Difference between revisions of "Copal"

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== Description ==
 
== Description ==
  
A large variety of hard, natural resins obtained directly from trees such as Trachylobium species (Africa), Hymenaea courbaril (South America) and Agathis australis (New Zealand). Copals are also obtained as fossil resins from Zaire and Zanzibar. These fossil resins are very hard and almost completely insoluble. Copals are diterpenoid resins that contain communic acids, communol, resene, and volatile oil. They range in color from colorless to a bright yellow-brown. Classified as copal dur, the hardest copal resin is [http://cameo.mfa.org/materials/fullrecord.asp?name=Zanzibar copal Zanzibar]. [http://cameo.mfa.org/materials/fullrecord.asp?name=Sierra Leone copal Sierra Leone], [http://cameo.mfa.org/materials/fullrecord.asp?name=Kauri resin Kauri], and [http://cameo.mfa.org/materials/fullrecord.asp?name=Congo copal Congo] are of medium hardness (le demi-dur). [http://cameo.mfa.org/materials/fullrecord.asp?name=Manila copal Manila] and Borneo are soft copals (le tendre). The oldest, most fossilized, resins are the hardest. Copal resins may be purchased as large lumps or small tears. They were used as [http://cameo.mfa.org/materials/fullrecord.asp?name=oil varnish oil varnishes] for coaches in the 18th and 19th centuries but they darken and become insoluble with age. They also have been used in commercial [http://cameo.mfa.org/materials/fullrecord.asp?name=varnish varnishes], [http://cameo.mfa.org/materials/fullrecord.asp?name=linoleum linoleum], [http://cameo.mfa.org/materials/fullrecord.asp?name=oilcloth oilcloth], and as an [http://cameo.mfa.org/materials/fullrecord.asp?name=amber amber] substitute.
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A large variety of hard, natural resins obtained directly from trees such as Trachylobium species (Africa), Hymenaea courbaril (South America) and Agathis australis (New Zealand). Copals are also obtained as fossil resins from Zaire and Zanzibar. These fossil resins are very hard and almost completely insoluble. Copals are diterpenoid resins that contain communic acids, communol, resene, and volatile oil. They range in color from colorless to a bright yellow-brown. Classified as copal dur, the hardest copal resin is [http://cameo.mfa.org/materials/fullrecord.asp?name=Zanzibar%20copal Zanzibar]. [http://cameo.mfa.org/materials/fullrecord.asp?name=Sierra%20Leone%20copal Sierra Leone], [http://cameo.mfa.org/materials/fullrecord.asp?name=Kauri%20resin Kauri], and [http://cameo.mfa.org/materials/fullrecord.asp?name=Congo%20copal Congo] are of medium hardness (le demi-dur). [http://cameo.mfa.org/materials/fullrecord.asp?name=Manila%20copal Manila] and Borneo are soft copals (le tendre). The oldest, most fossilized, resins are the hardest. Copal resins may be purchased as large lumps or small tears. They were used as [http://cameo.mfa.org/materials/fullrecord.asp?name=oil%20varnish oil varnishes] for coaches in the 18th and 19th centuries but they darken and become insoluble with age. They also have been used in commercial [http://cameo.mfa.org/materials/fullrecord.asp?name=varnish varnishes], [http://cameo.mfa.org/materials/fullrecord.asp?name=linoleum linoleum], [http://cameo.mfa.org/materials/fullrecord.asp?name=oilcloth oilcloth], and as an [http://cameo.mfa.org/materials/fullrecord.asp?name=amber amber] substitute.
  
 
[[File:copal necklace.jpg|thumb|Copal necklace]]
 
[[File:copal necklace.jpg|thumb|Copal necklace]]
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copal (Esp.); copale (It); Zanzibar; Demerara; Benguela; Sierra Leone; Mozambique; red Angola; white Angola; Congo; kauri; Manila; Pontianak; Madagascar; Accra; Loango;  Gaboon; Borneo; Singapore; South American; Cochin; Brazilian; Benin, swamp gum; anime; cowrie
 
copal (Esp.); copale (It); Zanzibar; Demerara; Benguela; Sierra Leone; Mozambique; red Angola; white Angola; Congo; kauri; Manila; Pontianak; Madagascar; Accra; Loango;  Gaboon; Borneo; Singapore; South American; Cochin; Brazilian; Benin, swamp gum; anime; cowrie
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[[[SliderGallery rightalign|Copal resin.jpg~FTIR]]]
  
 
== Other Properties ==
 
== Other Properties ==
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[[File:15-28_Copal_glass.jpg|thumb|Copal]]
 
