Difference between revisions of "Soluble nylon"

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== Description ==
 
== Description ==
  
A modified nylon developed by DuPont and ICI about 1940. Soluble nylon is [http://cameo.mfa.org/materials/fullrecord.asp?name=nylon resin nylon] that has been treated with [http://cameo.mfa.org/materials/fullrecord.asp?name=formaldehyde formaldehyde] to produce an unstable alkoxy substituted material. One commercial product, Calaton (n-methoxymethyl nylon), is prepared from [http://cameo.mfa.org/materials/fullrecord.asp?name=nylon 6,6 nylon 6,6]. The freshly prepared alkoxy substituted nylon is soluble in alcohols. However, when it is painted as a film, soluble nylon can hydrolyze, especially in the presence of acids, to produce a stiff, insoluble film. Soluble nylon was used in the mid-20th century as an adhesive, coating and sizing agent to add strength to wet paper and consolidate friable pigments. It is not recommended for any type of current conservation use.
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A modified nylon developed by DuPont and ICI about 1940. Soluble nylon is [http://cameo.mfa.org/materials/fullrecord.asp?name=nylon%20resin nylon] that has been treated with [http://cameo.mfa.org/materials/fullrecord.asp?name=formaldehyde formaldehyde] to produce an unstable alkoxy substituted material. One commercial product, Calaton (n-methoxymethyl nylon), is prepared from [http://cameo.mfa.org/materials/fullrecord.asp?name=nylon%206%2C6 nylon 6,6]. The freshly prepared alkoxy substituted nylon is soluble in alcohols. However, when it is painted as a film, soluble nylon can hydrolyze, especially in the presence of acids, to produce a stiff, insoluble film. Soluble nylon was used in the mid-20th century as an adhesive, coating and sizing agent to add strength to wet paper and consolidate friable pigments. It is not recommended for any type of current conservation use.
  
 
== Synonyms and Related Terms ==
 
== Synonyms and Related Terms ==
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== Additional Information ==
 
== Additional Information ==
  
C.Sease "The Case Against Using Soluble Nylon in Conservation Work" ''Studies in Conservation'', 26:102-110, 1981. E.De Witte "Soluble Nylon as Consolidation Agent for Stone" ''Studies in Conservation'', 20:30-34, 1975.
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° C.Sease "The Case Against Using Soluble Nylon in Conservation Work" ''Studies in Conservation'', 26:102-110, 1981. ° E.De Witte "Soluble Nylon as Consolidation Agent for Stone" ''Studies in Conservation'', 20:30-34, 1975.
  
 
== Comparisons ==
 
== Comparisons ==
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== Authority ==
 
== Authority ==
  
* Hermann Kuhn, Hermann Kuhn, ''Conservation and Restoration of Works of Art and Antiquities'', Butterworths, London, 1986
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* Hermann Kuhn, ''Conservation and Restoration of Works of Art and Antiquities'', Butterworths, London, 1986
  
* Pam Hatchfield, Pam Hatchfield, ''Pollutants in the Museum Environment'', Archetype Press, London, 2002
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* Pam Hatchfield, ''Pollutants in the Museum Environment'', Archetype Press, London, 2002
  
* Ceramics and Glass Conservation Section, Ceramics and Glass Conservation Section, List of Workshop Materials, The British Museum, London
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* Ceramics and Glass Conservation Section, List of Workshop Materials, The British Museum, London
  
* Meredith Montague, Meredith Montague, contributed information, 1998
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* Meredith Montague, contributed information, 1998
  
* Website address 1, Website address 1  Comment: Elvamide - www.dupont.com/enggpolymers/products/elvamide,html  states soluble in alcohol
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* Website address 1  Comment: Elvamide - www.dupont.com/enggpolymers/products/elvamide,html  states soluble in alcohol
  
 
* Website address 2  Comment: Zytel [DuPont] www.dupont.com/enggpolymers/products/zytel,html
 
* Website address 2  Comment: Zytel [DuPont] www.dupont.com/enggpolymers/products/zytel,html

Revision as of 07:54, 24 July 2013

Description

A modified nylon developed by DuPont and ICI about 1940. Soluble nylon is nylon that has been treated with formaldehyde to produce an unstable alkoxy substituted material. One commercial product, Calaton (n-methoxymethyl nylon), is prepared from nylon 6,6. The freshly prepared alkoxy substituted nylon is soluble in alcohols. However, when it is painted as a film, soluble nylon can hydrolyze, especially in the presence of acids, to produce a stiff, insoluble film. Soluble nylon was used in the mid-20th century as an adhesive, coating and sizing agent to add strength to wet paper and consolidate friable pigments. It is not recommended for any type of current conservation use.

Synonyms and Related Terms

nailon soluble (Esp.);

Examples: Calaton [ICI, Britain]; Maranyl [ICI]; Ultramid [BASF]; Elvamide [DuPont]

Other Properties

Initially soluble in methanol and ethanol.

Hazards and Safety

Hazardous to all artifacts. Becomes insoluble with age. Attracts dirt and shrinks with time.

DuPont: Elvamide MSDS

Additional Information

° C.Sease "The Case Against Using Soluble Nylon in Conservation Work" Studies in Conservation, 26:102-110, 1981. ° E.De Witte "Soluble Nylon as Consolidation Agent for Stone" Studies in Conservation, 20:30-34, 1975.

Comparisons

Physical Properties for Selected Thermoset Resins

General Characteristics of Polymers


Authority

  • Hermann Kuhn, Conservation and Restoration of Works of Art and Antiquities, Butterworths, London, 1986
  • Pam Hatchfield, Pollutants in the Museum Environment, Archetype Press, London, 2002
  • Ceramics and Glass Conservation Section, List of Workshop Materials, The British Museum, London
  • Meredith Montague, contributed information, 1998
  • Website address 1 Comment: Elvamide - www.dupont.com/enggpolymers/products/elvamide,html states soluble in alcohol
  • Website address 2 Comment: Zytel [DuPont] www.dupont.com/enggpolymers/products/zytel,html

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