Litharge

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Litharge

Description

A heavy yellow powder composed of lead monoxide. Litharge is prepared as the oxidized product of molten lead that has been stirred or atomized to incorporate air then cooled and ground to form the yellow powder. Massicot, another crystalline form of lead monoxide, occurs naturally but can also be made by heating lead carbonate to 300C. Litharge is lightly more orange than massicot due to some formation of red lead oxide. Both forms of lead monoxide has been used as a drier in oil and as a low-fire flux in making ceramics and glass. They were used as a yellow pigments in paints and glazes. Thin layers of lead monoxide are used to produce iridescent colors on brass and bronze. It has also been used as a filler for rubber and to produce artificial tortoiseshell and horn. Litharge is mixed with glycerol to make plumber's cement.

litharge

Synonyms and Related Terms

massicot; lead monoxide; lithargyros (Gr.); plumbum ustum (Latin); Lithargit (Deut.); Massicot (Deut.); litharge (Fr.); litargirio (Esp.); litargirio (giallo di piombo) (It.); massicot (Ned.); litharge (Ned.); litargírio (Port.); yellow lead oxide; plumbous oxide

Raman

LithargeUCL.jpg

FTIR

MFA- Litharge with lead carbonate.jpg

XRD

PIG284.jpg

SEM

F284sem.jpg

EDS

F284edsbw.jpg

XRF

Slide30 FC284.PNG


Other Properties

Soluble in acetic acid, dilute nitric acid and alkalis. Insoluble in water and ethanol. Turns gray on exposure to sulfur fumes.

Composition PbO
CAS 1317-36-8
Melting Point 888
Density 9.40-9.53
Refractive Index 2.51; 2.71; 2.61

Hazards and Safety

Toxic by inhalation or ingestion. Skin contact may cause irritation or ulcers. Carcinogen, teratogen, suspected mutagen.

LINK: International Chemical Safety Card

Authority

  • R. J. Gettens, G.L. Stout, Painting Materials, A Short Encyclopaedia, Dover Publications, New York, 1966 Comment: density 9.40 and ref. index 2.51; 2.71; 2.61
  • Thomas Gregory, The Condensed Chemical Dictionary, Reinhold Publishing, New York, 3rd ed., 1942
  • Ralph Mayer, A Dictionary of Art Terms and Techniques, Harper and Row Publishers, New York, 1969 (also 1945 printing)
  • Susan E. Schur, Conservation Terminology: A review of Past & Current Nomenclature of Materials, Technology and Conservation, Spring (p.34-39); Summer (p.35-38); Fall (p.25-36), 1985
  • Dictionary of Building Preservation, Ward Bucher, ed., John Wiley & Sons, Inc., New York City, 1996

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