Difference between revisions of "Benzene"

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== Description ==
 
== Description ==
  
A clear, colorless, volatile aromatic solvent. Benzene was first isolated by Faraday in 1825. It is obtained from the destructive distillation of [http://cameo.mfa.org/materials/fullrecord.asp?name=coal coal] and [http://cameo.mfa.org/materials/fullrecord.asp?name=oil oil]. The industrial grade distillation fraction sold as [http://cameo.mfa.org/materials/fullrecord.asp?name=benzol benzol] contains about 65% benzene, 33% [http://cameo.mfa.org/materials/fullrecord.asp?name=toluene toluene] plus 2% other aromatic compounds. Benzene was formerly a commonly used solvent for [http://cameo.mfa.org/materials/fullrecord.asp?name=wax waxes], [http://cameo.mfa.org/materials/fullrecord.asp?name=natural resin resins], [http://cameo.mfa.org/materials/fullrecord.asp?name=oil oils], [http://cameo.mfa.org/materials/fullrecord.asp?name=rubber, synthetic rubber], and [http://cameo.mfa.org/materials/fullrecord.asp?name=paint remover paint removers], but this was discontinued because of its toxicity. It is now used primarily for the manufacture of styrene polymers, aromatic chlorides, and some dyes.
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A clear, colorless, volatile aromatic solvent. Benzene was first isolated by Faraday in 1825. It is obtained from the destructive distillation of [[coal]] and [[oil]]. The industrial grade distillation fraction sold as [[benzol]] contains about 65% benzene, 33% [[toluene]] plus 2% other aromatic compounds. Benzene was formerly a commonly used solvent for [[wax|waxes]], [[natural%20resin|resins]], [[oil|oils]], [[rubber (synthetic)|rubber]], and [[paint%20remover|paint removers]], but this was discontinued because of its toxicity. It is now used primarily for the manufacture of styrene polymers, aromatic chlorides, and some dyes.
  
 
== Synonyms and Related Terms ==
 
== Synonyms and Related Terms ==
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[[[SliderGallery rightalign|benzene.jpg~Chemical structure]]]
 
[[[SliderGallery rightalign|benzene.jpg~Chemical structure]]]
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== Risks ==
  
== Other Properties ==
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* Known carcinogen. Toxic in ingestion and inhalation. 
 +
* Skin contact causes irritation and dissolves fat. 
 +
* Flammable and explosive.  Dangerous fire risk.  Burns with a sooty flame. 
 +
* ThermoFisher: [https://fscimage.fishersci.com/msds/02610.htm MSDS]
 +
* EPA lists benzene as hazardous waste; concentrations over 10% must be disposed of appropriately
 +
== Physical and Chemical Properties ==
  
 
Miscible with ethanol, ether, acetone, carbon tetrachloride, carbon disulfide, acetic acid, oils.  Slightly soluble in water.
 
Miscible with ethanol, ether, acetone, carbon tetrachloride, carbon disulfide, acetic acid, oils.  Slightly soluble in water.
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|-
 
|-
 
! scope="row"| Melting Point
 
! scope="row"| Melting Point
| 5.5
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| 5.5 C
 
|-
 
|-
 
! scope="row"| Density
 
! scope="row"| Density
| 0.8787
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| 0.8787 g/ml
 
|-
 
|-
 
! scope="row"| Molecular Weight
 
! scope="row"| Molecular Weight
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|-
 
|-
 
! scope="row"| Boiling Point
 
! scope="row"| Boiling Point
| 80.1
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| 80.1 C
 
|}
 
|}
 
== Hazards and Safety ==
 
 
Known carcinogen. Toxic in ingestion and inhalation.  Skin contact causes irritation and dissolves fat.  Flammable and explosive.  Dangerous fire risk.  Burns with a sooty flame. 
 
 
LINK: [http://www.cdc.gov/niosh/ipcsneng/neng0015.html International Chemical Safety Card]
 
  
 
== Comparisons ==
 
== Comparisons ==
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[[media:download_file_116.pdf|Properties of Common Solvents]]
 
[[media:download_file_116.pdf|Properties of Common Solvents]]
  
 
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== Resources and Citations ==
 
 
== Authority ==
 
  
 
* ''Van Nostrand's Scientific Encyclopedia'', Douglas M. Considine (ed.), Van Nostrand Reinhold, New York, 1976
 
* ''Van Nostrand's Scientific Encyclopedia'', Douglas M. Considine (ed.), Van Nostrand Reinhold, New York, 1976
  
* Random House, Random House, ''Webster's Encyclopedic Unabridged Dictionary of the English Language'', Grammercy Book, New York, 1997
+
* Random House, ''Webster's Encyclopedic Unabridged Dictionary of the English Language'', Grammercy Book, New York, 1997
  
 
* ''The American Heritage Dictionary'' or ''Encarta'', via Microsoft Bookshelf 98, Microsoft Corp., 1998
 
* ''The American Heritage Dictionary'' or ''Encarta'', via Microsoft Bookshelf 98, Microsoft Corp., 1998
  
* R. J. Gettens, G.L. Stout, R. J. Gettens, G.L. Stout, ''Painting Materials, A Short Encyclopaedia'', Dover Publications, New York, 1966
+
* R. J. Gettens, G.L. Stout, ''Painting Materials, A Short Encyclopaedia'', Dover Publications, New York, 1966
  
