Difference between revisions of "Sodium bisulfate"

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== Description ==
 
== Description ==
  
Colorless crystals or white lumps. Sodium bisulfate is used as an inexpensive substitute for [http://cameo.mfa.org/materials/fullrecord.asp?name=sulfuric%20acid sulfuric acid] in dyeing solutions. It is also used in the manufacture of [http://cameo.mfa.org/materials/fullrecord.asp?name=paper paper], [http://cameo.mfa.org/materials/fullrecord.asp?name=soap soap], [http://cameo.mfa.org/materials/fullrecord.asp?name=magnesia%20cement magnesia cements], and acid-based industrial cleaners. Sodium bisulfate acts as a [http://cameo.mfa.org/materials/fullrecord.asp?name=flux flux] in metallurgy. It can pickle [http://cameo.mfa.org/materials/fullrecord.asp?name=metal metals], carbonize [http://cameo.mfa.org/materials/fullrecord.asp?name=wool wool], and bleach [http://cameo.mfa.org/materials/fullrecord.asp?name=leather leather].
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Colorless crystals or white lumps. Sodium bisulfate is used as an inexpensive substitute for [[sulfuric%20acid|sulfuric acid]] in dyeing solutions. It is also used in the manufacture of [[paper|paper]], [[soap|soap]], [[magnesia%20cement|magnesia cements]], and acid-based industrial cleaners. Sodium bisulfate acts as a [[flux|flux]] in metallurgy. It can pickle [[metal|metals]], carbonize [[wool|wool]], and bleach [[leather|leather]].
 
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[[[SliderGallery rightalign|aaiNAbiSO4.jpg~FTIR|sodium bisulfate.jpg~Chemical structure]]]
 
== Synonyms and Related Terms ==
 
== Synonyms and Related Terms ==
  
 
sodium acid sulfate; niter cake; sodium hydrogen sulfate; sodium bisulphate (Br.); sodium pyrosulfate
 
sodium acid sulfate; niter cake; sodium hydrogen sulfate; sodium bisulphate (Br.); sodium pyrosulfate
  
[[[SliderGallery rightalign|aaiNAbiSO4.jpg~FTIR|sodium bisulfate.jpg~Chemical structure]]]
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== Risks ==
  
== Other Properties ==
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* Strongly irritating to skin, eyes and lungs.
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* Hygroscopic.
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* Noncombustible.
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* ThermoFisher: [https://www.fishersci.com/store/msds?partNumber=S2403&productDescription=SODIUM+BISULFATE+CERTIFD+3KG&vendorId=VN00033897&countryCode=US&language=en SDS]
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==Physical and Chemical Properties==
  
 
Soluble in water forming an acidic solution (0.1 molar has a pH of 1.4). Decomposes in ethanol to form sodium sulfate and sulfuric acid.
 
Soluble in water forming an acidic solution (0.1 molar has a pH of 1.4). Decomposes in ethanol to form sodium sulfate and sulfuric acid.
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|-
 
|-
 
! scope="row"| Melting Point
 
! scope="row"| Melting Point
| 315
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| 315 C
 
|-
 
|-
 
! scope="row"| Density
 
! scope="row"| Density
| 2.435
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| 2.435 g/ml
 
|-
 
|-
 
! scope="row"| Molecular Weight
 
! scope="row"| Molecular Weight
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|}
 
|}
  
== Hazards and Safety ==
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==Resources and Citations==
 
 
Strongly irritating to skin, eyes and lungs. Hygroscopic. Noncombustible.
 
 
 
Mallinckrodt Baker: [http://www.jtbaker.com/msds/englishhtml/s3050.htm MSDS]
 
 
 
== Authority ==
 
  
 
* ''The Merck Index'', Martha Windholz (ed.), Merck Research Labs, Rahway NJ, 10th edition, 1983  Comment: entry 8727
 
* ''The Merck Index'', Martha Windholz (ed.), Merck Research Labs, Rahway NJ, 10th edition, 1983  Comment: entry 8727
  
* Website address 1  Comment: www.jetcity.com/~mrjones/chemdesc.htm - photographic chemicals
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* Photographic chemicals: www.jetcity.com/~mrjones/chemdesc.htm  
  
 
* ''CRC Handbook of Chemistry and Physics'', Robert Weast (ed.), CRC Press, Boca Raton, Florida, v. 61, 1980  Comment: ref. index = 1.43, 1.46, 1.47
 
* ''CRC Handbook of Chemistry and Physics'', Robert Weast (ed.), CRC Press, Boca Raton, Florida, v. 61, 1980  Comment: ref. index = 1.43, 1.46, 1.47
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* ''The American Heritage Dictionary'' or ''Encarta'', via Microsoft Bookshelf 98, Microsoft Corp., 1998
 
* ''The American Heritage Dictionary'' or ''Encarta'', via Microsoft Bookshelf 98, Microsoft Corp., 1998
  
* MSDS Sheet
 
  
  
  
 
[[Category:Materials database]]
 
[[Category:Materials database]]

Latest revision as of 14:20, 3 October 2022

Description

Colorless crystals or white lumps. Sodium bisulfate is used as an inexpensive substitute for Sulfuric acid in dyeing solutions. It is also used in the manufacture of Paper, Soap, magnesia cements, and acid-based industrial cleaners. Sodium bisulfate acts as a Flux in metallurgy. It can pickle metals, carbonize Wool, and bleach Leather.

FTIR

AaiNAbiSO4.jpg

Chemical structure

Sodium bisulfate.jpg

Synonyms and Related Terms

sodium acid sulfate; niter cake; sodium hydrogen sulfate; sodium bisulphate (Br.); sodium pyrosulfate

Risks

  • Strongly irritating to skin, eyes and lungs.
  • Hygroscopic.
  • Noncombustible.
  • ThermoFisher: SDS

Physical and Chemical Properties

Soluble in water forming an acidic solution (0.1 molar has a pH of 1.4). Decomposes in ethanol to form sodium sulfate and sulfuric acid.

Composition NaHSO4
CAS 7681-38-1
Melting Point 315 C
Density 2.435 g/ml
Molecular Weight mol. wt. = 120.06
Refractive Index 1.43, 1.46, 1.47

Resources and Citations

  • The Merck Index, Martha Windholz (ed.), Merck Research Labs, Rahway NJ, 10th edition, 1983 Comment: entry 8727
  • Photographic chemicals: www.jetcity.com/~mrjones/chemdesc.htm
  • CRC Handbook of Chemistry and Physics, Robert Weast (ed.), CRC Press, Boca Raton, Florida, v. 61, 1980 Comment: ref. index = 1.43, 1.46, 1.47
  • Richard S. Lewis, Hawley's Condensed Chemical Dictionary, Van Nostrand Reinhold, New York, 10th ed., 1993
  • Random House, Webster's Encyclopedic Unabridged Dictionary of the English Language, Grammercy Book, New York, 1997
  • The American Heritage Dictionary or Encarta, via Microsoft Bookshelf 98, Microsoft Corp., 1998