Difference between revisions of "Adipic acid"

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== Description ==
 
== Description ==
  
A white crystalline, solid that occurs naturally in beet juice. Adipic acid is prepared synthetically from cyclohexanol. It is primarily used in the production of [http://cameo.mfa.org/materials/fullrecord.asp?name=nylon resin nylon] and [http://cameo.mfa.org/materials/fullrecord.asp?name=polyurethane polyurethane] foams. Adipic acid is also used as a [http://cameo.mfa.org/materials/fullrecord.asp?name=plasticizer plasticizer], [http://cameo.mfa.org/materials/fullrecord.asp?name=lubricant lubricant], and a food additive in baking powder (in place of [http://cameo.mfa.org/materials/fullrecord.asp?name=cream of tartar cream of tartar]) and in beverages (in place of [http://cameo.mfa.org/materials/fullrecord.asp?name=citric acid citric acid]). It is not [http://cameo.mfa.org/materials/fullrecord.asp?name=hygroscopic hygroscopic]. Prior to 1940, adipic acid was also used for bronzing metals, preparing photographic paper, textile dyeing, and as a component in synthetic wax sizes mixed with [http://cameo.mfa.org/materials/fullrecord.asp?name=glycerol glycerol], [http://cameo.mfa.org/materials/fullrecord.asp?name=stearic acid stearic acid], and [http://cameo.mfa.org/materials/fullrecord.asp?name=palmitic acid palmitic acid].
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A white crystalline, solid that occurs naturally in beet juice. Adipic acid is prepared synthetically from cyclohexanol. It is primarily used in the production of [[nylon%20resin|Nylon]] and [[polyurethane|polyurethane]] foams. Adipic acid is also used as a [[plasticizer|plasticizer]], [[lubricant|lubricant]], and a food additive in baking powder (in place of [[cream%20of%20tartar|cream of tartar]]) and in beverages (in place of [[citric%20acid|citric acid]]). It is not [[hygroscopic|hygroscopic]]. Prior to 1940, adipic acid was also used for bronzing metals, preparing photographic paper, textile dyeing, and as a component in synthetic wax sizes mixed with [[glycerol|glycerol]], [[stearic%20acid|stearic acid]], and [[palmitic%20acid|palmitic acid]].  Adipic acid may evolve from degraded polyurethane ester-type foams (Tétreault 2017).
  
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[[[SliderGallery rightalign|aaiADIPIC.jpg~FTIR|adipic acid.jpg~Chemical structure]]]
 
== Synonyms and Related Terms ==
 
== Synonyms and Related Terms ==
  
hexanedioic acid; 1,4-butanedicarboxylic acid; adipinic acid' Adipinsure (Deut.); acide adipique (Fr.); acide 1,6-hexanedioque (Fr.);
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hexanedioic acid; 1,4-butanedicarboxylic acid; adipinic acid' Adipinsäure (Deut.); acide adipique (Fr.); acide 1,6-hexanedioïque (Fr.);
 
 
[[[SliderGallery rightalign|aaiADIPIC.jpg~FTIR|adipic acid.jpg~Chemical structure]]]
 
 
 
== Other Properties ==
 
  
Soluble in methanol, ethanol, ethyl acetate, acetone. Slightly soluble in water, cyclohexane. Insoluble in benzene, ligroin.
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==Risks==
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* Can cause corrosion in copper, zinc and bronze
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* Fisher Scientific: [https://www.fishersci.com/store/msds?partNumber=S25124&productDescription=ADIPIC+ACID+POWDER+500G&vendorId=VN00115888&countryCode=US&language=en SDS]
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== Physical and Chemical Properties ==
  
pH of a saturated solution is 2.7
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* Soluble in methanol, ethanol, ethyl acetate, acetone. Slightly soluble in water, cyclohexane. Insoluble in benzene, ligroin. 
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* pH of a saturated solution is 2.7
  
 
{| class="wikitable"
 
