Merbromin

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Bottle of Mercurochrome

Description

An iridescent green crystalline compound composed of mercuric acetate dibromide fluorescein. Merbromin forms a red aqueous solution that fluoresces a bright yellow green. Since its discovery in 1919, merbromin was widely used as a germicide and antiseptic under the common brand name of Mercurochrome. In 1990, the U.S. banned its sale due to potential of mercury poisoning. Merbromin forms red stains that can be removed by washing first with permanganate solution and then with oxalic acid solution (Merck Index, 1996).

Synonyms and Related Terms

Mercurochrome; Merbromine; 'Monkey blood'; Asceptichrome; Cinfacromin; Supercrome orto; sodium mercurescein; mercuric acetate dibromide fluorescein; dibromohydroxymercurifluorescein disodium salt; 2,7-disodiumdibromo-4-hydroxymercurifluoescein

Chemical structure

Merbromin.jpg


Other Properties

Soluble in water to form a carmine red solution. pH (0.5% solution) = 8.8

Insoluble in ethanol, acetone, chloroform, ether.

Composition C20H8Br2HgNa2O6
CAS 129-16-8
Molecular Weight mol. wt. = 750.7

Hazards and Safety

Toxic by ingestion and inhalation. Contains mercury. Colors skin red.

Fisher Scientific: MSDS

Authority

  • Richard S. Lewis, Hawley's Condensed Chemical Dictionary, Van Nostrand Reinhold, New York, 10th ed., 1993
  • The Merck Index, Martha Windholz (ed.), Merck Research Labs, Rahway NJ, 10th edition, 1983 Comment: entry 5914
  • The American Heritage Dictionary or Encarta, via Microsoft Bookshelf 98, Microsoft Corp., 1998

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