Difference between pages "Cadmium sulfide" and "Candelilla wax"

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[[File:pg30717greenockite.jpg|thumb|Greenockite]]
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[[File:image3_candelillawax.jpg|thumb|Candelilla Wax]]
 
== Description ==
 
== Description ==
[[File:cdred C100x.jpg|thumb|Cadmium red]]
 
Cadmium sulfide and cadmium sulfoselenide are intense colorants ranging in color from bright yellow to deep red. Cadmium sulfide was first synthesized in Germany in 1817 and later marketed as an artist pigment in the mid 19th century. Its use was not widespread, however, until about 1917. The finely divided, stable, light resistant particles are deeply colored. Early preparations of cadmium pigments had widely varying particles sizes from 0.1 to 7 micrometers, while recently manufactured pigments contain only submicrometer particles. Since the pure pigment was expensive, cadmium pigments were also sold in diluted lithopone mixtures called cadmopones starting in 1927. Currently, cadmium pigments are primarily used in plastics, ceramics, metal enamel coatings, and as glass colorants. They are permanent and have good hiding power.
 
[[File:Cdyellow C100x.jpg|thumb|Cadmium yellow]]
 
See also [[cadmium yellow]] and [[cadmium red]].
 
  
Note: Cadmium sulfide also occurs naturally in the minerals greenockite and hawleyite.
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A yellowish-brown vegetable [[wax]] exuded from the leaves and stems of succulent shrubs, ''Euphorbia antisyphilitica'' and ''Pedilanthus pavinia'', native to northern Mexico and the southwestern U.S. Candelilla wax is obtained by boiling the leaves and stems in [[water]] and [[sulfuric acid]]. Candelilla is composed of hydrocarbons, centered around C31 with smaller amounts of esters and triterpenoids. It is a dark brown wax that is hard and brittle with little tack. Candelilla wax is an all-purpose wax used for [[leather dressing]], [[polish%20%28material%29|polishes]], [[cement|cements]], [[Ebonite]] varnishes, candles, [[sealing wax]], paper sizing, waterproofing, metal casting, and insect-proofing.
  
 
== Synonyms and Related Terms ==
 
== Synonyms and Related Terms ==
  
cadmium yellow (PY 37); cadmium red (PR 108); cadmium brown; cadmium orange (PO 20); CI 77199; CI 77202; Cadmiumgelb (Deut.); Cadmiumsulfid (Deut.); sulfure de cadmium (Fr.); sulfuro de cadmio (Esp.); theioycho kadmio (Gr.); solfuro di cadmio (arancio di cadmio) (It.); cadmiumoranje (Ned.); sulfureto de cádmio (Port.); cadmium monosulfide; greenockite (mineral); hawleyite (mineral); jaune brilliant; cadmopone
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''Copernicia cerifera; Corypha cerifera''; Carnaubawachs (Deut.); carnauba wosk (Pol.); cera carnauba (Esp., It.); Brazil wax; ceara wax; olho wax; flora wax; pahla wax; chalky wax; Butcher's wax
  
[[[SliderGallery rightalign|Cadmium yellow (Forbes MFA 315), 785nm resize.tif~Raman (Cd yellow MFA)|Cadmium orange (Forbes MFA 210) resize.tif~Raman (Cd orange MFA)|Cadmium (Forbes MFA 318) resize.tif~Raman (Cd red MFA)|PIG210.jpg~XRD|f210sem.jpg~SEM|f210edsbw.jpg~EDS]]]
 
 
== Risks ==
 
== Risks ==
  
Toxic by ingestion and inhalation. Carcinogen. 
+
Combustible.
 
 
ThermoFisher: [https://www.fishersci.com/store/msds?partNumber=AA3834218&productDescription=CADMIUM+SULFIDE%2C+99.999%25+50G&vendorId=VN00024248&countryCode=US&language=en SDS]
 
 
 
 
== Physical and Chemical Properties ==
 
== Physical and Chemical Properties ==
  
Cubic or hexagonal crystals. Soluble in concentrated mineral acids with the evolution of H2S. Insoluble in water.  May fluorecse red. 
+
* Soluble in chloroform, turpentine, carbon tetrachloride, trichloroethylene, toluene and alkalis. Insoluble in water.  
 
