Sandarac

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Sandarac Spirit

Description

A pale yellow natural resin from the alerce tree Callitris quadrivalvis that is native to Australia and from the sandarac tree Tetraclinis articulata that native to northern Africa. Sandarac tears are hard and brittle with a white powdery surface due to oxidation. It forms a clear, hard film that becomes darker and redder with age. Sandarac is composed primarily of polycommunic acid (~70%) with some sandaracopimaric acid and small amounts of phenols and labdanoid compounds (Mills and White 1994). Sandarac spirit varnishes dry quickly and have been used for retouching and metal coatings. Sandarac/oil varnishes, or vernice liquida, were commonly used in the 12-15th centuries in Italy (Eastlake 1847).

Sandarac

Synonyms and Related Terms

gum sandarac; sandarach; sandarac tree (Tetraclinis articulata); alerce tree (Callitris quadrivalvis); gum juniper; Berenice; Mogador; white gum; Cyprus pine; Australian pine gum (Callitris reessii); vernice liquida

FTIR

MFA- Sandarac.jpg


Other Properties

Soluble in ethanol, ether, acetone, amyl alcohol and hot alkali.

Insoluble in water, mineral spirits and turpentine.

Saponification number = 143; Acid number = 140-155.

Melting Point 135-150
Density 1.078-1.088
Refractive Index 1.545

Additional Information

J.S. Mills, R.White, The Organic Chemistry of Museum Objects, Butterworth Heinemann, London, 1994.

Comparisons

Properties of Natural Resins


Sources Checked for Data in Record

  • R. J. Gettens, G.L. Stout, Painting Materials, A Short Encyclopaedia, Dover Publications, New York, 1966 Comment: tree = Callitris quadrivalis
  • G.S.Brady, Materials Handbook, McGraw-Hill Book Co., New York, 1971 Comment: pp. 689 and 765
  • Ralph Mayer, A Dictionary of Art Terms and Techniques, Harper and Row Publishers, New York, 1969 (also 1945 printing) Comment: tree = Callitris quadrivalis
  • Hermann Kuhn, Conservation and Restoration of Works of Art and Antiquities, Butterworths, London, 1986 Comment: tree= Tetraclinis articulata
  • Matt Roberts, Don Etherington, Bookbinding and the Conservation of Books: a Dictionary of Descriptive Terminology, U.S. Government Printing Office, Washington DC, 1982 Comment: tree= Tetraclinis articulata
  • Dictionary of Building Preservation, Ward Bucher, ed., John Wiley & Sons, Inc., New York City, 1996
  • John S. Mills, Raymond White, The Organic Chemistry of Museum Objects, Butterworth Heineman, London, 2nd ed., 1994
  • Encyclopedia Britannica, http://www.britannica.com Comment: "Sandarac." Encyclopædia Britannica. 2004. Encyclopædia Britannica Premium Service. 14 Apr. 2004 . African tree= Tetraclinis articulata; Australian tree = genus callitris
  • Paintings Specialty Group, Painting Conservation Catalog, Wendy Samet (ed.), AIC, Washington, DC, 1998