Difference between revisions of "Mercuric chloride"
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== Description == | == Description == | ||
| − | A colorless crystalline compound that was used in the 19th and early 20th centuries as | + | A colorless crystalline compound that was used in the 19th and early 20th centuries as a [[disinfectant]], [[wood preservative]], rat poison, [[insecticide|insecticide]], and [[fungicide]] (for paper and books). Mercuric chloride was also used as an intensifier in photography, for tanning leather, for separating gold from lead, and as a paint preservative. It can react with sulfur causing black stains on paper and specimens. Mercuric chloride is highly toxic and its use is currently restricted in the United States. |
== Synonyms and Related Terms == | == Synonyms and Related Terms == | ||
mercury chloride; mercury bichloride; corrosive sublimate; mercury perchloride; corrosive sublimate; mercury (II) chloride | mercury chloride; mercury bichloride; corrosive sublimate; mercury perchloride; corrosive sublimate; mercury (II) chloride | ||
| + | == Risks == | ||
| − | == | + | * Violent poison, can be fatal in minutes with ingestion of 0.5 grams. |
| + | * Toxic by ingestion, and inhalation. | ||
| + | * Corrosive to eyes, skin and lungs. Biohazard. | ||
| + | * Egg white is used as an antidote. | ||
| + | * ThermoFisher: [https://www.fishersci.com/store/msds?partNumber=AC201430250&productDescription=MERCURY%28II%29CHLORIDE%2C+P.+25GRM&vendorId=VN00032119&countryCode=US&language=en SDS] | ||
| + | |||
| + | == Physical and Chemical Properties == | ||
Soluble in water, ethanol, ether, methanol, acetone, ethyl acetate, glycerol, and acetic acid. Slightly soluble in carbon disulfide, benzene, and pyridine. Incompatible with alkalis, metals and proteins. | Soluble in water, ethanol, ether, methanol, acetone, ethyl acetate, glycerol, and acetic acid. Slightly soluble in carbon disulfide, benzene, and pyridine. Incompatible with alkalis, metals and proteins. | ||
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! scope="row"| Melting Point | ! scope="row"| Melting Point | ||
| − | | 276-277 | + | | 276-277 C |
|- | |- | ||
! scope="row"| Density | ! scope="row"| Density | ||
| − | | 5.4 | + | | 5.4 g/ml |
|- | |- | ||
! scope="row"| Molecular Weight | ! scope="row"| Molecular Weight | ||
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|- | |- | ||
! scope="row"| Boiling Point | ! scope="row"| Boiling Point | ||
| − | | 302 | + | | 302 C |
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| − | = | + | = Resources and Citations == |
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| − | + | * C.Hawks, D.Bell, "Removal of Stains Caused by Mercuric Chloride Treatments from Herbarium Sheet Labels" in ICOM Preprints, Lyon, 1999. p. 723-727. | |
* G.S.Brady, ''Materials Handbook'', McGraw-Hill Book Co., New York, 1971 Comment: p. 502 | * G.S.Brady, ''Materials Handbook'', McGraw-Hill Book Co., New York, 1971 Comment: p. 502 | ||
Latest revision as of 13:29, 18 October 2022
Description
A colorless crystalline compound that was used in the 19th and early 20th centuries as a Disinfectant, Wood preservative, rat poison, Insecticide, and Fungicide (for paper and books). Mercuric chloride was also used as an intensifier in photography, for tanning leather, for separating gold from lead, and as a paint preservative. It can react with sulfur causing black stains on paper and specimens. Mercuric chloride is highly toxic and its use is currently restricted in the United States.
Synonyms and Related Terms
mercury chloride; mercury bichloride; corrosive sublimate; mercury perchloride; corrosive sublimate; mercury (II) chloride
Risks
- Violent poison, can be fatal in minutes with ingestion of 0.5 grams.
- Toxic by ingestion, and inhalation.
- Corrosive to eyes, skin and lungs. Biohazard.
- Egg white is used as an antidote.
- ThermoFisher: SDS
Physical and Chemical Properties
Soluble in water, ethanol, ether, methanol, acetone, ethyl acetate, glycerol, and acetic acid. Slightly soluble in carbon disulfide, benzene, and pyridine. Incompatible with alkalis, metals and proteins.
| Composition | HgCl2 |
|---|---|
| CAS | 7487-94-7 |
| Melting Point | 276-277 C |
| Density | 5.4 g/ml |
| Molecular Weight | mol. wt. = 271.52 |
| Refractive Index | 1.725, 1.859, 1.965 |
| Boiling Point | 302 C |
Resources and Citations =
- C.Hawks, D.Bell, "Removal of Stains Caused by Mercuric Chloride Treatments from Herbarium Sheet Labels" in ICOM Preprints, Lyon, 1999. p. 723-727.
- G.S.Brady, Materials Handbook, McGraw-Hill Book Co., New York, 1971 Comment: p. 502
- Richard S. Lewis, Hawley's Condensed Chemical Dictionary, Van Nostrand Reinhold, New York, 10th ed., 1993
- Michael McCann, Artist Beware, Watson-Guptill Publications, New York City, 1979
- Matt Roberts, Don Etherington, Bookbinding and the Conservation of Books: a Dictionary of Descriptive Terminology, U.S. Government Printing Office, Washington DC, 1982
- The Merck Index, Martha Windholz (ed.), Merck Research Labs, Rahway NJ, 10th edition, 1983 Comment: entry 5926
- CRC Handbook of Chemistry and Physics, Robert Weast (ed.), CRC Press, Boca Raton, Florida, v. 61, 1980 Comment: ref. index=1.725, 1.859, 1.965