Difference between revisions of "Ethyl alcohol"

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== Description ==
 
== Description ==
  
A clear, colorless, [http://cameo.mfa.org/materials/fullrecord.asp?name=hygroscopic hygroscopic] liquid with a pleasant odor. Ethyl alcohol, or ethanol, is primarily used as a [http://cameo.mfa.org/materials/fullrecord.asp?name=solvent solvent] and as an intoxicating beverage. Ethanol forms a binary [http://cameo.mfa.org/materials/fullrecord.asp?name=azeotrope azeotrope] with water that boils at 78.15C and contains 95.57% ethanol and 4.43% water. The addition of [http://cameo.mfa.org/materials/fullrecord.asp?name=benzene benzene] allows the mixture to be redistilled without the water. Ethyl alcohol is sold in many grades marked as 95%, absolute (100% or anhydrous), denatured, industrial, or listed as proofs (one-half the proof is the percentage of alcohol). In art and conservation, ethanol has been used as a solvent for [http://cameo.mfa.org/materials/fullrecord.asp?name=shellac shellac] and [http://cameo.mfa.org/materials/fullrecord.asp?name=mastic resin mastic], as a diluent for [http://cameo.mfa.org/materials/fullrecord.asp?name=fixative fixatives], and as a [http://cameo.mfa.org/materials/fullrecord.asp?name=wetting agent wetting agent]. When used as a solvent for resins, the ethanol must be dry because any moisture will produce a white haze in the varnish film.
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A clear, colorless, [[hygroscopic|hygroscopic]] liquid with a pleasant odor. Ethyl alcohol, or ethanol, is primarily used as a [[solvent|solvent]] and as an intoxicating beverage. Ethanol forms a binary [[azeotrope|azeotrope]] with water that boils at 78.15C and contains 95.57% ethanol and 4.43% water. The addition of [[benzene|benzene]] allows the mixture to be redistilled without the water. Ethyl alcohol is sold in many grades marked as 95%, absolute (100% or anhydrous), denatured, industrial, or listed as proofs (one-half the proof is the percentage of alcohol). In art and conservation, ethanol has been used as a solvent for [[shellac|shellac]] and [[mastic%20resin|Mastic]], as a diluent for [[fixative|fixatives]], and as a [[wetting%20agent|wetting agent]]. When used as a solvent for resins, the ethanol must be dry because any moisture will produce a white haze in the varnish film.
  
 
== Synonyms and Related Terms ==
 
== Synonyms and Related Terms ==
  
 
ethanol (IUPAC); alcohol; grain alcohol; absolute alcohol, EtOH, anhydrous alcohol; dehydrated alcohol; ethyl hydrate; ethyl hydroxide; Cologne spirits; colonial spirits; rectified spirits; spirits of wine; fermentation alcohol
 
ethanol (IUPAC); alcohol; grain alcohol; absolute alcohol, EtOH, anhydrous alcohol; dehydrated alcohol; ethyl hydrate; ethyl hydroxide; Cologne spirits; colonial spirits; rectified spirits; spirits of wine; fermentation alcohol
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== Risks ==
  
[[[SliderGallery rightalign|ethyl alcohol.jpg~Chemical structure]]]
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* Highly flammable. Flash point = 14 C (60F). 
 +
* Inhalation, and skin contact can cause irritation.
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* Ingestion of small amounts affects the central nervous system. 
 +
* Ingestion of large amounts is deadly. 
 +
* ThermoFisher: [https://www.fishersci.com/msdsproxy%3FproductName%3DA405P4%26productDescription%3DETHANOL%2BAHYD%2BHISTO%2B4L%26catNo%3DA405P-4%2B%26vendorId%3DVN00033897%26storeId%3D10652 SDS]
  
== Other Properties ==
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== Physical and Chemical Properties ==
  
 
Miscible with water, methanol, ether, chloroform, acetone.
 
Miscible with water, methanol, ether, chloroform, acetone.
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|-
 
|-
 
! scope="row"| Melting Point
 
! scope="row"| Melting Point
| -114.1
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| -114.1 C
 
|-
 
|-
 
! scope="row"| Density
 
! scope="row"| Density
| 0.789
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| 0.789 g/ml
 
|-
 
|-
 
! scope="row"| Molecular Weight
 
! scope="row"| Molecular Weight
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|-
 
|-
 
! scope="row"| Boiling Point
 
! scope="row"| Boiling Point
| 78.5
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| 78.5 C
 
|}
 
|}
 
== Hazards and Safety ==
 
 
Highly flammable. Flash point = 14 C (60F). 
 
 
Inhalation, and skin contact can cause irritation. Ingestion of small amounts affects the central nervous system.  Ingestion of large amounts is deadly. 
 
