Difference between revisions of "Zircon"

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[[File:1998.569-SC8319.jpg|thumb|'''MFA Acc. #:''' 1998.569]]
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[[File:1998.569-SC8319.jpg|thumb|Jeweled brooch<br>MFA# 1998.569]]
 
== Description ==
 
== Description ==
 
A natural mineral ore of zirconium silicate primarily used to produce [http://cameo.mfa.org/materials/fullrecord.asp?name=zirconium zirconium]. The zircon tetragonal prism crystals are found on beaches or in river placer deposits in association with [http://cameo.mfa.org/materials/fullrecord.asp?name=silica silica] containing minerals. The hard, refractory, but brittle crystals come in a wide range of colors: yellow, green, blue, red to brown. Clear zircon crystals, sold as Matura diamonds, make very brilliant gemstones because of their high refractive index. Clear yellow to red zircon, called [http://cameo.mfa.org/materials/fullrecord.asp?name=hyacinth hyacinth] or jacinth, is also used as a gem. Ancient gems of hessonite garnets were also called jacinth and hyacinth which led to some being incorrectly labeled zircon (Ogden 1982). Zircons from Sri Lanka have been used for 2000 years. Large deposits are found in Australia. Other sources are Brazil, India, Pakistan, Thailand, New Zealand, Myanmar (formerly Burma), Western Africa, Norway (Seiland), Russia, Canada (Ontario) and the U.S. (Florida, Colorado, South Carolina, New Jersey).
 
 
 
[[File:pz30324zircon2.jpg|thumb|Zircon]]
 
[[File:pz30324zircon2.jpg|thumb|Zircon]]
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A natural mineral ore of zirconium silicate primarily used to produce [[zirconium]]. The zircon tetragonal prism crystals are found on beaches or in river placer deposits in association with [[silica]] containing minerals. The hard, refractory, but brittle crystals come in a wide range of colors: yellow, green, blue, red to brown. Clear zircon crystals, sold as Matura diamonds, make very brilliant gemstones because of their high refractive index. Clear yellow to red zircon, called [[hyacinth]] or jacinth, is also used as a gem. Ancient gems of hessonite garnets were also called jacinth and hyacinth which led to some being incorrectly labeled zircon (Ogden 1982). Zircons from Sri Lanka have been used for 2000 years. Large deposits are found in Australia. Other sources are Brazil, India, Pakistan, Thailand, New Zealand, Myanmar (formerly Burma), Western Africa, Norway (Seiland), Russia, Canada (Ontario) and the U.S. (Florida, Colorado, South Carolina, New Jersey).
 +
[[File:Zirconemr1.jpg|thumb|Zircon sand]]
 
== Synonyms and Related Terms ==
 
== Synonyms and Related Terms ==
  
 
zirconium silicate; zirkelite; zirconite; zircon sand; Matura diamonds; jacinth; hyacinth; jargoon; jargon; Zircopax [Titanium Alloy Mfg.]; Superpax; Ultrox [M&T Chemical]; cubic zirconia; Zirkon (Deut.); zircón (Esp.); circón (Esp.); zircon (Fr.); zirkoon (Ned.); cyrkon (Pol.); zircão (Port.)
 
zirconium silicate; zirkelite; zirconite; zircon sand; Matura diamonds; jacinth; hyacinth; jargoon; jargon; Zircopax [Titanium Alloy Mfg.]; Superpax; Ultrox [M&T Chemical]; cubic zirconia; Zirkon (Deut.); zircón (Esp.); circón (Esp.); zircon (Fr.); zirkoon (Ned.); cyrkon (Pol.); zircão (Port.)
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[[[SliderGallery rightalign|zirconlyon.jpg~Raman (Lyon)|Zirconitaly1.jpg~Raman (U of Parma)|Jacinth yellow zircon.jpg~Raman Jacinth (MFA)|zircon.jpg~Chemical structure]]]
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== Risks ==
  
[[[SliderGallery rightalign|zirconlyon.jpg~Raman|Zirconitaly1.jpg~Raman|zircon.jpg~Chemical structure]]]
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* Contact and inhalation of zirconium compounds may cause nodules under the skin and in the lungs. 
 
