Lead white

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Lead white

Contents

Description

A white pigment composed of basic lead carbonate. Lead white (lead hydroxycarbonate), contains about 70% lead carbonate and 30% lead hydroxide chemically combined. Basic lead carbonate occurs in nature as the mineral hydrocerussite, but the mineral form was not commonly used as a pigment; instead lead white has been prepared synthetically from Classical antiquity by exposing metallic lead to vinegar (acetic acid) vapour. Lead acetate forms first, and this then reacts with carbon dioxide from the atmosphere (or from another source). Lead white is a dense, opaque pigment that was mainly used in drying oils where it acts as a siccative. It has also been found in egg tempera, glue tempera, and gum tempera, but it was not considered suitable for buon fresco techniques. Lead white was the principal white pigment used in paintings and ceramic glazes from ancient times until the 20th century. Lead white has been replaced as paint pigment by zinc white and titanium white, but it can still be found in some exterior paints and ceramic glazes. It was commonly used in house paints till the middle of the 20th century. In the United States, its use in interior paints was restricted in the 1950s and prohibited in 1978. Lead white can yellow or blacken in the presence of sulfides or alkalis, and it can be oxidized by microorganisms to form brownish-black lead dioxide. Cremnitz white is a very white, dense type of white lead prepared from litharge and acetic acid. Occasionally the name lead white has also been used for basic lead sulfate and basic lead silicate.

Lead white

Synonyms and Related Terms

basic lead carbonate; Pigment White 1; CI 77597; hydrocerussite (mineral); plomo blanco (Esp.); céruse (Fr.); blanc de plomb (Fr.); blanc d'argent (Fr.); Bleiweiss (Deut.); Kremserweiss (Deut.); leyko toy molybdoy (Gr.); psimythio (Gr.); ydrokeroyssitis (Gr.)bianco di piombo (It.); biacca (It.); cerussa (It.); loodwit (Ned.); branco de chumbo (Port.); enpaku (Jap.); bai (Chin.); Flemish white; Vienna white; Berlin white; slate white; Roman white; flake white; Cremnitz white; white lead; London white; silver white; Krems white; Dutch white lead

Raman

LeadwhitUCL.jpg

Raman

Leadwhite632.jpg

FTIR

MFA- Lead white.jpg

XRD

PIG523.jpg

SEM

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EDS

F523edsbw.jpg

Chemical structure

Lead white.jpg


Other Properties

Dissolves in acids, giving off carbon dioxide. Insoluble in water and ethanol. Fluoresces reddish purple. Pigment has fine, fairly uniform, rounded tabular particles. Converts to yellow lead oxide (massicot) with moderate heat and to red lead oxide at higher temperatures.

Composition 2PbCO3.Pb(OH)2
CAS 1319-46-6
Density 6.70-6.86
Molecular Weight mol. wt. = 775.62
Refractive Index e=1.94; w=2.09

Hazards and Safety

Toxic by inhalation or ingestion. Skin contact may cause irritation or ulcers. Carcinogen, teratogen, suspected mutagen.

It's use in interior house paints in the U.S. was prohibited in 1978.

Darkens with exposure to sulfur and alkalis. Susceptible to biological degradation.

Mallinckrodt Baker: MSDS

Additional Information

° R.J.Gettens, H. Kuhn, and W.T. Chase, "Lead White", Artists Pigments, Volume 2, A. Roy (ed.), Oxford University Press: Oxford, 1993.Record content reviewed by EU-Artech, November 2007.

Comparisons

Characteristics of Common White Pigments


Additional Images


Sources Checked for Data in Record

  • External source or communication Comment: Submitted information: Ashok Roy, November 2007.
  • Artists' Pigments: A Handbook of their History and Characteristics, Ashok Roy (ed.), National Gallery of Art, Washington DC, Vol. 2, 1993 Comment: R.J.Gettens, H. Kuhn, and W.T. Chase, "Lead White", ref. index = 1.94; 2.09
  • R. J. Gettens, G.L. Stout, Painting Materials, A Short Encyclopaedia, Dover Publications, New York, 1966 Comment: density = 6.70 and ref.index.= 1.94; 2.09
  • Reed Kay, The Painter's Guide To Studio Methods and Materials, Prentice-Hall, Inc., Englewood Cliffs, NJ, 1983
  • Ralph Mayer, A Dictionary of Art Terms and Techniques, Harper and Row Publishers, New York, 1969 (also 1945 printing)
  • R.D. Harley, Artists' Pigments c. 1600-1835, Butterworth Scientific, London, 1982
  • Dictionary of Building Preservation, Ward Bucher, ed., John Wiley & Sons, Inc., New York City, 1996
  • The Dictionary of Art, Grove's Dictionaries Inc., New York, 1996 Comment: 'Pigments'
  • Michael McCann, Artist Beware, Watson-Guptill Publications, New York City, 1979
  • R. Newman, E. Farrell, 'House Paint Pigments', Paint in America , R. Moss ed., Preservation Press, New York City, 1994
  • Thomas B. Brill, Light Its Interaction with Art and Antiquities, Plenum Press, New York City, 1980
  • R.Feller, M.Curran, C.Bailie, 'Identification of Traditional Organic Colorants Employed in Japanese Prints and Determination of their Rates of Fading', Japanese Woodblock Prints, Allen Memorial Art Museum, Oberlin College, Oberlin, 1984
  • Susan E. Schur, Conservation Terminology: A review of Past & Current Nomenclature of Materials, Technology and Conservation, Spring (p.34-39); Summer (p.35-38); Fall (p.25-36), 1985
  • Book and Paper Group, Paper Conservation Catalog, AIC, 1984, 1989
  • MSDS Sheet Comment: Baker MSDS Spec gravity = 6.14

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