Dammar

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Dammar on canvas (visible light left; UV light right)

Description

A clear, pale yellow natural resin derived from Dipterocarpaceae trees growing in southeast Asia. The principal trees that supply dammar resin are of the genera Shorea, Balanocarpus, or Hopea. Dammar is a triterpenoid resin that primarily contains dammarolic acid (C54H77O3(COOH)2). The soft, viscous, highly aromatic resin oozes readily from incisions in the bark and dries to become transparent, brittle, odorless lumps that are sorted into three grades: A (superior), B (small amount of impurities), and C (many impurities). To prepared as a varnish, dammar pieces are placed in a Cheesecloth bag partially submersed in turpentine. After a few hours, the dammar is dissolved and any residual material remaining in the bag is thrown out. This forms a high-quality, clear varnish for paintings. However, the presence of water during application may cause it to dry with a whitish bloom. Dammar was first introduced as a picture varnish in 1826 and by the end of the 19th century, its use surpassed mastic. It is also used in printing inks, cellulosic lacquers, alkyd baking enamels, and coatings for papers and textiles. Dammar solutions in Chloroform or Xylenes have been used for mounting thin sections for microscopic examination.

FTIR(MFA)

Dewaxed Damar No. 32 Mixture, Gettens 100.A42.TIF

Synonyms and Related Terms

dammar (AAT, Esp., Fr., It.); damar (JAIC style guide); dammer; dammar gum; Malay dammar; Mata Kuching; cat's eye; Penak; gum Batu; Kalulut; Siput; Daging; Saraya; Kepong; Bata gum; Singapore dammar; Batavia dammar; Padang; Dipterocarpaceae

Risks

  • Low toxicity rating although dust inhalation may cause allergies.
  • Darkens with age.
  • Turns cloudy when moisture is present during preparation.

Physical and Chemical Properties

  • Soluble in turpentine, oil, chloroform and aromatic hydrocarbons.
  • Slightly soluble in ethanol. Insoluble in water or mineral spirits.
  • Acid number = 16 -18;
  • Saponification number = 20-65.
Melting Point 90 (softens); 100-180 (melts)
Density 1.04-1.12 g/ml
Molecular Weight Tg =39.3 C
Refractive Index 1.515 -1.539

Comparisons

Properties of Natural Resins

Resources and Citations

  • J.S. Mills, R.White, The Organic Chemistry of Museum Objects, Butterworth Heinemann, London, 1994.
  • L.Merz-Le, "Natural Resin Varnishes: Damar" AIC Painting Conservation Catalog, Varnishes and Surface Coatings, p.63, 1998.
  • R. J. Gettens, G.L. Stout, Painting Materials, A Short Encyclopaedia, Dover Publications, New York, 1966 Comment: dammar; melting point = 100-150C; specific gravity = 1.062
  • G.S.Brady, Materials Handbook, McGraw-Hill Book Co., New York, 1971 Comment: dammar
  • Reed Kay, The Painter's Guide To Studio Methods and Materials, Prentice-Hall, Inc., Englewood Cliffs, NJ, 1983
  • Ralph Mayer, A Dictionary of Art Terms and Techniques, Harper and Row Publishers, New York, 1969 (also 1945 printing) Comment: damar
  • Richard S. Lewis, Hawley's Condensed Chemical Dictionary, Van Nostrand Reinhold, New York, 10th ed., 1993 Comment: dammar
  • Hermann Kuhn, Conservation and Restoration of Works of Art and Antiquities, Butterworths, London, 1986 Comment: softens at 90C, melting point at 180C
  • Michael McCann, Artist Beware, Watson-Guptill Publications, New York City, 1979 Comment: damar
  • C.V.Horie, Materials for Conservation, Butterworth-Heineman, London, 1997
  • Matt Roberts, Don Etherington, Bookbinding and the Conservation of Books: a Dictionary of Descriptive Terminology, U.S. Government Printing Office, Washington DC, 1982 Comment: dammar
  • Polymer Handbook, Sealants and Adhesives
  • John S. Mills, Raymond White, The Organic Chemistry of Museum Objects, Butterworth Heineman, London, 2nd ed., 1994
  • The Merck Index, Martha Windholz (ed.), Merck Research Labs, Rahway NJ, 10th edition, 1983 Comment: entry #2872 - damar
  • The American Heritage Dictionary or Encarta, via Microsoft Bookshelf 98, Microsoft Corp., 1998 Comment: dammar
  • Thomas B. Brill, Light Its Interaction with Art and Antiquities, Plenum Press, New York City, 1980
  • Paintings Specialty Group, Painting Conservation Catalog, Wendy Samet (ed.), AIC, Washington, DC, 1998