Purpurin

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Purpurin

Description

One of the natural colorants extracted from Madder roots and other Rubiaceae family plants. Purpurin has been manufactured synthetically by the oxidation of alizarin since the 1920s. Purpurin forms a brilliant red color when mordanted with aluminum salts. It is not considered a permanent artists pigment (Mayer 1969). In red dyed fabric, the presence of purpurin along with alizarin has been used to distinguish natural madder dyes from the synthetic alizarin dyes first sold in 1871. Purpurin fluoresces a bright yellow-red while alizarin produces a pale violet color.

Synonyms and Related Terms

1,2,4-trihydroxyanthraquinone; Natural Red 16; CI 75410; purpurine; purpuriini (Fin.); purpurina (Esp., Port.)

FTIR (MFA)

Purpurin.TIF

Raman (UCL)

PurpurinUCL.jpg

EEM Color

Purpurin color.PNG

EEM Line

Purpurin line.PNG


Physical and Chemical Properties

  • Soluble in alkali, benzene, ether, glacial acetic acid.
  • Slightly soluble in hot water, ethanol.
  • Fluoresces a bright yellow-red color.
  • Bright red, needle crystals. Turns yellow in alkaline solutions.
  • Melting Point = 263

Resources and Citations

  • H.Schweppe, J.Winter, "Madder and Alizarin", Artists Pigments, Volume 3, E. West FitzHugh (ed.), Oxford University Press: Oxford, 1997. ° R. Mayer, A Dictionary of Art Terms and Techniques, Harper and Row, New York, 1969.
  • G.S.Brady, Materials Handbook, McGraw-Hill Book Co., New York, 1971 Comment: p. 475
  • Ralph Mayer, A Dictionary of Art Terms and Techniques, Harper and Row Publishers, New York, 1969 (also 1945 printing)
  • Thomas B. Brill, Light Its Interaction with Art and Antiquities, Plenum Press, New York City, 1980
  • Artists' Pigments: A Handbook of their History and Characteristics, Elisabeth West FitzHugh, Oxford University Press, Oxford, Vol. 3, 1997 Comment: H.Schweppe, J.Winter, "Madder and Alizarin"