{| class="wikitable"
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|-
 
|-
 
! scope="row"| Melting Point
 
! scope="row"| Melting Point
| 152
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| 152 C
 
|-
 
|-
 
! scope="row"| Density
 
! scope="row"| Density
| 1.360
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| 1.360 g/ml
 
|-
 
|-
 
! scope="row"| Molecular Weight
 
! scope="row"| Molecular Weight
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|-
 
|-
 
! scope="row"| Boiling Point
 
! scope="row"| Boiling Point
| 337.5
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| 337.5 C
 
|}
 
|}
  
== Hazards and Safety ==
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== Resources and Citations ==
 
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* Jean Tétreault, 'Products used in Preventive Conservation' Technical Bulletin #2, CCI, 2017. [https://www.canada.ca/en/conservation-institute/services/conservation-preservation-publications/technical-bulletins/products-used-preventive-conservation.html#a2c1 Link]
[http://www.cdc.gov/niosh/ipcsneng/neng0369.html International Chemical Safety Card]
 
 
 
== Authority ==
 
  
* G.S.Brady, G.S.Brady, ''Materials Handbook'', McGraw-Hill Book Co., New York, 1971  Comment: p. 17
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* G.S.Brady, ''Materials Handbook'', McGraw-Hill Book Co., New York, 1971  Comment: p. 17
  
* Richard S. Lewis, Richard S. Lewis, ''Hawley's Condensed Chemical Dictionary'', Van Nostrand Reinhold, New York, 10th ed., 1993
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* Richard S. Lewis, ''Hawley's Condensed Chemical Dictionary'', Van Nostrand Reinhold, New York, 10th ed., 1993
  
 
* ''The Merck Index'', Martha Windholz (ed.), Merck Research Labs, Rahway NJ, 10th edition, 1983  Comment: entry # 161
 
* ''The Merck Index'', Martha Windholz (ed.), Merck Research Labs, Rahway NJ, 10th edition, 1983  Comment: entry # 161

Latest revision as of 11:39, 20 November 2022

Description

A white crystalline, solid that occurs naturally in beet juice. Adipic acid is prepared synthetically from cyclohexanol. It is primarily used in the production of Nylon and Polyurethane foams. Adipic acid is also used as a Plasticizer, Lubricant, and a food additive in baking powder (in place of Cream of tartar) and in beverages (in place of Citric acid). It is not Hygroscopic. Prior to 1940, adipic acid was also used for bronzing metals, preparing photographic paper, textile dyeing, and as a component in synthetic wax sizes mixed with Glycerol, Stearic acid, and Palmitic acid. Adipic acid may evolve from degraded polyurethane ester-type foams (Tétreault 2017).

FTIR

AaiADIPIC.jpg

Chemical structure

Adipic acid.jpg

Synonyms and Related Terms

hexanedioic acid; 1,4-butanedicarboxylic acid; adipinic acid' Adipinsäure (Deut.); acide adipique (Fr.); acide 1,6-hexanedioïque (Fr.);

Risks

  • Can cause corrosion in copper, zinc and bronze
  • Fisher Scientific: SDS

Physical and Chemical Properties

  • Soluble in methanol, ethanol, ethyl acetate, acetone. Slightly soluble in water, cyclohexane. Insoluble in benzene, ligroin.
  • pH of a saturated solution is 2.7
Composition COOH(CH2)4COOH
CAS 124-04-9
Melting Point 152 C
Density 1.360 g/ml
Molecular Weight mol. wt. = 146.14
Boiling Point 337.5 C

Resources and Citations

  • Jean Tétreault, 'Products used in Preventive Conservation' Technical Bulletin #2, CCI, 2017. Link
  • G.S.Brady, Materials Handbook, McGraw-Hill Book Co., New York, 1971 Comment: p. 17
  • Richard S. Lewis, Hawley's Condensed Chemical Dictionary, Van Nostrand Reinhold, New York, 10th ed., 1993
  • The Merck Index, Martha Windholz (ed.), Merck Research Labs, Rahway NJ, 10th edition, 1983 Comment: entry # 161