Shellac

From CAMEO
Revision as of 15:51, 30 May 2022 by MDerrick (talk | contribs) (→‎Physical and Chemical Properties)
(diff) ← Older revision | Latest revision (diff) | Newer revision → (diff)
Jump to navigation Jump to search
Lacquer base of shellac and red ocher; MFA# 1991.444

Description

Shellaced paper
MFA# 1992.206

A resinous substance excreted by the female of the lac insect, Laccifer lacca, native to India. The insects primarily deposit lac on the twigs and soft new branches of several varieties of soapberry and acacia trees, such as the sacred fig, Ficus religiosa, found in India, Thailand, Myanmar (Burma), and elsewhere in southeast Asia. Lac was used as early as about 1200 BCE in India. Shellac and Lac dye were imported to Europe in the 17th century. The resin coated twigs, also called sticklac, undergoes several processing steps to extract useful components. The raw lac is washed, heated and drawn out into thin sheets. Once cooled, the shellac is broken into small flakes for sale as flake shellac. The color of shellac ranges from a pale yellow to a deep red. Shellac is soluble in alcohol and is used to obtain the high gloss on French polished furniture. It is also used as a protective coating for plaster molds and casts. In the 19th century, shellac was filled with wood flour and used for molded composition products such as buttons, picture frames, Daguerreotype and Ambrotype cases, and gramophone records. Black pigmented, mineral-filled shellac was used for 78 rpm phonograph records, mirror frames, brooches, and dressing table sets. Shellac was often adulterated with Rosin (Doerner 1934).

Shellac-based picture frame

Synonyms and Related Terms

Laccifer lacca (also listed as Coccus lacca); Ficus religiosa; gomme laque (Fr.); Schellack (Deut.); Tafellack (Deut.); Plattlack (Deut.); goma laca (Esp.); gommalacca (It); schellack (Ned.); Lacca in tabulis (Deut.); lac; lacca; shell lacca; shell-lacca; gum lac; bleached shellac; lemon flakes; orange flakes; garnet lac; refined shellac; kiri; black buttonlac; buttonlac; sticklac; stick-lac; seedlac; kusmi; katki; kusmi; shellack; Diatite; Smiths Patent American Composition

Applications

  • Coating
  • Natural plastic

Risks

FTIR(MFA)

Shellac, Orange, Gettens 100.A17.TIF

Moisture can produce a white haze in a shellac finish.

Physical and Chemical Properties

  • Fresh shellac is soluble in ethanol, acetone. Shellac becomes insoluble with age.
  • Insoluble in water, turpentine or mineral spirit.
  • Iodine number = 10-18
  • Saponification number = 185-213
  • Acid number = 48-64
  • Autofluoresces orange: shade depends on initial color of shellac
Melting Point 115-120 C
Density 1.035-1.140 g/ml
Refractive Index 1.516

Comparisons

Properties of Natural Resins

Additional Images

Resources and Citations

  • K.Wehlte, The Materials and Techniques of Painting, Van Nostrand Reinhold Co., New York, 1975.
  • G.S.Brady, Materials Handbook, McGraw-Hill Book Co., New York, 1971 Comment: p. 705
  • Ralph Mayer, A Dictionary of Art Terms and Techniques, Harper and Row Publishers, New York, 1969 (also 1945 printing)
  • Richard S. Lewis, Hawley's Condensed Chemical Dictionary, Van Nostrand Reinhold, New York, 10th ed., 1993
  • Matt Roberts, Don Etherington, Bookbinding and the Conservation of Books: a Dictionary of Descriptive Terminology, U.S. Government Printing Office, Washington DC, 1982
  • Dictionary of Building Preservation, Ward Bucher, ed., John Wiley & Sons, Inc., New York City, 1996
  • The Merck Index, Martha Windholz (ed.), Merck Research Labs, Rahway NJ, 10th edition, 1983 Comment: entry 8623
  • Pam Hatchfield, Pollutants in the Museum Environment, Archetype Press, London, 2002
  • Thomas B. Brill, Light Its Interaction with Art and Antiquities, Plenum Press, New York City, 1980 Comment: ref. index = 1.516
  • Susan E. Schur, Conservation Terminology: A review of Past & Current Nomenclature of Materials, Technology and Conservation, Spring (p.34-39); Summer (p.35-38); Fall (p.25-36), 1985
  • Website: www.nswpmith.com.au/historyofplastics.html