* Richard S. Lewis, Richard S. Lewis, ''Hawley's Condensed Chemical Dictionary'', Van Nostrand Reinhold, New York, 10th ed., 1993
+
* Richard S. Lewis, ''Hawley's Condensed Chemical Dictionary'', Van Nostrand Reinhold, New York, 10th ed., 1993
  
 
* ''The Merck Index'', Martha Windholz (ed.), Merck Research Labs, Rahway NJ, 10th edition, 1983  Comment: entry 1094
 
* ''The Merck Index'', Martha Windholz (ed.), Merck Research Labs, Rahway NJ, 10th edition, 1983  Comment: entry 1094
  
* Hoechst Celanese Corporation, Hoechst Celanese Corporation, ''Dictionary of Fiber & Textile Technology'' (older version called Man-made Fiber and Textile Dictionary, 1965), Hoechst Celanese Corporation, Charlotte NC, 1990
+
* Hoechst Celanese Corporation, ''Dictionary of Fiber & Textile Technology'' (older version called Man-made Fiber and Textile Dictionary, 1965), Hoechst Celanese Corporation, Charlotte NC, 1990
  
* Matt Roberts, Don Etherington, Matt Roberts, Don Etherington, ''Bookbinding and the Conservation of Books: a Dictionary of Descriptive Terminology'', U.S. Government Printing Office, Washington DC, 1982
+
* Matt Roberts, Don Etherington, ''Bookbinding and the Conservation of Books: a Dictionary of Descriptive Terminology'', U.S. Government Printing Office, Washington DC, 1982
  
* Reed Kay, Reed Kay, ''The Painter's Guide To Studio Methods and Materials'', Prentice-Hall, Inc., Englewood Cliffs, NJ, 1983
+
* Reed Kay, ''The Painter's Guide To Studio Methods and Materials'', Prentice-Hall, Inc., Englewood Cliffs, NJ, 1983
  
* Michael McCann, Michael McCann, ''Artist Beware'', Watson-Guptill Publications, New York City, 1979
+
* Michael McCann, ''Artist Beware'', Watson-Guptill Publications, New York City, 1979
  
  
  
 
[[Category:Materials database]]
 
[[Category:Materials database]]

Latest revision as of 12:19, 17 April 2024

Absorption and fluorescence emission spectra

Description

A clear, colorless, volatile aromatic solvent. Benzene was first isolated by Faraday in 1825. It is obtained from the destructive distillation of Coal and Oil. The industrial grade distillation fraction sold as Benzol contains about 65% benzene, 33% Toluene plus 2% other aromatic compounds. Benzene was formerly a commonly used solvent for waxes, resins, oils, rubber, and paint removers, but this was discontinued because of its toxicity. It is now used primarily for the manufacture of styrene polymers, aromatic chlorides, and some dyes.

Synonyms and Related Terms

benzol; cyclohexatriene

Chemical structure

Benzene.jpg

Risks

  • Known carcinogen. Toxic in ingestion and inhalation.
  • Skin contact causes irritation and dissolves fat.
  • Flammable and explosive. Dangerous fire risk. Burns with a sooty flame.
  • ThermoFisher: MSDS
  • EPA lists benzene as hazardous waste; concentrations over 10% must be disposed of appropriately

Physical and Chemical Properties

Miscible with ethanol, ether, acetone, carbon tetrachloride, carbon disulfide, acetic acid, oils. Slightly soluble in water.

Composition C6H6
CAS 71-43-2
Melting Point 5.5 C
Density 0.8787 g/ml
Molecular Weight mol. wt. = 78.1
Refractive Index 1.50110
Boiling Point 80.1 C

Comparisons

Properties of Common Solvents

Resources and Citations

  • Van Nostrand's Scientific Encyclopedia, Douglas M. Considine (ed.), Van Nostrand Reinhold, New York, 1976
  • Random House, Webster's Encyclopedic Unabridged Dictionary of the English Language, Grammercy Book, New York, 1997
  • The American Heritage Dictionary or Encarta, via Microsoft Bookshelf 98, Microsoft Corp., 1998
  • R. J. Gettens, G.L. Stout, Painting Materials, A Short Encyclopaedia, Dover Publications, New York, 1966
  • Richard S. Lewis, Hawley's Condensed Chemical Dictionary, Van Nostrand Reinhold, New York, 10th ed., 1993
  • The Merck Index, Martha Windholz (ed.), Merck Research Labs, Rahway NJ, 10th edition, 1983 Comment: entry 1094
  • Hoechst Celanese Corporation, Dictionary of Fiber & Textile Technology (older version called Man-made Fiber and Textile Dictionary, 1965), Hoechst Celanese Corporation, Charlotte NC, 1990
  • Matt Roberts, Don Etherington, Bookbinding and the Conservation of Books: a Dictionary of Descriptive Terminology, U.S. Government Printing Office, Washington DC, 1982
  • Reed Kay, The Painter's Guide To Studio Methods and Materials, Prentice-Hall, Inc., Englewood Cliffs, NJ, 1983
  • Michael McCann, Artist Beware, Watson-Guptill Publications, New York City, 1979