Aragonite

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Contents

Description

A crystalline form of calcium carbonate that occurs in coral, shells, pearls, stalactites, and water deposits. Aragonite was named after the Aragon region in Spain where it was first discovered. Its orthorhombic system forms compact, acicular crystals that make it harder and heavier than calcite. When aragonite is formed by water deposition of calcium carbonate, the crystals often grow in radiating flowers. Aragonite mines are located in Europe, Bolivia, and the U.S. (New Mexico, Arizona). Aragonite was used in antiquity for beads and decorative items. It can be converted to calcite with heat (470 C) and changes slowly to calcite at room temperature.

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Synonyms and Related Terms

calcium carbonate; nacre; shell white; coral; Aragonit (Deut., Pol.); aragonita (Esp.); aragonito (Esp.); aragonite (Fr., Port.); aragoniet (Ned.)

Raman

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FTIR

MFA- Aragonite.jpg

Chemical structure

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Other Properties

Orthorhombic crystal system with platy or fibrous, acicular crystals that are often twinned. Reacts with acids to evolve carbon dioxide. Fluorescent. Brittle. Aragonite is harder and denser than calcite.

Luster = vitreous to resinous. Transparent to translucent. Fracture = subconchoidal. Streak = white

Strongly birefringent showing interference colors. Straight extinction

Composition CaCO3
CAS 471-34-1
Mohs Hardness 3.5 - 4.0
Density 2.93-2.95
Molecular Weight mol. wt. = 100.09
Refractive Index 1.530, 1.682, 1.686

Hazards and Safety

No significant hazards.

Mallinckrodt Baker: MSDS

Additional Information

° R. Gettens, E. West Fitzhugh, R.Feller, "Calcium Carbonate Whites", Artists Pigments, Vol. 2., A. Roy ed. Oxford University Press, Oxford, 1993.

° Mineralogy Database: Aragonite

Additional Images


Sources Checked for Data in Record

  • Jack Odgen, Jewellery of the Ancient World, Rizzoli International Publications Inc., New York City, 1982
  • Nicholas Eastaugh, Valentine Walsh, Tracey Chaplin, Ruth Siddall, Pigment Compendium, Elsevier Butterworth-Heinemann, Oxford, 2004 Comment: Refractive Index: alpha=1.529-1.530; beta=1.680-1.682; gamma=1.685-1.686
  • C.W.Chesterman, K.E.Lowe, Audubon Society Field Guide to North American Rocks and Minerals, Alfred A. Knopf, New York, 1979
  • G.S.Brady, Materials Handbook, McGraw-Hill Book Co., New York, 1971 Comment: p. 131
  • Richard S. Lewis, Hawley's Condensed Chemical Dictionary, Van Nostrand Reinhold, New York, 10th ed., 1993
  • Van Nostrand's Scientific Encyclopedia, Douglas M. Considine (ed.), Van Nostrand Reinhold, New York, 1976
  • Random House, Webster's Encyclopedic Unabridged Dictionary of the English Language, Grammercy Book, New York, 1997
  • The American Heritage Dictionary or Encarta, via Microsoft Bookshelf 98, Microsoft Corp., 1998

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