Difference between revisions of "Sodium dithionite"

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== Description ==
 
== Description ==
  
Pale yellow powder that is used as a [http://cameo.mfa.org/materials/fullrecord.asp?name=reducing agent reducing agent] in dyeing [http://cameo.mfa.org/materials/fullrecord.asp?name=indigo indigo] and [http://cameo.mfa.org/materials/fullrecord.asp?name=vat dye vat dyes]. Sodium dithionite is also used to strip dyes from dyed textiles and reduce [http://cameo.mfa.org/materials/fullrecord.asp?name=iron stain iron oxide stains] to [http://cameo.mfa.org/materials/fullrecord.asp?name=ferrous oxide ferrous oxide]. Sodium dithionite was also used as a [http://cameo.mfa.org/materials/fullrecord.asp?name=bleaching agent bleach] for [http://cameo.mfa.org/materials/fullrecord.asp?name=leather leather] and [http://cameo.mfa.org/materials/fullrecord.asp?name=mechanical wood pulp mechanical paper pulps] but its use has declined in recent years due to poor color reversion properties (AIC Book and Paper Catalog).  
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Pale yellow powder that is used as a [http://cameo.mfa.org/materials/fullrecord.asp?name=reducing%20agent reducing agent] in dyeing [http://cameo.mfa.org/materials/fullrecord.asp?name=indigo indigo] and [http://cameo.mfa.org/materials/fullrecord.asp?name=vat%20dye vat dyes]. Sodium dithionite is also used to strip dyes from dyed textiles and reduce [http://cameo.mfa.org/materials/fullrecord.asp?name=iron%20stain iron oxide stains] to [http://cameo.mfa.org/materials/fullrecord.asp?name=ferrous%20oxide ferrous oxide]. Sodium dithionite was also used as a [http://cameo.mfa.org/materials/fullrecord.asp?name=bleaching%20agent bleach] for [http://cameo.mfa.org/materials/fullrecord.asp?name=leather leather] and [http://cameo.mfa.org/materials/fullrecord.asp?name=mechanical%20wood%20pulp mechanical paper pulps] but its use has declined in recent years due to poor color reversion properties (AIC Book and Paper Catalog).  
  
Note: this is not the same compound as [http://cameo.mfa.org/materials/fullrecord.asp?name=sodium thiosulfate sodium thiosulfate] (Na2S2O3; also called sodium hyposulfite) that is used for fixation in photography.
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Note: this is not the same compound as [http://cameo.mfa.org/materials/fullrecord.asp?name=sodium%20thiosulfate sodium thiosulfate] (Na2S2O3; also called sodium hyposulfite) that is used for fixation in photography.
  
 
== Synonyms and Related Terms ==
 
== Synonyms and Related Terms ==
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== Authority ==
 
== Authority ==
  
* G.S.Brady, G.S.Brady, ''Materials Handbook'', McGraw-Hill Book Co., New York, 1971  Comment: p. 786
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* G.S.Brady, ''Materials Handbook'', McGraw-Hill Book Co., New York, 1971  Comment: p. 786
  
* Richard S. Lewis, Richard S. Lewis, ''Hawley's Condensed Chemical Dictionary'', Van Nostrand Reinhold, New York, 10th ed., 1993
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* Richard S. Lewis, ''Hawley's Condensed Chemical Dictionary'', Van Nostrand Reinhold, New York, 10th ed., 1993
  
* Matt Roberts, Don Etherington, Matt Roberts, Don Etherington, ''Bookbinding and the Conservation of Books: a Dictionary of Descriptive Terminology'', U.S. Government Printing Office, Washington DC, 1982
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* Matt Roberts, Don Etherington, ''Bookbinding and the Conservation of Books: a Dictionary of Descriptive Terminology'', U.S. Government Printing Office, Washington DC, 1982
  
* Book and Paper Group, Book and Paper Group, ''Paper Conservation Catalog'', AIC, 1984, 1989
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* Book and Paper Group, ''Paper Conservation Catalog'', AIC, 1984, 1989
  
 
* ''The Dictionary of Paper'', American Paper Institute, New York, Fourth Edition, 1980
 
* ''The Dictionary of Paper'', American Paper Institute, New York, Fourth Edition, 1980

Revision as of 06:34, 24 July 2013

Description

Pale yellow powder that is used as a reducing agent in dyeing indigo and vat dyes. Sodium dithionite is also used to strip dyes from dyed textiles and reduce iron oxide stains to ferrous oxide. Sodium dithionite was also used as a bleach for leather and mechanical paper pulps but its use has declined in recent years due to poor color reversion properties (AIC Book and Paper Catalog).

Note: this is not the same compound as sodium thiosulfate (Na2S2O3; also called sodium hyposulfite) that is used for fixation in photography.

Synonyms and Related Terms

sodium thiosulfite; sodium hydrosulfite; sodium sulfoxylate

Chemical structure

Sodium dithionite.jpg


Other Properties

Soluble in water (pH = 6.0-7.5 for 1-6% solution). Insoluble in ethanol.

Composition Na2S2O4
CAS 7775-14-6
Melting Point 52-55
Density 2.19
Molecular Weight mol. wt. = 174.1

Hazards and Safety

Fire risk in contact with moisture and air. Use dry sand to extinguish fires. Flash point=90 C

Contact causes irritation

Mallinckrodt Baker: MSDS

Additional Information

AIC Book and Paper Catalog, p.

Authority

  • G.S.Brady, Materials Handbook, McGraw-Hill Book Co., New York, 1971 Comment: p. 786
  • Richard S. Lewis, Hawley's Condensed Chemical Dictionary, Van Nostrand Reinhold, New York, 10th ed., 1993
  • Matt Roberts, Don Etherington, Bookbinding and the Conservation of Books: a Dictionary of Descriptive Terminology, U.S. Government Printing Office, Washington DC, 1982
  • Book and Paper Group, Paper Conservation Catalog, AIC, 1984, 1989
  • The Dictionary of Paper, American Paper Institute, New York, Fourth Edition, 1980
  • Van Nostrand's Scientific Encyclopedia, Douglas M. Considine (ed.), Van Nostrand Reinhold, New York, 1976
  • The Merck Index, Martha Windholz (ed.), Merck Research Labs, Rahway NJ, 10th edition, 1983 Comment: entry 8771

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