Aureolin

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Aureolin

Contents

Description

A brilliant, transparent yellow pigment also known by the name cobalt yellow. Cobalt yellow is composed of potassium cobaltinitrite. It was discovered by N.W. Fischer in Germany in 1848. Cobalt yellow was introduced as an artists' pigment in 1852 (Saint-Evre) and began selling commercially in the U.S. in 1861. Aureolin is a permanent pigment, but may discolor to brown when mixed with indigo in the presence of hydrogen sulfide. Because of its poor hiding power, cobalt yellow is most often used in watercolor and tempera paints, for oil-based glazes and as a colorant in glass.

Synonyms and Related Terms

cobalt yellow; potassium cobaltinitrite; Pigment Yellow 40; CI 77357; Kobaltgelb (Deut.); aureolina (Esp.); jaune de cobalt (Fr.); giallo di cobalto (It.); aureolina (It.); amarillo de cobalto (Esp.)

Raman

CobaltylUCL.jpg

FTIR

MFA- Aureolin.jpg

FTIR

AureolinRoberson.jpg

FTIR

AureolinRoberson.jpg

XRD

PIG342.jpg

SEM

F342sem.jpg

EDS

F342edsbw.jpg

XRF

Slide9 FC342.PNG


Other Properties

Slightly soluble in water, ethanol, ether and carbon disulfide. Soluble in acids producing a pink solution. Decomposes in alkalis evolving nitrogen oxide fumes.

Composition K3[Co(NO2)6].3H2O
CAS 13782-01-9
Density 1.8
Refractive Index 1.72 - 1.76

Hazards and Safety

Ingestion may cause poisoning with decreased blood pressure, headaches, nausea, vomiting and cyanosis.

Additional Information

° M.Cornman, "Cobalt Yellow", Artists Pigments, Volume 1, R. Feller (ed.), Cambridge University Press; Cambridge, 1986.

° Pigments Through the Ages: Cobalt yellow

Additional Images


Sources Checked for Data in Record

  • The Dictionary of Art, Grove's Dictionaries Inc., New York, 1996 Comment: Artists Pigments
  • R. J. Gettens, G.L. Stout, Painting Materials, A Short Encyclopaedia, Dover Publications, New York, 1966
  • Ralph Mayer, A Dictionary of Art Terms and Techniques, Harper and Row Publishers, New York, 1969 (also 1945 printing)
  • Reed Kay, The Painter's Guide To Studio Methods and Materials, Prentice-Hall, Inc., Englewood Cliffs, NJ, 1983
  • Michael McCann, Artist Beware, Watson-Guptill Publications, New York City, 1979
  • Susan E. Schur, Conservation Terminology: A review of Past & Current Nomenclature of Materials, Technology and Conservation, Spring (p.34-39); Summer (p.35-38); Fall (p.25-36), 1985
  • Book and Paper Group, Paper Conservation Catalog, AIC, 1984, 1989

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