Generic table of caulking materials

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Description

Any material used to fill or seal joints and openings. Many names have been used historically and commercially for these materials including:

  • caulking (noun); caulk (verb); calking (sp); cauking (sp.); sealant; putty; spackle

For this database, the term 'Caulking' will be used. This table tries to include most types of materials that have been used. For a specific comparison of commercial products, please see: Comparison of commercial caulking materials.


Caulk/putty Earliest use Composition Examples Applications Characteristics and Risks
Fibers/Wood ancient times boats
Wax ancient times vessels becomes soft with heat
Tar ancient times boats
Oil-based caulk (sometimes lead-based putty) 19th-20th c. 10-15% Linseed oil with Calcium carbonate, red or White lead and sometimes other inorganic fillers (Talc, Alum, Asbestos) Seal window to frame, fill defects in wood and metal; surround pipe joint Lead compounds accelerate drying; some components are toxic
Cement putty Concrete mortar
Gesso putty Gelatin with Chalk
Rubber (natural, vulcanized) 19th c to WWII gaskets, shock mounts, waterproof, can crack due to ozone
Polysulfide 1950s Any synthetic rubber vulcanized with sulfur (styrene-butadiene, Polyisoprene) Neoprene, Thiokol o-rings, pipe linings, building joints, and as sealants to fill joints in pavements, and glass/metal connections. may release sulfur; may contain PCBs; poor tensile strength; abrade easily; replaced in 1980s by silicone and urethane sealants
Butyl rubber 1950s Isobutylene-isoprene, talc, calcium carbonate, mineral spirits, adhesion promoters primarily used outdoors for metal and masonry joints that may expand and contract (gutters) sticky and messy, but more resistant to sunlight than natural rubbers; combustible; paintable
Acrylic (solvent-based) 1958 solvent cured acrylic resin with calcium carbonate, silica, solvent and plasticizer.
Silicone 1960s silicone resin cured with moisture or peroxides; may contain fumed silica, calcium carbonate, ground quartz, carbon black, talc, plasticizers, acetone,, methylene chloride. Silastic, Clear Museum Gel used around plumbing fixtures; to caulk joints in bathroom tiles; seal gap on exterior walls/roofs around pipes and wirings water-repellent; long-life; wide temperature range; mold/mildew resistant; not paintable; poor adhesion; may release acetic acid or methanol on cure; may have residual curing compounds and silicone oils; may stain porous materials; some silicone caulks contain latex making them paintable but less durable
Polyurethane elastomers Polyurethane cured with moisture; calcium carbonate, titanium dioxide, aromatic naphthas and petroleum distillates; Vulkem primarily used for sealing cracks and expansion joints in driveways and other outdoor concrete surfaces. It's also suitable for filling and repairing cracks in masonry-stucco walls. very durable; abrasion resistant; flexible at low temperatures; combustible producing toxic fumes; may release acetic acid on curing, aging, or deterioration; susceptible to hydrolysis that may decrease adhesion
Vinyl latex late 1960s Vinyl (Polyvinyl acetate) with calcium carbonate, plasticizers Reprosil fill small gaps and blemishes in wood trim prior to painting inexpensive; may be painted and used outdoors; may evolve trace acetic acid as it cures
Acrylic latex Butyl methacrylate, calcium carbonate, water Flugger fill small gaps and blemishes in wood trim prior to painting inexpensive, fast-drying, and paintable; minimal shrinkage; used indoors

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