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* Fisher Scientific: [https://fscimage.fishersci.com/msds/33934.htm MSDS]
== Other Properties ==
 
  
Insoluble in acids. 
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== Physical and Chemical Properties ==
  
Tetragonal system with square prismatic crystals.    
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* Insoluble in acids 
 
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* Tetragonal system with tabular to prismatic crystals     
Fracture = uneven. Luster = adamantine to vitreous. Streak = colorless.  
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* Fracture = conchoidal to uneven   
 
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* Luster = adamantine to vitreous   
Pleochroic.  Fluorescence = some show dull yellow color; some may phosphoresce.
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* Streak = colorless   
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* Pleochroism = moderate purplish red to brown dichroism 
 +
* Fluorescence = some show dull yellow color; some may phosphoresce. Not diagnostic.
 +
* Birefringence = 0 to 0.059
  
 
Heating brown zircon crystals produces strong colors (blue, green, red, etc.) that fade slowly with time or with UV exposure.
 
Heating brown zircon crystals produces strong colors (blue, green, red, etc.) that fade slowly with time or with UV exposure.
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|-
 
|-
 
! scope="row"| Melting Point
 
! scope="row"| Melting Point
| 2550
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| 2550 C
 
|-
 
|-
 
! scope="row"| Density
 
! scope="row"| Density
| 4.6-4.7
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| 4.0-4.7 g/ml
 
|-
 
|-
 
! scope="row"| Molecular Weight
 
! scope="row"| Molecular Weight
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! scope="row"| Refractive Index
 
! scope="row"| Refractive Index
 
| 1.94; 1.98
 
| 1.94; 1.98
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|-
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! scope="row"| Dispersion
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| 0.038 (moderate fire sometimes masked by body color)
 
|}
 
|}
 
== Hazards and Safety ==
 
 
Contact and inhalation of zirconium compounds may cause nodules under the skin and in the lungs. 
 
 
Fisher Scientific: [https://fscimage.fishersci.com/msds/33934.htm MSDS]
 
 
== Additional Information ==
 
 
° J. Ogden, ''Jewelry of the Ancient World'', Rizzoli International Publications, New York, 1982. ° Mineralogy Database: [http://www.webmineral.com/data/Zircon.shtml Zircon]
 
  
 
== Comparisons ==
 
== Comparisons ==
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[[media:download_file_441.pdf|Natural and Simulated Diamonds]]
 
[[media:download_file_441.pdf|Natural and Simulated Diamonds]]
  
 
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==Resources and Citations==
 
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* Gem Identification Lab Manual, Gemological Institute of America, 2016.
== Additional Images ==
 
 
 
<gallery>
 
File:Zirconemr1.jpg|Zircon sand
 
</gallery>
 
 
 
 
 
== Authority ==
 
 
 
 
* Jack Odgen, ''Jewellery of the Ancient World'', Rizzoli International Publications Inc., New York City, 1982
 
* Jack Odgen, ''Jewellery of the Ancient World'', Rizzoli International Publications Inc., New York City, 1982
 
 
* R.F.Symmes, T.T.Harding, Paul Taylor, ''Rocks, Fossils and Gems'', DK Publishing, Inc., New York City, 1997
 
* R.F.Symmes, T.T.Harding, Paul Taylor, ''Rocks, Fossils and Gems'', DK Publishing, Inc., New York City, 1997
 
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* ''Encyclopedia Britannica'', http://www.britannica.com  Comment: "zircon" [Accessed December 11, 2001]. (color photo and tech Info)
* ''Encyclopedia Britannica'', http://www.britannica.com  Comment: "zircon" Encyclopædia Britannica [Accessed December 11, 2001]. (color photo and tech Info)
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* Website: http://www.geo.utexas.edu/courses/347k/redesign/gem_notes/Zircon/zircon_triple.htm (fluorescence information)
 
 
* Website address 1  Comment: http://www.geo.utexas.edu/courses/347k/redesign/gem_notes/Zircon/zircon_triple.htm (fluorescence information)
 
 
 
 
* C.W.Chesterman, K.E.Lowe, ''Audubon Society Field Guide to North American Rocks and Minerals'', Alfred A. Knopf, New York, 1979
 
* C.W.Chesterman, K.E.Lowe, ''Audubon Society Field Guide to North American Rocks and Minerals'', Alfred A. Knopf, New York, 1979
 
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* Wikipedia: [https://en.wikipedia.org/wiki/Zircon Zircon] (Accessed Sept. 20, 2005 and Jan 2023)
* Wikipedia, the free encyclopedia, at http://www.wikipedia.com  Comment: http://en.wikipedia.org/wiki/Zircon (Accessed Sept. 20, 2005)
 
 
 
 
* G.S.Brady, ''Materials Handbook'', McGraw-Hill Book Co., New York, 1971  Comment: p. 890
 
* G.S.Brady, ''Materials Handbook'', McGraw-Hill Book Co., New York, 1971  Comment: p. 890
 
 
* ''The Merck Index'', Susan Budavari (ed.), Merck Research Labs, Whitehouse Station, NJ, 12th Edition, 1996  Comment: entry 9986
 
