Difference between revisions of "Zinc sulfide"

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== Description ==
 
== Description ==
  
An off-white powder that occurs in nature as the minerals wurtzite and sphalerite. Zinc sulfide slowly oxidizes in moist air to form [http://cameo.mfa.org/materials/fullrecord.asp?name=zinc sulfate zinc sulfate]. The synthetic form was introduced as a pigment in 1852 but not widely used by itself due to gray tonalities from impurities.  Zinc sulfide is mixed with [http://cameo.mfa.org/materials/fullrecord.asp?name=barium sulfate barium sulfate] to form [http://cameo.mfa.org/materials/fullrecord.asp?name=lithopone lithopone].
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An off-white powder that occurs in nature as the minerals wurtzite and sphalerite. Zinc sulfide slowly oxidizes in moist air to form [[zinc%20sulfate|zinc sulfate]]. The synthetic form was introduced as a pigment in 1852 but not widely used by itself due to gray tonalities from impurities.  Zinc sulfide is mixed with [[barium%20sulfate|barium sulfate]] to form [[lithopone|lithopone]].
  
 
== Synonyms and Related Terms ==
 
== Synonyms and Related Terms ==
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zinc sulphide (Br.); zinc blende; CI 77975; Pigment White 7
 
zinc sulphide (Br.); zinc blende; CI 77975; Pigment White 7
  
[[[SliderGallery rightalign|zinc sulfide.jpg~Chemical structure]]]
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== Risks ==
  
== Other Properties ==
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* Sensitive to moisture and air. 
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* Contact causes irritation.
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* Fisher Scientific: [https://fscimage.fishersci.com/msds/28584.htm MSDS]
  
Soluble in mineral acids.  Insoluble in water.
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== Physical and Chemical Properties ==
  
Transparent, colorless crystals with high relief.  In crossed polars the crystals are isotropic with very weak birefringence.
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* Soluble in mineral acids.  Insoluble in water.
 
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* Transparent, colorless crystals with high relief.   
Fluoresces weak yellow
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* In crossed polars the crystals are isotropic with very weak birefringence.
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* Fluoresces weak yellow
  
 
{| class="wikitable"
 
{| class="wikitable"
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|-
 
|-
 
! scope="row"| Density
 
! scope="row"| Density
| 3.98
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| 3.98 g/ml
 
|-
 
|-
 
! scope="row"| Molecular Weight
 
! scope="row"| Molecular Weight
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|}
 
|}
  
== Hazards and Safety ==
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==Resources and Citations==
 
 
Sensitive to moisture and air.  Contact causes irritation.
 
 
 
Fisher Scientific: [https://fscimage.fishersci.com/msds/28584.htm MSDS]
 
 
 
== Authority ==
 
  
* Nicholas Eastaugh, Valentine Walsh, Tracey Chaplin, Ruth Siddall, Nicholas Eastaugh, Valentine Walsh, Tracey Chaplin, Ruth Siddall, ''Pigment Compendium'', Elsevier Butterworth-Heinemann, Oxford, 2004
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* Nicholas Eastaugh, Valentine Walsh, Tracey Chaplin, Ruth Siddall, ''Pigment Compendium'', Elsevier Butterworth-Heinemann, Oxford, 2004
  
 
* ''The Merck Index'', Martha Windholz (ed.), Merck Research Labs, Rahway NJ, 10th edition, 1983  Comment: entry 10294
 
* ''The Merck Index'', Martha Windholz (ed.), Merck Research Labs, Rahway NJ, 10th edition, 1983  Comment: entry 10294

Latest revision as of 08:34, 23 September 2022

Description

An off-white powder that occurs in nature as the minerals wurtzite and sphalerite. Zinc sulfide slowly oxidizes in moist air to form Zinc sulfate. The synthetic form was introduced as a pigment in 1852 but not widely used by itself due to gray tonalities from impurities. Zinc sulfide is mixed with Barium sulfate to form Lithopone.

Synonyms and Related Terms

zinc sulphide (Br.); zinc blende; CI 77975; Pigment White 7

Risks

  • Sensitive to moisture and air.
  • Contact causes irritation.
  • Fisher Scientific: MSDS

Physical and Chemical Properties

  • Soluble in mineral acids. Insoluble in water.
  • Transparent, colorless crystals with high relief.
  • In crossed polars the crystals are isotropic with very weak birefringence.
  • Fluoresces weak yellow
Composition ZnS
CAS 1314-98-3
Density 3.98 g/ml
Molecular Weight mol. wt. = 97.45
Refractive Index 2.37

Resources and Citations

  • Nicholas Eastaugh, Valentine Walsh, Tracey Chaplin, Ruth Siddall, Pigment Compendium, Elsevier Butterworth-Heinemann, Oxford, 2004
  • The Merck Index, Martha Windholz (ed.), Merck Research Labs, Rahway NJ, 10th edition, 1983 Comment: entry 10294