 
== Hazards and Safety ==
 
== Hazards and Safety ==
  
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<gallery>
 
<gallery>
File:Copal resin.jpg|Infrared spectrum of copal
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File:15-28_Copal_glass.jpg|Copal
 
</gallery>
 
</gallery>
  
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== Authority ==
 
== Authority ==
  
* R. J. Gettens, G.L. Stout, R. J. Gettens, G.L. Stout, ''Painting Materials, A Short Encyclopaedia'', Dover Publications, New York, 1966  Comment: melting points vary from 180-340C
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* R. J. Gettens, G.L. Stout, ''Painting Materials, A Short Encyclopaedia'', Dover Publications, New York, 1966  Comment: melting points vary from 180-340C
  
* ''Encyclopedia Britannica'', http://www.britannica.com  Comment: "Copal." Encyclopdia Britannica. 2004.  Encyclopdia Britannica Premium Service.  5 Jan. 2004  .
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* ''Encyclopedia Britannica'', http://www.britannica.com  Comment: "Copal." Encyclopædia Britannica. 2004.  Encyclopædia Britannica Premium Service.  5 Jan. 2004  .
  
* Ralph Mayer, Ralph Mayer, ''A Dictionary of Art Terms and Techniques'', Harper and Row Publishers, New York, 1969 (also 1945 printing)
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* Ralph Mayer, ''A Dictionary of Art Terms and Techniques'', Harper and Row Publishers, New York, 1969 (also 1945 printing)
  
 
* ''Dictionary of Building Preservation'', Ward Bucher, ed., John Wiley & Sons, Inc., New York City, 1996
 
* ''Dictionary of Building Preservation'', Ward Bucher, ed., John Wiley & Sons, Inc., New York City, 1996
  
* Reed Kay, Reed Kay, ''The Painter's Guide To Studio Methods and Materials'', Prentice-Hall, Inc., Englewood Cliffs, NJ, 1983
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* Reed Kay, ''The Painter's Guide To Studio Methods and Materials'', Prentice-Hall, Inc., Englewood Cliffs, NJ, 1983
  
* Hermann Kuhn, Hermann Kuhn, ''Conservation and Restoration of Works of Art and Antiquities'', Butterworths, London, 1986
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* Hermann Kuhn, ''Conservation and Restoration of Works of Art and Antiquities'', Butterworths, London, 1986
  
* Michael McCann, Michael McCann, ''Artist Beware'', Watson-Guptill Publications, New York City, 1979
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* Michael McCann, ''Artist Beware'', Watson-Guptill Publications, New York City, 1979
  
* Thomas B. Brill, Thomas B. Brill, ''Light Its Interaction with Art and Antiquities'', Plenum Press, New York City, 1980  Comment: ref. index = 1.545 (Congo)
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* Thomas B. Brill, ''Light Its Interaction with Art and Antiquities'', Plenum Press, New York City, 1980  Comment: ref. index = 1.545 (Congo)
  
* G.S.Brady, G.S.Brady, ''Materials Handbook'', McGraw-Hill Book Co., New York, 1971  Comment: p. 227
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* G.S.Brady, ''Materials Handbook'', McGraw-Hill Book Co., New York, 1971  Comment: p. 227
  
* Richard S. Lewis, Richard S. Lewis, ''Hawley's Condensed Chemical Dictionary'', Van Nostrand Reinhold, New York, 10th ed., 1993
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* Richard S. Lewis, ''Hawley's Condensed Chemical Dictionary'', Van Nostrand Reinhold, New York, 10th ed., 1993
  
* Matt Roberts, Don Etherington, Matt Roberts, Don Etherington, ''Bookbinding and the Conservation of Books: a Dictionary of Descriptive Terminology'', U.S. Government Printing Office, Washington DC, 1982
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* Matt Roberts, Don Etherington, ''Bookbinding and the Conservation of Books: a Dictionary of Descriptive Terminology'', U.S. Government Printing Office, Washington DC, 1982
  
 
* ''Van Nostrand's Scientific Encyclopedia'', Douglas M. Considine (ed.), Van Nostrand Reinhold, New York, 1976
 
* ''Van Nostrand's Scientific Encyclopedia'', Douglas M. Considine (ed.), Van Nostrand Reinhold, New York, 1976
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* ''CRC Handbook of Chemistry and Physics'', Robert Weast (ed.), CRC Press, Boca Raton, Florida, v. 61, 1980  Comment: density=1.04-1.14; ref. index = 1.528
 
* ''CRC Handbook of Chemistry and Physics'', Robert Weast (ed.), CRC Press, Boca Raton, Florida, v. 61, 1980  Comment: density=1.04-1.14; ref. index = 1.528
  