* ''The Merck Index'', Susan Budavari (ed.), Merck Research Labs, Whitehouse Station, NJ, 12th Edition, 1996  Comment: entry 9986
 
 
* Michael McCann, ''Artist Beware'', Watson-Guptill Publications, New York City, 1979
 
* Michael McCann, ''Artist Beware'', Watson-Guptill Publications, New York City, 1979
  

Latest revision as of 14:54, 24 January 2023

Jeweled brooch
MFA# 1998.569

Description

Zircon

A natural mineral ore of zirconium silicate primarily used to produce Zirconium. The zircon tetragonal prism crystals are found on beaches or in river placer deposits in association with Silica containing minerals. The hard, refractory, but brittle crystals come in a wide range of colors: yellow, green, blue, red to brown. Clear zircon crystals, sold as Matura diamonds, make very brilliant gemstones because of their high refractive index. Clear yellow to red zircon, called Hyacinth or jacinth, is also used as a gem. Ancient gems of hessonite garnets were also called jacinth and hyacinth which led to some being incorrectly labeled zircon (Ogden 1982). Zircons from Sri Lanka have been used for 2000 years. Large deposits are found in Australia. Other sources are Brazil, India, Pakistan, Thailand, New Zealand, Myanmar (formerly Burma), Western Africa, Norway (Seiland), Russia, Canada (Ontario) and the U.S. (Florida, Colorado, South Carolina, New Jersey).

Zircon sand

Synonyms and Related Terms

zirconium silicate; zirkelite; zirconite; zircon sand; Matura diamonds; jacinth; hyacinth; jargoon; jargon; Zircopax [Titanium Alloy Mfg.]; Superpax; Ultrox [M&T Chemical]; cubic zirconia; Zirkon (Deut.); zircón (Esp.); circón (Esp.); zircon (Fr.); zirkoon (Ned.); cyrkon (Pol.); zircão (Port.)

Raman (Lyon)

Zirconlyon.jpg

Raman (U of Parma)

Zirconitaly1.jpg

Raman Jacinth (MFA)

Jacinth yellow zircon.jpg

Chemical structure

Zircon.jpg

Risks

  • Contact and inhalation of zirconium compounds may cause nodules under the skin and in the lungs.
  • Fisher Scientific: MSDS

Physical and Chemical Properties

  • Insoluble in acids
  • Tetragonal system with tabular to prismatic crystals
  • Fracture = conchoidal to uneven
  • Luster = adamantine to vitreous
  • Streak = colorless
  • Pleochroism = moderate purplish red to brown dichroism
  • Fluorescence = some show dull yellow color; some may phosphoresce. Not diagnostic.
  • Birefringence = 0 to 0.059

Heating brown zircon crystals produces strong colors (blue, green, red, etc.) that fade slowly with time or with UV exposure.

Composition ZrSiO4
CAS 14940-68-2
Mohs Hardness 6.0 - 7.5
Melting Point 2550 C
Density 4.0-4.7 g/ml
Molecular Weight mol. wt. = 183.31
Refractive Index 1.94; 1.98
Dispersion 0.038 (moderate fire sometimes masked by body color)

Comparisons

Properties of Common Gemstones

Natural and Simulated Diamonds

Resources and Citations

  • Gem Identification Lab Manual, Gemological Institute of America, 2016.
  • Jack Odgen, Jewellery of the Ancient World, Rizzoli International Publications Inc., New York City, 1982
  • R.F.Symmes, T.T.Harding, Paul Taylor, Rocks, Fossils and Gems, DK Publishing, Inc., New York City, 1997
  • Encyclopedia Britannica, http://www.britannica.com Comment: "zircon" [Accessed December 11, 2001]. (color photo and tech Info)
  • Website: http://www.geo.utexas.edu/courses/347k/redesign/gem_notes/Zircon/zircon_triple.htm (fluorescence information)
  • C.W.Chesterman, K.E.Lowe, Audubon Society Field Guide to North American Rocks and Minerals, Alfred A. Knopf, New York, 1979
  • Wikipedia: Zircon (Accessed Sept. 20, 2005 and Jan 2023)
  • G.S.Brady, Materials Handbook, McGraw-Hill Book Co., New York, 1971 Comment: p. 890
  • The Merck Index, Susan Budavari (ed.), Merck Research Labs, Whitehouse Station, NJ, 12th Edition, 1996 Comment: entry 9986
  • Michael McCann, Artist Beware, Watson-Guptill Publications, New York City, 1979

Retrieved from "https://cameo.mfa.org/index.php?title=Zircon&oldid=95366"