 
[http://www.cdc.gov/niosh/ipcsneng/neng0044.html International Chemical Safety Card]
 
  
 
== Comparisons ==
 
== Comparisons ==
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[[media:download_file_126.pdf|Properties of Common Solvents]]
 
[[media:download_file_126.pdf|Properties of Common Solvents]]
  
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== Resources and Citations ==
  
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* R. J. Gettens, G.L. Stout, ''Painting Materials, A Short Encyclopaedia'', Dover Publications, New York, 1966
  
== Authority ==
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* Ralph Mayer, ''A Dictionary of Art Terms and Techniques'', Harper and Row Publishers, New York, 1969 (also 1945 printing)
 
 
* R. J. Gettens, G.L. Stout, R. J. Gettens, G.L. Stout, ''Painting Materials, A Short Encyclopaedia'', Dover Publications, New York, 1966
 
 
 
* Ralph Mayer, Ralph Mayer, ''A Dictionary of Art Terms and Techniques'', Harper and Row Publishers, New York, 1969 (also 1945 printing)
 
  
* Richard S. Lewis, Richard S. Lewis, ''Hawley's Condensed Chemical Dictionary'', Van Nostrand Reinhold, New York, 10th ed., 1993
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* Richard S. Lewis, ''Hawley's Condensed Chemical Dictionary'', Van Nostrand Reinhold, New York, 10th ed., 1993
  
* Susan E. Schur, Susan E. Schur, Conservation Terminology: A review of Past & Current Nomenclature of Materials, ''Technology and Conservation'', Spring (p.34-39); Summer (p.35-38); Fall (p.25-36), 1985
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* Susan E. Schur, Conservation Terminology: A review of Past & Current Nomenclature of Materials, ''Technology and Conservation'', Spring (p.34-39); Summer (p.35-38); Fall (p.25-36), 1985
  
 
* ''The Merck Index'', Martha Windholz (ed.), Merck Research Labs, Rahway NJ, 10th edition, 1983  Comment: entry 3806
 
* ''The Merck Index'', Martha Windholz (ed.), Merck Research Labs, Rahway NJ, 10th edition, 1983  Comment: entry 3806
  
* G.S.Brady, G.S.Brady, ''Materials Handbook'', McGraw-Hill Book Co., New York, 1971
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* G.S.Brady, ''Materials Handbook'', McGraw-Hill Book Co., New York, 1971
  
 
* ''Van Nostrand's Scientific Encyclopedia'', Douglas M. Considine (ed.), Van Nostrand Reinhold, New York, 1976
 
* ''Van Nostrand's Scientific Encyclopedia'', Douglas M. Considine (ed.), Van Nostrand Reinhold, New York, 1976
  
* Random House, Random House, ''Webster's Encyclopedic Unabridged Dictionary of the English Language'', Grammercy Book, New York, 1997
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* Random House, ''Webster's Encyclopedic Unabridged Dictionary of the English Language'', Grammercy Book, New York, 1997
  
 
* ''CRC Handbook of Chemistry and Physics'', Robert Weast (ed.), CRC Press, Boca Raton, Florida, v. 61, 1980  Comment: ref. index=1.359
 
* ''CRC Handbook of Chemistry and Physics'', Robert Weast (ed.), CRC Press, Boca Raton, Florida, v. 61, 1980  Comment: ref. index=1.359

Latest revision as of 14:18, 5 August 2022

Description

A clear, colorless, Hygroscopic liquid with a pleasant odor. Ethyl alcohol, or ethanol, is primarily used as a Solvent and as an intoxicating beverage. Ethanol forms a binary Azeotrope with water that boils at 78.15C and contains 95.57% ethanol and 4.43% water. The addition of Benzene allows the mixture to be redistilled without the water. Ethyl alcohol is sold in many grades marked as 95%, absolute (100% or anhydrous), denatured, industrial, or listed as proofs (one-half the proof is the percentage of alcohol). In art and conservation, ethanol has been used as a solvent for Shellac and Mastic, as a diluent for fixatives, and as a Wetting agent. When used as a solvent for resins, the ethanol must be dry because any moisture will produce a white haze in the varnish film.

Synonyms and Related Terms

ethanol (IUPAC); alcohol; grain alcohol; absolute alcohol, EtOH, anhydrous alcohol; dehydrated alcohol; ethyl hydrate; ethyl hydroxide; Cologne spirits; colonial spirits; rectified spirits; spirits of wine; fermentation alcohol

Risks

  • Highly flammable. Flash point = 14 C (60F).
  • Inhalation, and skin contact can cause irritation.
  • Ingestion of small amounts affects the central nervous system.
  • Ingestion of large amounts is deadly.
  • ThermoFisher: SDS

Physical and Chemical Properties

Miscible with water, methanol, ether, chloroform, acetone.

Composition C2H5OH
CAS 64-17-5
Melting Point -114.1 C
Density 0.789 g/ml
Molecular Weight mol. wt.= 46.08
Refractive Index 1.359
Boiling Point 78.5 C

Comparisons

Properties of Common Solvents

Resources and Citations

  • R. J. Gettens, G.L. Stout, Painting Materials, A Short Encyclopaedia, Dover Publications, New York, 1966
  • Ralph Mayer, A Dictionary of Art Terms and Techniques, Harper and Row Publishers, New York, 1969 (also 1945 printing)
  • Richard S. Lewis, Hawley's Condensed Chemical Dictionary, Van Nostrand Reinhold, New York, 10th ed., 1993
  • Susan E. Schur, Conservation Terminology: A review of Past & Current Nomenclature of Materials, Technology and Conservation, Spring (p.34-39); Summer (p.35-38); Fall (p.25-36), 1985
  • The Merck Index, Martha Windholz (ed.), Merck Research Labs, Rahway NJ, 10th edition, 1983 Comment: entry 3806
  • G.S.Brady, Materials Handbook, McGraw-Hill Book Co., New York, 1971
  • Van Nostrand's Scientific Encyclopedia, Douglas M. Considine (ed.), Van Nostrand Reinhold, New York, 1976
  • Random House, Webster's Encyclopedic Unabridged Dictionary of the English Language, Grammercy Book, New York, 1997
  • CRC Handbook of Chemistry and Physics, Robert Weast (ed.), CRC Press, Boca Raton, Florida, v. 61, 1980 Comment: ref. index=1.359