Difference between revisions of "Malathion"

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[[File:malathionir.jpg|thumb|Infrared spectrum of malathion]]
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[[File:malathionms.jpg|thumb|Mass spectrum of malathion]]
 
== Description ==
 
== Description ==
  
 
A dark yellow liquid that is used as an [http://cameo.mfa.org/materials/fullrecord.asp?name=insecticide insecticide]. Malathion is an organophosphate compound that acts as a cholinesterase inhibitor. It has an unpleasant, [http://cameo.mfa.org/materials/fullrecord.asp?name=sulfur sulfur] type odor and can be corrosive to [http://cameo.mfa.org/materials/fullrecord.asp?name=iron iron]. Malathion has been used for control of [http://cameo.mfa.org/materials/fullrecord.asp?name=cockroach cockroaches], treatment of head lice, and the aerial spraying to eradicate the Mediterranean fruit fly. Malathion biodegrades to form nontoxic compounds.
 
A dark yellow liquid that is used as an [http://cameo.mfa.org/materials/fullrecord.asp?name=insecticide insecticide]. Malathion is an organophosphate compound that acts as a cholinesterase inhibitor. It has an unpleasant, [http://cameo.mfa.org/materials/fullrecord.asp?name=sulfur sulfur] type odor and can be corrosive to [http://cameo.mfa.org/materials/fullrecord.asp?name=iron iron]. Malathion has been used for control of [http://cameo.mfa.org/materials/fullrecord.asp?name=cockroach cockroaches], treatment of head lice, and the aerial spraying to eradicate the Mediterranean fruit fly. Malathion biodegrades to form nontoxic compounds.
  
[[File:malathionms.jpg|thumb|Mass spectrum of malathion]]
 
 
== Synonyms and Related Terms ==
 
== Synonyms and Related Terms ==
  
 
S-[1,2-bis(ethoxycarbonyl)ethyl]O,O-dimethylphosphorodithioate; carbofos; mercaptothion; [(dimethoxyphosphinothioyl)thio]butanedioic acid diethyl ester; insecticide no. 4049; Cythion [American Cyanamid]
 
S-[1,2-bis(ethoxycarbonyl)ethyl]O,O-dimethylphosphorodithioate; carbofos; mercaptothion; [(dimethoxyphosphinothioyl)thio]butanedioic acid diethyl ester; insecticide no. 4049; Cythion [American Cyanamid]
  
[[[SliderGallery rightalign|malathionstr.jpg~Chemical structure]]]
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[[[SliderGallery rightalign|malathionir.jpg~FTIR|malathionstr.jpg~Chemical structure]]]
  
 
== Other Properties ==
 
== Other Properties ==
Line 48: Line 47:
 
== Additional Information ==
 
== Additional Information ==
  
L. Zycherman and J.R. Schrock, ''A Guide to Museum Pest Control'', FAIC,  Washington, DC, 1988. J.Dawson, "Solving Museum Insect Problems: Chemical  Control" CCI Technical Bulletin No. 15.
+
° L. Zycherman and J.R. Schrock, ''A Guide to Museum Pest Control'', FAIC,  Washington, DC, 1988. ° J.Dawson, "Solving Museum Insect Problems: Chemical  Control" CCI Technical Bulletin No. 15.
  
 
== Authority ==
 
== Authority ==
  
* Richard S. Lewis, Richard S. Lewis, ''Hawley's Condensed Chemical Dictionary'', Van Nostrand Reinhold, New York, 10th ed., 1993
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* Richard S. Lewis, ''Hawley's Condensed Chemical Dictionary'', Van Nostrand Reinhold, New York, 10th ed., 1993
  
 
* ''The Merck Index'', Martha Windholz (ed.), Merck Research Labs, Rahway NJ, 10th edition, 1983  Comment: entry # 5740
 
* ''The Merck Index'', Martha Windholz (ed.), Merck Research Labs, Rahway NJ, 10th edition, 1983  Comment: entry # 5740
  