+
* Saponification value = 35 - 86;  
Particles are tiny (about 1 micrometer) and have a high refractive index.
+
* Iodine number = 14-37; 
 +
* Acid number = 12-20 
 +
* Total % alcohols and hydrocarbons = 65-75
  
 
{| class="wikitable"
 
{| class="wikitable"
|-
 
! scope="row"| Composition
 
| CdS
 
 
|-
 
|-
 
! scope="row"| CAS
 
! scope="row"| CAS
| 1306-23-6
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| 8006-44-8
 
|-
 
|-
 
! scope="row"| Melting Point
 
! scope="row"| Melting Point
| sublimes at 980 C
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| 67-71 C
 
|-
 
|-
 
! scope="row"| Density
 
! scope="row"| Density
| 4.35-4.82 g/ml
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| 0.950-0.990 g/ml
|-
 
! scope="row"| Molecular Weight
 
| mol. wt. = 144.5
 
 
|-
 
|-
 
! scope="row"| Refractive Index
 
! scope="row"| Refractive Index
| e=2.506, w=2.529
+
| 1.4555
 
|}
 
|}
  
==Resources and Citations==
+
== Comparisons ==
* I. Fiedler, M. Bayard, "Cadmium yellows, oranges and reds", ''Artists Pigments'', Volume 1, R. Feller (ed.), Cambridge University Press: Cambridge, 1986.
+
 
* Nicholas Eastaugh, Valentine Walsh, Tracey Chaplin, Ruth Siddall, ''Pigment Compendium'', Elsevier Butterworth-Heinemann, Oxford, 2004
+
[[media:download_file_25.pdf|Properties of Natural Waxes]]
 +
 
 +
== Resources and Citations ==
  
* R. J. Gettens, G.L. Stout, ''Painting Materials, A Short Encyclopaedia'', Dover Publications, New York, 1966
+
* R. J. Gettens, G.L. Stout, ''Painting Materials, A Short Encyclopaedia'', Dover Publications, New York, 1966 Comment: melting range 67-71 C
  
 
* Ralph Mayer, ''A Dictionary of Art Terms and Techniques'', Harper and Row Publishers, New York, 1969 (also 1945 printing)
 
* Ralph Mayer, ''A Dictionary of Art Terms and Techniques'', Harper and Row Publishers, New York, 1969 (also 1945 printing)
  
* ''The Dictionary of Art'', Grove's Dictionaries Inc., New York, 1996 Comment: "Pigment"
+
* Matt Roberts, Don Etherington, ''Bookbinding and the Conservation of Books: a Dictionary of Descriptive Terminology'', U.S. Government Printing Office, Washington DC, 1982  Comment: softening range 64-68C
 +
 
 +
* G.S.Brady, ''Materials Handbook'', McGraw-Hill Book Co., New York, 1971 Comment: p. 136; melting point=67-70C, iodine value=37, saponification value=45-65
 +
 
 +
* John S. Mills, Raymond White, ''The Organic Chemistry of Museum Objects'', Butterworth Heineman, London, 2nd ed., 1994
 +
 
 +
* ''A History of Technology'', Charles Singer, E.J. Holmyard, A.R. Hall (eds.), Clarendon Press, Oxford, Volume 1: From Early times to Fall of Ancient Empires, 1954
 +
 
 +
* Wikipedia: http://en.wikipedia.org/wiki/Candelilla_wax (Accessed Feb. 10, 2006)
 +
 
 +
* ''CRC Handbook of Chemistry and Physics'', Robert Weast (ed.), CRC Press, Boca Raton, Florida, v. 61, 1980  Comment: melting point=67-69C, density=0.982-0.986, ref. index=1.454-1.463, iodine value=14.4-20.4, acid value=12.7-18.1, saponification value=35-86
  
* Reed Kay, ''The Painter's Guide To Studio Methods and Materials'', Prentice-Hall, Inc., Englewood Cliffs, NJ, 1983
+
* Richard S. Lewis, ''Hawley's Condensed Chemical Dictionary'', Van Nostrand Reinhold, New York, 10th ed., 1993
  
