Polyacrylonitrile

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Infrared spectrum of Creslan acrylic fiber

Description

A polymer made from the addition polymerization of acrylonitrile. Polyacrylonitrile was first made in the late 1930s and it quickly became an important types of synthetic synthetic rubber. During W.W.II, polyacrylonitrile was made into fibers for military use. After the war, DuPont began to commercially produce acrylonitrile fibers under the brand name of Orlon in 1950. Initially all acrylonitrile fibers were called acrylic fibers. As processing variations developed, the FTC divided the types of fibers into the following two classes:

- Acrylic fibers - contain at least 85% acrylonitrile units

- Modacrylic fibers - contain 35-85 % acrylonitrile units. Pure polyacrylonitrile is also used for moldings, shoe soling and wall panels.

See fiber acrylic fiber, and fiber modacrylic fiber.

Synonyms and Related Terms

PAN; poliacrilonitrilo (Esp.); polyacrylonitrile (Fr.); poliacrilonitrile (It.); poliacrilonitrilo (Port.); polyvinyl cyanide

Examples: Fiber A; Orlon [DuPont]; Acrilan [Solutia]; Dynel [Union Carbide]; Courtelle [Courtaulds];

Other Properties

Soluble in dimethylformamide, dimethylsulfoxide. Insoluble in alcohols, diethyl ether, water, hydrocarbons.

Density 1.14-1.17

Additional Information

G.Cook, Handbook of Textile Fibres:II. Man-made Fibres, 5th edition, Merrow Publishing Co., Durham, England, 1984, p393.

Comparisons

Properties of Synthetic Fibers


Authority

  • Theodore J. Reinhart, Theodore J. Reinhart, 'Glossary of Terms', Engineered Plastics, ASM International, 1988
  • Richard S. Lewis, Richard S. Lewis, Hawley's Condensed Chemical Dictionary, Van Nostrand Reinhold, New York, 10th ed., 1993
  • Pam Hatchfield, Pam Hatchfield, Pollutants in the Museum Environment, Archetype Press, London, 2002
  • Random House, Random House, Webster's Encyclopedic Unabridged Dictionary of the English Language, Grammercy Book, New York, 1997
  • J.Gordon Cook, J.Gordon Cook, Handbook of Textile Fibres:II Man-made Fibres, Merrow Publishing Co. , Durham, England

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