Difference between revisions of "FORS analysis of Ukiyo-e prints"

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==Overview==
 
==Overview==
 
[[File:Ocean Optics FORS.jpg|thumb|Ocean Optics FORS components for reflective analysis]]
 
[[File:Ocean Optics FORS.jpg|thumb|Ocean Optics FORS components for reflective analysis]]
[[File:Dayflower FORS.JPG|thumb|FORS spectrum of Dayflower reference]]
 
[[File:Indigo FORS.JPG|thumb|FORS spectrum of Indigo reference]]
 
[[File:Prussian blue FORS.jpg|thumb|FORS spectrum of Prussian blue reference]]
 
  
[[Fiber optics reflectance spectroscopy (FORS)|Fiber Optics Reflectance spectroscopy (FORS)]] measures the reflectance of a point on an object across the visible and near infrared region (about 400-1000 nm).  FORS uses a fiber optic probe and a high intensity halogen light source to examine very small spots, minimizing the interference from ambient light. For this research, an Ocean Optics miniature spectrometer was used.
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FORS reflectance spectra can distinguish between three common blue colorants used in Japanese woodblock prints (dayflower, indigo, and Prussian blue).  Greens were usually made from a combination of a blue and a yellow colorant, while purples were usually made from a combination of a blue and a red colorant. The blue colorants in these mixtures can usually be determined by FORS analysis. FORS is not usually useful for identifying yellow colorants, but can sometimes be useful for the organic reds.  
 
 
Reflectance spectra can distinguish between some colorants.  For example, the three common blue colorants used in Japanese woodblock prints (dayflower, indigo, and Prussian blue) can be easily identified by FORS.  Greens were usually made from a combination of a blue and a yellow colorant, while purples were usually made from a combination of a blue and a red colorant. The blue colorants in these mixtures can usually be determined by FORS analysis. FORS is not usually useful for identifying yellow colorants, but can sometimes be useful for the organic reds.
 
 
 
Reflectance spectra for the three common blues are show below, along with spectra of each blue from a print.  The paper used in the prints typically has a slight yellowish tint, thus for the FORS analysis, an area of bare paper is used to acquire a background spectrum, which is then subtracted from the spectrum of the colored area.  In principal, this gives spectra which should be more directly comparable between standards prepared in the lab and areas on prints.
 
  
 
==FORS Reference Spectra==
 
==FORS Reference Spectra==
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! Reds
 
! Reds
 
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|-
|[[[SliderGallery Leftalign|Dayflower FORS.JPG~Dayflower|Indigo FORS.JPG~Indigo|Prussian blue FORS.jpg~Prussian blue]]]
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|[[[SliderGallery Leftalign|Indigo FORS.JPG~Indigo|Dayflower FORS.JPG~Dayflower|Prussian blue FORS.jpg~Prussian blue|Azurite-FORS.png~Azurite|Ultramarine-FORS.png~Ultramarine]]]
|[[[SliderGallery center|Malachite reference FORS.png~Malachite|Orpiment-Indigo FORS.png~Orpiment/Indigo|Orpiment-Prussian blue FORS.png~Orpiment/Prussian Blue|Turmeric-Dayflower FORS.png~Turmeric/Dayflower|Verdigris FORS.png~Verdigris]]]
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|[[[SliderGallery center|Orpiment-Indigo-FORS.png~Orpiment/Indigo|Orpiment-Prussian blue-FORS.png~Orpiment/Prussian Blue|Turmeric-Dayflower FORS.png~Turmeric/Dayflower|Malachite reference FORS.png~Malachite|Verdigris-FORS.png~Verdigris]]]
|[[[SliderGallery center|Indigo(443).PNG~FTIR (MFA)|Indigo, Forbes (MFA 443), 785nm.TIF~Raman (MFA)|PIG441.jpg~XRD|f441sem.jpg~SEM|f441edsbw.jpg~EDS|Indigo_FORS.JPG~FORS|indigo.jpg~Chemical structure]]]
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|[[[SliderGallery center|Orpiment-FORS.png~Orpiment|Turmeric-FORS.png~Turmeric|Pagoda Tree FORS.png~Pagoda Tree|Rice plant FORS.png~Rice Plant|Yellowwood FORS.png~Yellowwood]]]
|[[[SliderGallery center|Indigo(443).PNG~FTIR (MFA)|Indigo, Forbes (MFA 443), 785nm.TIF~Raman (MFA)|PIG441.jpg~XRD|f441sem.jpg~SEM|f441edsbw.jpg~EDS|Indigo_FORS.JPG~FORS|indigo.jpg~Chemical structure]]]
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|[[[SliderGallery center|Madder R.Tinctorium-FORS.png~Madder|Safflower-FORS.png~Safflower|Iron oxide red-FORS.png~Iron Oxide Red|Red lead-FORS.png~Red Lead|Vermilion-FORS.png~Vermilion]]]
 
|}
 
|}
  
==Limitations==
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==Analysis==
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Reflectance spectra for the three common blues are show below, along with spectra of each blue from a print.  The paper used in the prints typically has a slight yellowish tint, thus for the FORS analysis, an area of bare paper is used to acquire a background spectrum, which is then subtracted from the spectrum of the colored area.  In principal, this gives spectra which should be more directly comparable between standards prepared in the lab and areas on prints.

Latest revision as of 14:00, 1 May 2025

Overview

Ocean Optics FORS components for reflective analysis

FORS reflectance spectra can distinguish between three common blue colorants used in Japanese woodblock prints (dayflower, indigo, and Prussian blue). Greens were usually made from a combination of a blue and a yellow colorant, while purples were usually made from a combination of a blue and a red colorant. The blue colorants in these mixtures can usually be determined by FORS analysis. FORS is not usually useful for identifying yellow colorants, but can sometimes be useful for the organic reds.

FORS Reference Spectra

Blues Greens Yellows Reds

Indigo

Indigo FORS.JPG

Dayflower

Dayflower FORS.JPG

Prussian blue

Prussian blue FORS.jpg

Azurite

Azurite-FORS.png

Ultramarine

Ultramarine-FORS.png

Orpiment/Indigo

Orpiment-Indigo-FORS.png

Orpiment/Prussian Blue

Orpiment-Prussian blue-FORS.png

Turmeric/Dayflower

Turmeric-Dayflower FORS.png

Malachite

Malachite reference FORS.png

Verdigris

Verdigris-FORS.png

Orpiment

Orpiment-FORS.png

Turmeric

Turmeric-FORS.png

Pagoda Tree

Pagoda Tree FORS.png

Rice Plant

Rice plant FORS.png

Yellowwood

Yellowwood FORS.png

Madder

Madder R.Tinctorium-FORS.png

Safflower

Safflower-FORS.png

Iron Oxide Red

Iron oxide red-FORS.png

Red Lead

Red lead-FORS.png

Vermilion

Vermilion-FORS.png

Analysis

Reflectance spectra for the three common blues are show below, along with spectra of each blue from a print. The paper used in the prints typically has a slight yellowish tint, thus for the FORS analysis, an area of bare paper is used to acquire a background spectrum, which is then subtracted from the spectrum of the colored area. In principal, this gives spectra which should be more directly comparable between standards prepared in the lab and areas on prints.