Difference between pages "Sodium azide test" and "Sodium benzoate"

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[[File:azide1.jpg|thumb|Iodide-Azide Test]]
 
 
== Description ==
 
== Description ==
  
A microchemical test used to identify potentially hazardous [[sulfur|sulfur]] components in materials prior to their use near [[silver|silver]] objects. The sodium azide test detects the presence of reducible sulfur but not stable sulfur compounds such as sulfates. Reducible sulfur compounds can readily tarnish silver. For the test, 3 gm of sodium azide is dissolved in 100 ml of a 0.05 M [[iodine|iodine]] solution, then mixed with 3 ml [[denatured%20alcohol|methylated spirits]] and allowed to set for 30 minutes. A small portion of the test sample (2 mm fiber or 200 micron particles) is placed on a glass microscope slide under a coverslip. While observing the sample with a microscope (usually 40x), the reagent is introduced under the coverslip. Reducible sulfur produces visually apparent bubbles due to the formation of nitrogen during its reaction with the sodium azide/iodine solution. [[Wool|Wool]] fibers can be used as a reference for a positive test.
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White granular powder.  Sodium benzoate is used as an antiseptic and preservative in paints, food, and medicine. It is also used as a rust and mildew inhibitor.
  
 
== Synonyms and Related Terms ==
 
== Synonyms and Related Terms ==
  
iodide azide test
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benzoate of soda; sodium benzoic acid; Antimol
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[[[SliderGallery rightalign|sodium benzoate.jpg~Chemical structure]]]
  
 
== Risks ==
 
== Risks ==
  
* Sodium azide is highly toxic.   
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* Combustible.
* ThermoFisher: [https://www.fishersci.com/store/msds?partNumber=S227I1&productDescription=SODIUM+AZIDE+GRAN+PURIF+1+KG&vendorId=VN00033897&countryCode=US&language=en SDS]
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* Ingestion of large quantities is toxic.   
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* Maximum allowable concentration in food is 0.1%.   
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* ThermoFisher: [https://www.fishersci.com/store/msds?partNumber=AAA1594630&productDescription=SODIUM+BENZOATE+99%25+250G&vendorId=VN00024248&countryCode=US&language=en SDS]
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==Physical and Chemical Properties==
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Soluble in water, ethanol. Forms slightly alkaline solution in water.
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{| class="wikitable"
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|-
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! scope="row"| Composition
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| C6H5COONa
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|-
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! scope="row"| CAS
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| 532-32-1
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|-
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! scope="row"| Molecular Weight
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| mol. wt. = 144.1
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|}
  
 
==Resources and Citations==
 
==Resources and Citations==
  
* N.Odegaard, S.Carroll, W.Zimmt, ''Material Characterization Tests for Objects of Art and Archaeology'', Archetype Publications, London, 2000.
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* Michael McCann, ''Artist Beware'', Watson-Guptill Publications, New York City, 1979
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* Thomas Gregory, ''The Condensed Chemical Dictionary'', Reinhold Publishing, New York, 3rd ed., 1942
  
* V. Daniels, S Ward, "A Rapid Test for the Detection of Substance which will Tarnish Silver" ''Studies in Conservation'', 27(2), 1982, p.58-60.
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* ''The Merck Index'', Susan Budavari (ed.), Merck Research Labs, Whitehouse Station, NJ, 12th Edition, 1996  Comment: entry 8725
  
* Richard S. Lewis, ''Hawley's Condensed Chemical Dictionary'', Van Nostrand Reinhold, New York, 10th ed., 1993
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* G.S.Brady, ''Materials Handbook'', McGraw-Hill Book Co., New York, 1971  Comment: p 777
  
* Pam Hatchfield, ''Pollutants in the Museum Environment'', Archetype Press, London, 2002
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* ''The American Heritage Dictionary'' or ''Encarta'', via Microsoft Bookshelf 98, Microsoft Corp., 1998
  
* ''The Merck Index'', Martha Windholz (ed.), Merck Research Labs, Rahway NJ, 10th edition, 1983  Comment: entry 8724
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* ''Van Nostrand's Scientific Encyclopedia'', Douglas M. Considine (ed.), Van Nostrand Reinhold, New York, 1976
  
  
  
 
[[Category:Materials database]]
 
[[Category:Materials database]]

Latest revision as of 15:41, 31 May 2022

Description

White granular powder. Sodium benzoate is used as an antiseptic and preservative in paints, food, and medicine. It is also used as a rust and mildew inhibitor.

Synonyms and Related Terms

benzoate of soda; sodium benzoic acid; Antimol

Chemical structure

Sodium benzoate.jpg


Risks

  • Combustible.
  • Ingestion of large quantities is toxic.
  • Maximum allowable concentration in food is 0.1%.
  • ThermoFisher: SDS

Physical and Chemical Properties

Soluble in water, ethanol. Forms slightly alkaline solution in water.

Composition C6H5COONa
CAS 532-32-1
Molecular Weight mol. wt. = 144.1

Resources and Citations

  • Michael McCann, Artist Beware, Watson-Guptill Publications, New York City, 1979
  • Thomas Gregory, The Condensed Chemical Dictionary, Reinhold Publishing, New York, 3rd ed., 1942
  • The Merck Index, Susan Budavari (ed.), Merck Research Labs, Whitehouse Station, NJ, 12th Edition, 1996 Comment: entry 8725
  • G.S.Brady, Materials Handbook, McGraw-Hill Book Co., New York, 1971 Comment: p 777
  • The American Heritage Dictionary or Encarta, via Microsoft Bookshelf 98, Microsoft Corp., 1998
  • Van Nostrand's Scientific Encyclopedia, Douglas M. Considine (ed.), Van Nostrand Reinhold, New York, 1976