Difference between revisions of "Diphenylcarbazide"

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== Description ==
 
== Description ==
  
White crystalline powder used for the colorimetric detection of [http://cameo.mfa.org/materials/fullrecord.asp?name=chromium chromium] in metals, tanned [http://cameo.mfa.org/materials/fullrecord.asp?name=leather leather], and [http://cameo.mfa.org/materials/fullrecord.asp?name=pigments pigments] (Odegaard et al 2000). Diphenylcarbazide gives a dark blue-violet positive reaction. Other metals, such as [http://cameo.mfa.org/materials/fullrecord.asp?name=cadmium cadmium], [http://cameo.mfa.org/materials/fullrecord.asp?name=mercury mercury], [http://cameo.mfa.org/materials/fullrecord.asp?name=magnesium magnesium], [http://cameo.mfa.org/materials/fullrecord.asp?name=silver silver], [http://cameo.mfa.org/materials/fullrecord.asp?name=nickel nickel], [http://cameo.mfa.org/materials/fullrecord.asp?name=tin tin], and [http://cameo.mfa.org/materials/fullrecord.asp?name=aluminum aluminum] will also react with diphenylcarbazide.
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White crystalline powder used for the colorimetric detection of [[chromium]] in metals, tanned [[leather]], and [[pigment|pigments]] (Odegaard et al 2000). Diphenylcarbazide gives a dark blue-violet positive reaction. Other metals, such as [[cadmium]], [[mercury]], [[magnesium]], [[silver]], [[nickel]], [[tin]], and [[aluminum]] will also react with diphenylcarbazide.
 
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[[[SliderGallery rightalign|diphenylcarbazide.jpg~Chemical structure]]]
 
== Synonyms and Related Terms ==
 
== Synonyms and Related Terms ==
  
 
2,2'-diphenylcarbonic dihydrazide; 1,5-diphenylcarbazide; S-diphenylcarbazide; DPC
 
2,2'-diphenylcarbonic dihydrazide; 1,5-diphenylcarbazide; S-diphenylcarbazide; DPC
  
[[[SliderGallery rightalign|diphenylcarbazide.jpg~Chemical structure]]]
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== Risks ==
 +
 
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* Degrades in light.   
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* May be harmful by ingestion or inhalation. 
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* Contact may cause irritation. 
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* ThermoFisher: [https://www.fishersci.com/store/msds?partNumber=AC158840250&productDescription=SYM.-DIPHENYLCARBAZIDE+25GR&vendorId=VN00032119&countryCode=US&language=en SDS]
  
== Other Properties ==
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==Physical and Chemical Properties==
  
 
Slightly soluble in water.  Soluble in hot alcohol, acetone, glacial acetic acid
 
Slightly soluble in water.  Soluble in hot alcohol, acetone, glacial acetic acid
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|-
 
|-
 
! scope="row"| Melting Point
 
! scope="row"| Melting Point
| 168-171
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| 168-171 C
 
|-
 
|-
 
! scope="row"| Molecular Weight
 
! scope="row"| Molecular Weight
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|}
 
|}
  
== Hazards and Safety ==
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==Resources and Citations==
 
 
Degrades in light.   
 
 
 
May be harmful by ingestion or inhalation.  Contact may cause irritation. 
 
 
 
Mallinckrodt Baker: [http://www.jtbaker.com/msds/englishhtml/d7816.htm MSDS]
 
 
 
== Additional Information ==
 
 
 
N.Odegaard, S.Carroll, W.Zimmt, ''Material Characterization Tests for Objects of Art and Archaeology'' Archetype Publications, London, 2000, p.44.
 
 
 
== Authority ==
 
  
 
* ''The Merck Index'', Susan Budavari (ed.), Merck Research Labs, Whitehouse Station, NJ, 12th Edition, 1996  Comment: entry 3333
 
* ''The Merck Index'', Susan Budavari (ed.), Merck Research Labs, Whitehouse Station, NJ, 12th Edition, 1996  Comment: entry 3333
  
* N.Odegaard, S.Carroll, W.Zimmt, ''Material Characterization Tests for Objects of Art and Archaeology'', Archetype Publications, London, 2000
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* N.Odegaard, S.Carroll, W.Zimmt, ''Material Characterization Tests for Objects of Art and Archaeology'', Archetype Publications, London, 2000, p.44.
  
  
  
 
[[Category:Materials database]]
 
[[Category:Materials database]]

Latest revision as of 16:04, 21 July 2022

Description

White crystalline powder used for the colorimetric detection of Chromium in metals, tanned Leather, and pigments (Odegaard et al 2000). Diphenylcarbazide gives a dark blue-violet positive reaction. Other metals, such as Cadmium, Mercury, Magnesium, Silver, Nickel, Tin, and Aluminum will also react with diphenylcarbazide.

Chemical structure

Diphenylcarbazide.jpg

Synonyms and Related Terms

2,2'-diphenylcarbonic dihydrazide; 1,5-diphenylcarbazide; S-diphenylcarbazide; DPC

Risks

  • Degrades in light.
  • May be harmful by ingestion or inhalation.
  • Contact may cause irritation.
  • ThermoFisher: SDS

Physical and Chemical Properties

Slightly soluble in water. Soluble in hot alcohol, acetone, glacial acetic acid

Composition C33H14N4O
CAS 140-22-7
Melting Point 168-171 C
Molecular Weight mol. wt. = 242.27

Resources and Citations

  • The Merck Index, Susan Budavari (ed.), Merck Research Labs, Whitehouse Station, NJ, 12th Edition, 1996 Comment: entry 3333
  • N.Odegaard, S.Carroll, W.Zimmt, Material Characterization Tests for Objects of Art and Archaeology, Archetype Publications, London, 2000, p.44.