* Lynda A. Zycherman, J.Richard Schrock, Lynda A. Zycherman, J.Richard Schrock, ''A Guide to Museum Pest Control'', FAIC and Association of Systematics Collections, Washington DC, 1988
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* Lynda A. Zycherman, J.Richard Schrock, ''A Guide to Museum Pest Control'', FAIC and Association of Systematics Collections, Washington DC, 1988
  
* J. Dawson, J. Dawson, ''CCI Technical Bulletin'', 'Solving Museum Insect Problems: Chemical Control' , Canadian Conservation Institute, Ottawa, No. 15
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* J. Dawson, ''CCI Technical Bulletin'', 'Solving Museum Insect Problems: Chemical Control' , Canadian Conservation Institute, Ottawa, No. 15
  
* Pam Hatchfield, Pam Hatchfield, ''Pollutants in the Museum Environment'', Archetype Press, London, 2002
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* Pam Hatchfield, ''Pollutants in the Museum Environment'', Archetype Press, London, 2002
  
* G.Caneva, M.P.Nugari, O.Salvadori, G.Caneva, M.P.Nugari, O.Salvadori, ''Biology in the Conservation of Works of Art'', ICCROM, Rome, 1991
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* G.Caneva, M.P.Nugari, O.Salvadori, ''Biology in the Conservation of Works of Art'', ICCROM, Rome, 1991
  
  
  
 
[[Category:Materials database]]
 
[[Category:Materials database]]

Revision as of 06:31, 24 July 2013

Mass spectrum of malathion

Description

A dark yellow liquid that is used as an insecticide. Malathion is an organophosphate compound that acts as a cholinesterase inhibitor. It has an unpleasant, sulfur type odor and can be corrosive to iron. Malathion has been used for control of cockroaches, treatment of head lice, and the aerial spraying to eradicate the Mediterranean fruit fly. Malathion biodegrades to form nontoxic compounds.

Synonyms and Related Terms

S-[1,2-bis(ethoxycarbonyl)ethyl]O,O-dimethylphosphorodithioate; carbofos; mercaptothion; [(dimethoxyphosphinothioyl)thio]butanedioic acid diethyl ester; insecticide no. 4049; Cythion [American Cyanamid]

FTIR

Malathionir.jpg

Chemical structure

Malathionstr.jpg


Other Properties

Miscible with alcohols, ketones, ether, aromatic hydrocarbons and oils. Slightly soluble in water. Decomposes with acids or bases to produce sulfur compounds.

Composition C10H19O6PS2
CAS 121-75-5
Melting Point 2.9
Density 1.23
Molecular Weight mol. wt. = 330.4
Boiling Point 156-157

Hazards and Safety

Relatively low toxicity for mammals. Overexposure through inhalation and skin absorption can causes irritation and/or vision/breathing problems. LD50=2800 mg/kg

Potential teratogen. Combustible.

Corrodes iron, steel, tin, lead, and copper. May discolor organic red dyes.

LINK: International Chemical Safety Card

Additional Information

° L. Zycherman and J.R. Schrock, A Guide to Museum Pest Control, FAIC, Washington, DC, 1988. ° J.Dawson, "Solving Museum Insect Problems: Chemical Control" CCI Technical Bulletin No. 15.

Authority

  • Richard S. Lewis, Hawley's Condensed Chemical Dictionary, Van Nostrand Reinhold, New York, 10th ed., 1993
  • The Merck Index, Martha Windholz (ed.), Merck Research Labs, Rahway NJ, 10th edition, 1983 Comment: entry # 5740
  • Lynda A. Zycherman, J.Richard Schrock, A Guide to Museum Pest Control, FAIC and Association of Systematics Collections, Washington DC, 1988
  • J. Dawson, CCI Technical Bulletin, 'Solving Museum Insect Problems: Chemical Control' , Canadian Conservation Institute, Ottawa, No. 15
  • Pam Hatchfield, Pollutants in the Museum Environment, Archetype Press, London, 2002
  • G.Caneva, M.P.Nugari, O.Salvadori, Biology in the Conservation of Works of Art, ICCROM, Rome, 1991

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