* R.D. Harley, ''Artists' Pigments c. 1600-1835'', Butterworth Scientific, London, 1982
+
* Random House, ''Webster's Encyclopedic Unabridged Dictionary of the English Language'', Grammercy Book, New York, 1997
  
* Monona Rossol, ''The Artist's Complete Health and Safety Guide'', Allworth Press, New York, 1994
+
* ''The American Heritage Dictionary'' or ''Encarta'', via Microsoft Bookshelf 98, Microsoft Corp., 1998
  
* Book and Paper Group, ''Paper Conservation Catalog'', AIC, 1984, 1989
+
* Art and Architecture Thesaurus Online, http://www.getty.edu/research/tools/vocabulary/aat/, J. Paul Getty Trust, Los Angeles, 2000
  
  
  
 
[[Category:Materials database]]
 
[[Category:Materials database]]

Latest revision as of 16:19, 18 May 2022

Candelilla Wax

Description

A yellowish-brown vegetable Wax exuded from the leaves and stems of succulent shrubs, Euphorbia antisyphilitica and Pedilanthus pavinia, native to northern Mexico and the southwestern U.S. Candelilla wax is obtained by boiling the leaves and stems in Water and Sulfuric acid. Candelilla is composed of hydrocarbons, centered around C31 with smaller amounts of esters and triterpenoids. It is a dark brown wax that is hard and brittle with little tack. Candelilla wax is an all-purpose wax used for Leather dressing, polishes, cements, Ebonite varnishes, candles, Sealing wax, paper sizing, waterproofing, metal casting, and insect-proofing.

Synonyms and Related Terms

Copernicia cerifera; Corypha cerifera; Carnaubawachs (Deut.); carnauba wosk (Pol.); cera carnauba (Esp., It.); Brazil wax; ceara wax; olho wax; flora wax; pahla wax; chalky wax; Butcher's wax

Risks

Combustible.

Physical and Chemical Properties

  • Soluble in chloroform, turpentine, carbon tetrachloride, trichloroethylene, toluene and alkalis. Insoluble in water.
  • Saponification value = 35 - 86;
  • Iodine number = 14-37;
  • Acid number = 12-20
  • Total % alcohols and hydrocarbons = 65-75
CAS 8006-44-8
Melting Point 67-71 C
Density 0.950-0.990 g/ml
Refractive Index 1.4555

Comparisons

Properties of Natural Waxes

Resources and Citations

  • R. J. Gettens, G.L. Stout, Painting Materials, A Short Encyclopaedia, Dover Publications, New York, 1966 Comment: melting range 67-71 C
  • Ralph Mayer, A Dictionary of Art Terms and Techniques, Harper and Row Publishers, New York, 1969 (also 1945 printing)
  • Matt Roberts, Don Etherington, Bookbinding and the Conservation of Books: a Dictionary of Descriptive Terminology, U.S. Government Printing Office, Washington DC, 1982 Comment: softening range 64-68C
  • G.S.Brady, Materials Handbook, McGraw-Hill Book Co., New York, 1971 Comment: p. 136; melting point=67-70C, iodine value=37, saponification value=45-65
  • John S. Mills, Raymond White, The Organic Chemistry of Museum Objects, Butterworth Heineman, London, 2nd ed., 1994
  • A History of Technology, Charles Singer, E.J. Holmyard, A.R. Hall (eds.), Clarendon Press, Oxford, Volume 1: From Early times to Fall of Ancient Empires, 1954
  • CRC Handbook of Chemistry and Physics, Robert Weast (ed.), CRC Press, Boca Raton, Florida, v. 61, 1980 Comment: melting point=67-69C, density=0.982-0.986, ref. index=1.454-1.463, iodine value=14.4-20.4, acid value=12.7-18.1, saponification value=35-86
  • Richard S. Lewis, Hawley's Condensed Chemical Dictionary, Van Nostrand Reinhold, New York, 10th ed., 1993
  • Random House, Webster's Encyclopedic Unabridged Dictionary of the English Language, Grammercy Book, New York, 1997
  • The American Heritage Dictionary or Encarta, via Microsoft Bookshelf 98, Microsoft Corp., 1998