide red|copper oxide]], or [[basic copper carbonate]] (Kuhn 1993).
  
 
== Synonyms and Related Terms ==
 
== Synonyms and Related Terms ==
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cupric resinate; transparent copper green; Kupferresinat (Deut.); résinate de cuivre (Fr.); resinato de cobre (Esp., Port.); resinato di rame (It.)
 
cupric resinate; transparent copper green; Kupferresinat (Deut.); résinate de cuivre (Fr.); resinato de cobre (Esp., Port.); resinato di rame (It.)
  
[[[SliderGallery rightalign|Copper Resinate.PNG~FTIR|MFA- Copper resinate.jpg~FTIR]]]
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[[[SliderGallery rightalign|Copper Resinate.PNG~FTIR (MFA)|Copper Resinate, sample 2.PNG~FTIR (MFA)]]]
  
== Other Properties ==
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== Risks ==
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* Combustible. 
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* Decomposes with heat. 
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* Turns brown with exposure to short-wave ultraviolet light.
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==Physical and Chemical Properties==
  
 
Soluble in ether, oils, and many organic solvents (benzene, chloroform, mineral spirits, etc.). Insoluble in water.   
 
Soluble in ether, oils, and many organic solvents (benzene, chloroform, mineral spirits, etc.). Insoluble in water.   
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== Hazards and Safety ==
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==Resources and Citations==
 
 
Combustible.  Decomposes with heat. 
 
 
 
Turns brown with exposure to short-wave ultraviolet light.
 
  
== Additional Information ==
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* H. Kuhn, "Verdigris and Copper Resinate", in ''Artists Pigments'', Volume 2, A. Roy (ed.), Oxford University Press: Oxford, 1993.
  
° H. Kuhn, "Verdigris and Copper Resinate", in ''Artists Pigments'', Volume 2, A. Roy (ed.), Oxford University Press: Oxford, 1993. ° Pigments Through the Ages: [http://www.webexhibits.org/pigments/indiv/overview/curesinate.html| Copper Resinate]
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* Pigments Through the Ages: [http://www.webexhibits.org/pigments/indiv/overview/curesinate.html| Copper Resinate]
 
 
== Authority ==
 
  
 
* R. J. Gettens, G.L. Stout, ''Painting Materials, A Short Encyclopaedia'', Dover Publications, New York, 1966  Comment: p. 110
 
* R. J. Gettens, G.L. Stout, ''Painting Materials, A Short Encyclopaedia'', Dover Publications, New York, 1966  Comment: p. 110
  
 
* Ralph Mayer, ''A Dictionary of Art Terms and Techniques'', Harper and Row Publishers, New York, 1969 (also 1945 printing)
 
* Ralph Mayer, ''A Dictionary of Art Terms and Techniques'', Harper and Row Publishers, New York, 1969 (also 1945 printing)
 
* Website address 1  Comment: Pigments Through the Ages: http://webexhibits.org/pigments/indiv/overview/curesinate.html
 
  
 
* R. Newman, E. Farrell, 'House Paint Pigments', ''Paint in America '', R. Moss ed., Preservation Press, New York City, 1994
 
* R. Newman, E. Farrell, 'House Paint Pigments', ''Paint in America '', R. Moss ed., Preservation Press, New York City, 1994
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* Richard C. Wolbers, Nanette T. Sterman, Chris Stavroudis, ''Notes for Workshop on New Methods in the Cleaning of Paintings'', J.Paul Getty Trust, Los Angeles, 1990
 
* Richard C. Wolbers, Nanette T. Sterman, Chris Stavroudis, ''Notes for Workshop on New Methods in the Cleaning of Paintings'', J.Paul Getty Trust, Los Angeles, 1990
  
* Art and Architecture Thesaurus Online, http://www.getty.edu/research/tools/vocabulary/aat/, J. Paul Getty Trust, Los Angeles, 2000
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* Art and Architecture Thesaurus Online, https://www.getty.edu/research/tools/vocabulary/aat/, J. Paul Getty Trust, Los Angeles, 2000
  
  
  
 
[[Category:Materials database]]
 
[[Category:Materials database]]

Latest revision as of 15:16, 4 July 2022

Description

The common name for a transparent green glaze containing copper salts of resin acids. Examples of copper resinate layers have been seen on manuscripts dating to the 8th century but it was most commonly used in 15th - 17th c. paintings. Several recipes for copper resinate indicate it is a mixture of Verdigris in Venice turpentine while others describe it as a mixture of verdigris in an oil/resin medium. Current preparation techniques melt natural resins then mix in reactive copper salts such as Copper acetate, Copper hydroxide, copper oxide, or Basic copper carbonate (Kuhn 1993).

Synonyms and Related Terms

cupric resinate; transparent copper green; Kupferresinat (Deut.); résinate de cuivre (Fr.); resinato de cobre (Esp., Port.); resinato di rame (It.)

FTIR (MFA)

Copper Resinate.PNG

FTIR (MFA)

Copper Resinate, sample 2.PNG


Risks

  • Combustible.
  • Decomposes with heat.
  • Turns brown with exposure to short-wave ultraviolet light.

Physical and Chemical Properties

Soluble in ether, oils, and many organic solvents (benzene, chloroform, mineral spirits, etc.). Insoluble in water.

Appears microscopically as irregular, green fragments.

Refractive Index 1.52

Resources and Citations

  • H. Kuhn, "Verdigris and Copper Resinate", in Artists Pigments, Volume 2, A. Roy (ed.), Oxford University Press: Oxford, 1993.
  • R. J. Gettens, G.L. Stout, Painting Materials, A Short Encyclopaedia, Dover Publications, New York, 1966 Comment: p. 110
  • Ralph Mayer, A Dictionary of Art Terms and Techniques, Harper and Row Publishers, New York, 1969 (also 1945 printing)
  • R. Newman, E. Farrell, 'House Paint Pigments', Paint in America , R. Moss ed., Preservation Press, New York City, 1994
  • The Dictionary of Art, Grove's Dictionaries Inc., New York, 1996 Comment: "Pigments"
  • Richard S. Lewis, Hawley's Condensed Chemical Dictionary, Van Nostrand Reinhold, New York, 10th ed., 1993
  • Richard C. Wolbers, Nanette T. Sterman, Chris Stavroudis, Notes for Workshop on New Methods in the Cleaning of Paintings, J.Paul Getty Trust, Los Angeles, 1990