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| − | [[File:pg30717greenockite.jpg|thumb|Greenockite]]
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| | == Description == | | == Description == |
| − | [[File:cdred C100x.jpg|thumb|Cadmium red]]
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| − | Cadmium sulfide and cadmium sulfoselenide are intense colorants ranging in color from bright yellow to deep red. Cadmium sulfide was first synthesized in Germany in 1817 and later marketed as an artist pigment in the mid 19th century. Its use was not widespread, however, until about 1917. The finely divided, stable, light resistant particles are deeply colored. Early preparations of cadmium pigments had widely varying particles sizes from 0.1 to 7 micrometers, while recently manufactured pigments contain only submicrometer particles. Since the pure pigment was expensive, cadmium pigments were also sold in diluted lithopone mixtures called cadmopones starting in 1927. Currently, cadmium pigments are primarily used in plastics, ceramics, metal enamel coatings, and as glass colorants. They are permanent and have good hiding power.
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| − | [[File:Cdyellow C100x.jpg|thumb|Cadmium yellow]]
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| − | See also [[cadmium yellow]] and [[cadmium red]].
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| − | Note: Cadmium sulfide also occurs naturally in the minerals greenockite and hawleyite.
| + | Colorless crystals. Titanium potassium oxalate is used as a mordant in dyeing [[cotton|cotton]] and [[leather|leather]]. It is also used as a sensitizer of aluminum for photography (Lewis 1993). |
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| | == Synonyms and Related Terms == | | == Synonyms and Related Terms == |
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| − | cadmium yellow (PY 37); cadmium red (PR 108); cadmium brown; cadmium orange (PO 20); CI 77199; CI 77202; Cadmiumgelb (Deut.); Cadmiumsulfid (Deut.); sulfure de cadmium (Fr.); sulfuro de cadmio (Esp.); theioycho kadmio (Gr.); solfuro di cadmio (arancio di cadmio) (It.); cadmiumoranje (Ned.); sulfureto de cádmio (Port.); cadmium monosulfide; greenockite (mineral); hawleyite (mineral); jaune brilliant; cadmopone
| + | T.P.O. |
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| − | [[[SliderGallery rightalign|Cadmium yellow (Forbes MFA 315), 785nm resize.tif~Raman (Cd yellow MFA)|Cadmium orange (Forbes MFA 210) resize.tif~Raman (Cd orange MFA)|Cadmium (Forbes MFA 318) resize.tif~Raman (Cd red MFA)|PIG210.jpg~XRD|f210sem.jpg~SEM|f210edsbw.jpg~EDS]]]
| + | ==Risks== |
| − | == Risks == | + | * Toxic |
| − | | + | * Neoprene gloves and goggles are recommended |
| − | Toxic by ingestion and inhalation. Carcinogen.
| + | * Loba Chem: [https://www.lobachemie.com/lab-chemical-msds/MSDS-POTASSIUM-TITANIUM-OXALATE-CASNO-14402-67-05461-EN.aspx SDS] |
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| − | ThermoFisher: [https://www.fishersci.com/store/msds?partNumber=AA3834218&productDescription=CADMIUM+SULFIDE%2C+99.999%25+50G&vendorId=VN00024248&countryCode=US&language=en SDS]
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| | == Physical and Chemical Properties == | | == Physical and Chemical Properties == |
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| − | Cubic or hexagonal crystals. Soluble in concentrated mineral acids with the evolution of H2S. Insoluble in water. May fluorecse red.
| + | * Soluble in water. |
| − | | + | * Composition = K2TiC2O5 - 2H2O |
| − | Particles are tiny (about 1 micrometer) and have a high refractive index.
| + | * Loba Chem: [https://www.lobachemie.com/lab-chemical-msds/MSDS-POTASSIUM-TITANIUM-OXALATE-CASNO-14402-67-05461-EN.aspx SDS] |
| − | | |
| − | {| class="wikitable"
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| − | |-
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| − | ! scope="row"| Composition
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| − | | CdS
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| − | |-
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| − | ! scope="row"| CAS
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| − | | 1306-23-6
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| − | |-
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| − | ! scope="row"| Melting Point
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| − | | sublimes at 980 C
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| − | |-
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| − | ! scope="row"| Density
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| − | | 4.35-4.82 g/ml
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| − | |-
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| − | ! scope="row"| Molecular Weight
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| − | | mol. wt. = 144.5
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| − | |-
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| − | ! scope="row"| Refractive Index
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| − | | e=2.506, w=2.529
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| − | |}
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| − | | |
| − | ==Resources and Citations==
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| − | * I. Fiedler, M. Bayard, "Cadmium yellows, oranges and reds", ''Artists Pigments'', Volume 1, R. Feller (ed.), Cambridge University Press: Cambridge, 1986.
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| − | * Nicholas Eastaugh, Valentine Walsh, Tracey Chaplin, Ruth Siddall, ''Pigment Compendium'', Elsevier Butterworth-Heinemann, Oxford, 2004
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| − | * R. J. Gettens, G.L. Stout, ''Painting Materials, A Short Encyclopaedia'', Dover Publications, New York, 1966
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| − | * Ralph Mayer, ''A Dictionary of Art Terms and Techniques'', Harper and Row Publishers, New York, 1969 (also 1945 printing)
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| − | * ''The Dictionary of Art'', Grove's Dictionaries Inc., New York, 1996 Comment: "Pigment"
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| − | | |
| − | * Reed Kay, ''The Painter's Guide To Studio Methods and Materials'', Prentice-Hall, Inc., Englewood Cliffs, NJ, 1983
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| − | | |
| − | * R.D. Harley, ''Artists' Pigments c. 1600-1835'', Butterworth Scientific, London, 1982
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| − | | |
| − | * Monona Rossol, ''The Artist's Complete Health and Safety Guide'', Allworth Press, New York, 1994
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| − | | |
| − | * Book and Paper Group, ''Paper Conservation Catalog'', AIC, 1984, 1989
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| | [[Category:Materials database]] | | [[Category:Materials database]] |