Eosin

From CAMEO
Jump to: navigation, search
Eosin

Description

A red crystalline dye composed of the potassium, sodium, or lead salt of tetrabromofluorescein. First discovered by Caro in 1871, eosin is primarily used as an acid dye for producing a blood red color in silk, wool, paper, leather, and cotton. It is also used as a histological stain, a cosmetic colorant, and a colorant in red inks. In the late 19th and early 20th century, eosin was also used as a red paint pigment. Alcoholic solutions have a strong green autofluorescence. Eosin is not permanent and fades rapidly in sunlight.

Absorption spectrum

Synonyms and Related Terms

tetrabromofluorescein; Pigment Red 90; CI 45380; D&C Red No. 22; D&C Red No. 21; Acid Red 87; Solvent Red 43; éosine (Fr.); eosina (Esp., Port.); eosin Y; eosine A; eosine G; bromeosin; bromofluoresceic acid; geranium lake; eosine yellowish

Other Properties

Soluble in ethanol. Insoluble in water (potassium and sodium salts of eosin are water soluble).

Maximum absorption wavelength = 520 nm.

Maximum emission wavelength = 540 nm.

Composition C20H8O5Br4
CAS 548-26-5
Melting Point 300
Molecular Weight Mol. wt. = 647.9

Hazards and Safety

Causes skin irritation. Fades rapidly in sunlight.

Mallinckrodt Baker: MSDS

Additional Information

M.Ballard (ed.), Important Early Synthetic Dyes. Chemistry, Constitution, Date, Properties. Conservation Analytical Laboratory, Smithsonian Institution, 1991.

Sources Checked for Data in Record

  • R. J. Gettens, G.L. Stout, Painting Materials, A Short Encyclopaedia, Dover Publications, New York, 1966
  • Richard S. Lewis, Hawley's Condensed Chemical Dictionary, Van Nostrand Reinhold, New York, 10th ed., 1993
  • Monona Rossol, The Artist's Complete Health and Safety Guide, Allworth Press, New York, 1994
  • The Merck Index, Martha Windholz (ed.), Merck Research Labs, Rahway NJ, 10th edition, 1983 Comment: entry 3639
  • Encyclopedia Britannica, http://www.britannica.com Comment: "Chemical Compound." Encyclopædia Britannica. 2004. Encyclopædia Britannica Premium Service. 12 May 2004 .
  • Website address 1 Comment: www.probes.com/handbook/sections - gives absorption max=524 and emission max=544
  • Website address 2 Comment: member.pgonline.com/~bryand/dyes/45380.htm - absorption max = 516
  • Colour Index International online at www.colour-index.org Comment: discoverer and date
  • Sigma Dyes, Stains and Natural Pigments, Infrared Library, Nicolet, 1991-1995 Comment: OMNIC: formula= C20H8O5Br4, CAS= 548-26-5
  • The American Heritage Dictionary or Encarta, via Microsoft Bookshelf 98, Microsoft Corp., 1998