Viridian

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Viridian

Contents

Description

A permanent green pigment composed of hydrated chromium oxide. Viridian is a synthetic pigment with characteristic deep green, transparent particles which are unaffected by light and chemicals. The process for making the hydrated form of chromium oxide was discovered in 1838 by Pannetier in Paris. A less expensive method for manufacturing viridian was patented by Guignet in 1859. Viridian, though not extremely popular because of its high price, was used as a pigment in all types of binding media. The stable pigment is also used as a colorant in concrete mixtures, rubber, inks, and automotive paints.

Viridian

Synonyms and Related Terms

chromium oxide hydrate; Pigment Green 18; CI 77289; transparent chrome oxide; vert émeraude (Fr.); Chromoxidhydratgrün (Deut.); Veridian (Deut); viridiana (Esp.); verde smeraldo (It.); viridiaan (Ned.); viridian (Port.); chromium oxide green transparent; chromium oxide dihydrate; French Veronese green; Pannetier's green; Mittlers' green; Guignet's green; Casali's green

Raman

ViridianUCL.jpg

Raman

Viridian632.jpg

FTIR

MFA- Chromium oxide green.jpg

SEM

F412sem.jpg

EDS

F412edsbw.jpg

Chemical structure

Viridian.jpg


Other Properties

Particle size irregular (0.07 - 20 micrometers). Resistant to acids and alkalis. Irregular undulose extinction in polarized light. Bright green birefringent particles.

Composition Cr2O3.2H2O
CAS 1308-38-9
Melting Point 2435
Density 3.32
Refractive Index 1.62; 2.12
Boiling Point 4000

Hazards and Safety

Mallinckrodt Baker: MSDS

Additional Information

° R. Newman, "Chromium Oxide Greens", Artists Pigments, Volume 3, E. West FitzHugh (ed.), Oxford University Press: Oxford, 1997. ° Pigments Through the Ages: Viridian

Additional Images


Sources Checked for Data in Record

  • Artists' Pigments: A Handbook of their History and Characteristics, Elisabeth West FitzHugh, Oxford University Press, Oxford, Vol. 3, 1997 Comment: R. Newman, "Chromium Oxide Greens"
  • The Dictionary of Art, Grove's Dictionaries Inc., New York, 1996 Comment: "Pigments"
  • R. J. Gettens, G.L. Stout, Painting Materials, A Short Encyclopaedia, Dover Publications, New York, 1966 Comment: p. 173
  • Ralph Mayer, A Dictionary of Art Terms and Techniques, Harper and Row Publishers, New York, 1969 (also 1945 printing)
  • Thomas B. Brill, Light Its Interaction with Art and Antiquities, Plenum Press, New York City, 1980
  • R.D. Harley, Artists' Pigments c. 1600-1835, Butterworth Scientific, London, 1982
  • Random House, Webster's Encyclopedic Unabridged Dictionary of the English Language, Grammercy Book, New York, 1997
  • The American Heritage Dictionary or Encarta, via Microsoft Bookshelf 98, Microsoft Corp., 1998

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