* Paintings Specialty Group, Paintings Specialty Group, ''Painting Conservation Catalog'', Wendy Samet (ed.), AIC, Washington, DC, 1998
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* Paintings Specialty Group, ''Painting Conservation Catalog'', Wendy Samet (ed.), AIC, Washington, DC, 1998
  
  
  
 
[[Category:Materials database]]
 
[[Category:Materials database]]

Revision as of 06:46, 24 July 2013

02.222-E11509CR-d1.jpg

Description

A large variety of hard, natural resins obtained directly from trees such as Trachylobium species (Africa), Hymenaea courbaril (South America) and Agathis australis (New Zealand). Copals are also obtained as fossil resins from Zaire and Zanzibar. These fossil resins are very hard and almost completely insoluble. Copals are diterpenoid resins that contain communic acids, communol, resene, and volatile oil. They range in color from colorless to a bright yellow-brown. Classified as copal dur, the hardest copal resin is Zanzibar. Sierra Leone, Kauri, and Congo are of medium hardness (le demi-dur). Manila and Borneo are soft copals (le tendre). The oldest, most fossilized, resins are the hardest. Copal resins may be purchased as large lumps or small tears. They were used as oil varnishes for coaches in the 18th and 19th centuries but they darken and become insoluble with age. They also have been used in commercial varnishes, linoleum, oilcloth, and as an amber substitute.

Copal necklace

Synonyms and Related Terms

copal (Esp.); copale (It); Zanzibar; Demerara; Benguela; Sierra Leone; Mozambique; red Angola; white Angola; Congo; kauri; Manila; Pontianak; Madagascar; Accra; Loango; Gaboon; Borneo; Singapore; South American; Cochin; Brazilian; Benin, swamp gum; anime; cowrie

FTIR

Copal resin.jpg


Other Properties

After melting, copals are soluble in oil and turpentine. Soft copals are partially soluble in ethanol, chloroform, glacial acetic acid. Most copals fluoresce white in short-wave UV light.

Melting Point 180-340
Density 1.04-1.13
Refractive Index 1.528-1.545

Hazards and Safety

Contact and inhalation may cause irritation. Combustible, burning with a bright flame, dense smoke and strong smell.

Additional Information

K.van den Berg, J.van der Horst, J.Boon, "Recognition of Copals in Aged Resin/oil Paints and Varnishes" in ICOM Preprints, Lyon, 1999. p.855-861.

Comparisons

Properties of Natural Resins

Properties of Natural Resins


Additional Images


Authority

  • R. J. Gettens, G.L. Stout, Painting Materials, A Short Encyclopaedia, Dover Publications, New York, 1966 Comment: melting points vary from 180-340C
  • Encyclopedia Britannica, http://www.britannica.com Comment: "Copal." Encyclopædia Britannica. 2004. Encyclopædia Britannica Premium Service. 5 Jan. 2004 .
  • Ralph Mayer, A Dictionary of Art Terms and Techniques, Harper and Row Publishers, New York, 1969 (also 1945 printing)
  • Dictionary of Building Preservation, Ward Bucher, ed., John Wiley & Sons, Inc., New York City, 1996
  • Reed Kay, The Painter's Guide To Studio Methods and Materials, Prentice-Hall, Inc., Englewood Cliffs, NJ, 1983
  • Hermann Kuhn, Conservation and Restoration of Works of Art and Antiquities, Butterworths, London, 1986
  • Michael McCann, Artist Beware, Watson-Guptill Publications, New York City, 1979
  • Thomas B. Brill, Light Its Interaction with Art and Antiquities, Plenum Press, New York City, 1980 Comment: ref. index = 1.545 (Congo)
  • G.S.Brady, Materials Handbook, McGraw-Hill Book Co., New York, 1971 Comment: p. 227
  • Richard S. Lewis, Hawley's Condensed Chemical Dictionary, Van Nostrand Reinhold, New York, 10th ed., 1993
  • Matt Roberts, Don Etherington, Bookbinding and the Conservation of Books: a Dictionary of Descriptive Terminology, U.S. Government Printing Office, Washington DC, 1982
  • Van Nostrand's Scientific Encyclopedia, Douglas M. Considine (ed.), Van Nostrand Reinhold, New York, 1976
  • The Merck Index, Martha Windholz (ed.), Merck Research Labs, Rahway NJ, 10th edition, 1983 Comment: entry # 2581
  • CRC Handbook of Chemistry and Physics, Robert Weast (ed.), CRC Press, Boca Raton, Florida, v. 61, 1980 Comment: density=1.04-1.14; ref. index = 1.528
  • Paintings Specialty Group, Painting Conservation Catalog, Wendy Samet (ed.), AIC, Washington, DC, 1998

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