Titanium dioxide

Rutile

Description

Titanium dioxide occurs naturally in three crystalline forms: Anatase, Rutile and Brookite, with rutile being the most abundant. In mineral form, titanium dioxide is often deeply coloured due to elemental impurities. Ground mineral rutile found some use as a colored pigment, but difficulties in grinding result in coarse particles with a different morphology than that of synthetic material. Naturally occurring anatase and brookite are not used for pigment manufacture. Both anatase and rutile have been synthesized since the early 20th century for use as white pigments, generally using processes based on either sulfuric acid or chlorine. The pigments are used in applications including paints, pastels, inks, paper, enamels, ceramics, glass, rubber, plastics, and as coatings and surface treatments in the textile and leather industries. They are nontoxic and can be used in foods and pharmaceuticals; their ultraviolet absorption properties have led to applications in sunscreen and lotions. Titanium dioxide is also used as a white reference material in many instruments for optical measurements or color spectrometry. Rutile can be made into synthetic gemstones of varying color.

From about 1908 onward, researchers in Norway and in the United States who were seeking to find a use for titanium-rich ore such as Ilmenite (iron titanium oxide) noted that titanium dioxide showed promise as a pigment due to its high hiding power. During development of a viable manufacturing method, small experimental batches of pigment were produced of various compositions and ranging in color from reddish yellow to off-white. Commercial manufacturing of anatase-based pigments began in Norway in 1918 (Titan Company A/S), and in the United States (Titanium Pigment Company) ramping up from 1916 to full production in 1919. Anatase pigments were developed first, and most of these early products were composites with barium sulfate, some also with calcium phosphate; pure pigments with 98% titanium dioxide were only introduced in 1923 in France and 1926 in the United States (an 83% pure product in Norway was replaced by a composite in the first year of production: for more detail on history see Anatase). Because anatase converts to rutile at high temperatures, calcination of the early pigments could result in up to 20% of coarse, gritty rutile.

Titanium dioxide (anatase and rutile)

Synonyms and Related Terms

titanium white; rutile; anatase; brookite; Pigment White 6; CI 77891; dioxyde de titane (Fr.); Titandioxid (Deut., Sven.); bianco di titanio (It.); dióxido de titanio (Esp.); titandioksid (Nor.); dióxido de titânio (Port.); titania; titanic anhydride; titanic acid anhydride; titanic oxide; Unitane; Titanox; Kronos

Raman

Raman

Raman

FTIR

FTIR

XRD

XRD

SEM

SEM

EDS

XRF

Other Properties

Particle size = 0.2-0.5 micrometers.

Chemically inert, insoluble in water, organic solvents, aqueous alkalis; can be dissolved in sulfuric or hydrofluoric acid; slow to dry in oil without additives or surface treatment.

Absorb strongly in the UV, are photochemically active and can cause deterioration of admixed media if exposed to ultraviolet light.

Composition	TiO2
CAS	13463-67-7
Mohs Hardness	5.5-6.5
Melting Point	1640 (dec)
Density	4.26
Molecular Weight	mol. wt. = 79.9
Refractive Index	2.5-2.7

|}== Hazards and Safety ==

Nontoxic. Noncombustible.

No significant hazards.

LINK: International Chemical Safety Card

Additional Information

° M.Laver, "Titanium Dioxide Whites", Artists Pigments, Volume 3, E. West FitzHugh (ed.), Oxford University Press: Oxford, 1997. ° Walter C. McCrone, "Polarized Light Microscopy in Conservation: A Personal Perspective" JAIC 33(2):101-14, 1994. (contains a table of dates on the history of titanium white as a pigment)

Comparisons

Properties of Common Abrasives

Natural and Simulated Diamonds

Characteristics of Common White Pigments

Sources Checked for Data in Record

• The Dictionary of Art, Grove's Dictionaries Inc., New York, 1996 Comment: "Pigments"

• Artists' Pigments: A Handbook of their History and Characteristics, Elisabeth West FitzHugh, Oxford University Press, Oxford, Vol. 3, 1997 Comment: M.Laver, "Titanium Dioxide Whites" -In Norway, production of TiO2 patented in 1913, and pigment production in November 1918 (Titan Co. In U.S., patent applications filed in 1912 and production of a composite pigment began in 1916.

• R. J. Gettens, G.L. Stout, Painting Materials, A Short Encyclopaedia, Dover Publications, New York, 1966

• Ralph Mayer, A Dictionary of Art Terms and Techniques, Harper and Row Publishers, New York, 1969 (also 1945 printing)

• Matt Roberts, Don Etherington, Bookbinding and the Conservation of Books: a Dictionary of Descriptive Terminology, U.S. Government Printing Office, Washington DC, 1982

• Dictionary of Building Preservation, Ward Bucher, ed., John Wiley & Sons, Inc., New York City, 1996 Comment: Pigment available in 1918

• The Merck Index, Martha Windholz (ed.), Merck Research Labs, Rahway NJ, 10th edition, 1983 Comment: entry 9612

• Reed Kay, The Painter's Guide To Studio Methods and Materials, Prentice-Hall, Inc., Englewood Cliffs, NJ, 1983

• Hoechst Celanese Corporation, Dictionary of Fiber & Textile Technology (older version called Man-made Fiber and Textile Dictionary, 1965), Hoechst Celanese Corporation, Charlotte NC, 1990

• Michael McCann, Artist Beware, Watson-Guptill Publications, New York City, 1979

• C.W.Chesterman, K.E.Lowe, Audubon Society Field Guide to North American Rocks and Minerals, Alfred A. Knopf, New York, 1979 Comment: density=4.2-4.3, hardness=6.0-6.5

• Thomas B. Brill, Light Its Interaction with Art and Antiquities, Plenum Press, New York City, 1980

• M. de Keijzer, 'A survey of red and yellow modern synthetic organic artists pigments discovered in the 20th century and used in oil colors', ICOM Preprints Lyons, France, Getty Conservation Institute, Los Angeles, p. 369, 1999

• Wikipedia, the free encyclopedia, at http://www.wikipedia.com Comment: http://en.wikipedia.org/wiki/Titanium_dioxide (Accessed Sept. 17, 2005)

• Richard S. Lewis, Hawley's Condensed Chemical Dictionary, Van Nostrand Reinhold, New York, 10th ed., 1993

• Susan E. Schur, Conservation Terminology: A review of Past & Current Nomenclature of Materials, Technology and Conservation, Spring (p.34-39); Summer (p.35-38); Fall (p.25-36), 1985 Comment: Artists pigments sold in mid 1920s

• Book and Paper Group, Paper Conservation Catalog, AIC, 1984, 1989

• External source or communication Comment: Submission by N. Marco 8/25/05.

• Website address 1 Comment: Pigments Through the Ages -http://webexhibits.org/pigments/indiv/overview/tiwhite.html