Difference between revisions of "Caprolactam"

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A white, hygroscopic flakes used to make [[Nylon 6]]. Caprolactam is also used as a plasticizer in paint and a crosslinking agent for [[polyurethane]].
 
A white, hygroscopic flakes used to make [[Nylon 6]]. Caprolactam is also used as a plasticizer in paint and a crosslinking agent for [[polyurethane]].
  
 +
[[[SliderGallery rightalign|caprolactam.jpg~Chemical structure]]]
 
== Synonyms and Related Terms ==
 
== Synonyms and Related Terms ==
  
 
aminocaproic lactam; 2-oxohexamethyleneimine; hexahydro-2H-azepin-2-one
 
aminocaproic lactam; 2-oxohexamethyleneimine; hexahydro-2H-azepin-2-one
  
[[[SliderGallery rightalign|caprolactam.jpg~Chemical structure]]]
+
== Risks ==
 +
 
 +
* Toxic by inhalation.
 +
* Skin contact causes irritation. 
 +
* Combustible.  Flash point = 125C   
 +
* Produces toxic fumes including nitrogen oxide and ammonia when burnt. 
 +
* ThermoFisher: [https://www.fishersci.com/store/msds?partNumber=AC108231000&productDescription=EPSILON-CAPROLACTAM%2C+99%2B+100GR&vendorId=VN00032119&countryCode=US&language=en SDS]
  
== Other Properties ==
+
==Physical and Chemical Properties==
  
 
Soluble in water, methanol, ethanol, ether, tetrahydrofurfuryl alcohol, dimethylformamide, cyclohexene, petroleum fractions, chlorinated hydrocarbons.
 
Soluble in water, methanol, ethanol, ether, tetrahydrofurfuryl alcohol, dimethylformamide, cyclohexene, petroleum fractions, chlorinated hydrocarbons.
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|-
 
|-
 
! scope="row"| Melting Point
 
! scope="row"| Melting Point
| 70
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| 70 C
 
|-
 
|-
 
! scope="row"| Density
 
! scope="row"| Density
| 1.02
+
| 1.02 g/ml
 
|-
 
|-
 
! scope="row"| Molecular Weight
 
! scope="row"| Molecular Weight
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|-
 
|-
 
! scope="row"| Boiling Point
 
! scope="row"| Boiling Point
| 267
+
| 267 C
 
|}
 
|}
  
== Hazards and Safety ==
+
==Resources and Citations==
 
 
Toxic by inhalation. Skin contact causes irritation. 
 
 
 
Combustible.  Flash point = 125C   
 
 
 
Produces toxic fumes including nitrogen oxide and ammonia when burnt. 
 
 
 
[http://www.cdc.gov/niosh/ipcsneng/neng0118.html International Chemical Safety Card]
 
 
 
== Authority ==
 
  
 
* G.S.Brady, ''Materials Handbook'', McGraw-Hill Book Co., New York, 1971  Comment: p. 554
 
* G.S.Brady, ''Materials Handbook'', McGraw-Hill Book Co., New York, 1971  Comment: p. 554
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* ''The Merck Index'', Martha Windholz (ed.), Merck Research Labs, Rahway NJ, 10th edition, 1983  Comment: entry 1805
 
* ''The Merck Index'', Martha Windholz (ed.), Merck Research Labs, Rahway NJ, 10th edition, 1983  Comment: entry 1805
  
* Wikipedia, the free encyclopedia, at http://www.wikipedia.com  Comment: http://en.wikipedia.org/wiki/Caprolactam (Accessed Feb. 25, 2006)
+
* Wikipedia: http://en.wikipedia.org/wiki/Caprolactam (Accessed Feb. 25, 2006)
  
 
* ''Van Nostrand's Scientific Encyclopedia'', Douglas M. Considine (ed.), Van Nostrand Reinhold, New York, 1976
 
* ''Van Nostrand's Scientific Encyclopedia'', Douglas M. Considine (ed.), Van Nostrand Reinhold, New York, 1976

Latest revision as of 15:31, 18 May 2022

Description

A white, hygroscopic flakes used to make Nylon 6. Caprolactam is also used as a plasticizer in paint and a crosslinking agent for Polyurethane.

Chemical structure

Caprolactam.jpg

Synonyms and Related Terms

aminocaproic lactam; 2-oxohexamethyleneimine; hexahydro-2H-azepin-2-one

Risks

  • Toxic by inhalation.
  • Skin contact causes irritation.
  • Combustible. Flash point = 125C
  • Produces toxic fumes including nitrogen oxide and ammonia when burnt.
  • ThermoFisher: SDS

Physical and Chemical Properties

Soluble in water, methanol, ethanol, ether, tetrahydrofurfuryl alcohol, dimethylformamide, cyclohexene, petroleum fractions, chlorinated hydrocarbons.

Composition NH(CH2)5CO
CAS 105-60-2
Melting Point 70 C
Density 1.02 g/ml
Molecular Weight mol. wt. = 113.2
Refractive Index 1.4965
Boiling Point 267 C

Resources and Citations

  • G.S.Brady, Materials Handbook, McGraw-Hill Book Co., New York, 1971 Comment: p. 554
  • Theodore J. Reinhart, 'Glossary of Terms', Engineered Plastics, ASM International, 1988
  • Richard S. Lewis, Hawley's Condensed Chemical Dictionary, Van Nostrand Reinhold, New York, 10th ed., 1993
  • The Merck Index, Martha Windholz (ed.), Merck Research Labs, Rahway NJ, 10th edition, 1983 Comment: entry 1805
  • Van Nostrand's Scientific Encyclopedia, Douglas M. Considine (ed.), Van Nostrand Reinhold, New York, 1976
  • Random House, Webster's Encyclopedic Unabridged Dictionary of the English Language, Grammercy Book, New York, 1997

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