Difference between revisions of "Butadiene"

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== Description ==
 
== Description ==
  
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A colorless, flammable gas obtained from [http://cameo.mfa.org/materials/fullrecord.asp?name=petroleum petroleum], [http://cameo.mfa.org/materials/fullrecord.asp?name=acetylene acetylene] or from [http://cameo.mfa.org/materials/fullrecord.asp?name=ethyl%20alcohol ethanol]. Butadiene polymerizes readily in the presence of [http://cameo.mfa.org/materials/fullrecord.asp?name=oxygen oxygen] to form a rubbery polymer.  It was first polymerized in Russia by Sergei Lebedev in 1910. By the 1930s, many countries developed butadiene production capabilities as a replacement for natural rubber.  Currently, butadiene is primarily used as a starting material for synthetic elastomers.  
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A colorless, flammable gas obtained from [[petroleum]], [[acetylene]] or from [[ethyl%20alcohol|ethanol]]. Butadiene polymerizes readily in the presence of [[oxygen]] to form a rubbery polymer.  It was first polymerized in Russia by Sergei Lebedev in 1910. By the 1930s, many countries developed butadiene production capabilities as a replacement for natural rubber.  Currently, butadiene is primarily used as a starting material for synthetic elastomers.  
  
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See [http://cameo.mfa.org/materials/fullrecord.asp?name=Buna Buna], [http://cameo.mfa.org/materials/fullrecord.asp?name=acrylonitrile%20butadiene%20styrene%20resin ABS resin], [http://cameo.mfa.org/materials/fullrecord.asp?name=neoprene neoprene], and [http://cameo.mfa.org/materials/fullrecord.asp?name=polybutadiene polybutadiene].
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See [[Buna]], [[acrylonitrile%20butadiene%20styrene|ABS resin]], [[neoprene]], and [[polybutadiene]].
  
 
== Synonyms and Related Terms ==
 
== Synonyms and Related Terms ==
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1,3-butadiene; bivinyl; divinyl B; erythrene; vinyl ethylene; biethylene; pyrrollylene; methylallene; Butadien (Deut.); butadieen (Ned.)
 
1,3-butadiene; bivinyl; divinyl B; erythrene; vinyl ethylene; biethylene; pyrrollylene; methylallene; Butadien (Deut.); butadieen (Ned.)
  
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== Other Properties ==
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== Risks ==
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Contact can cause frostbite and irritation to membranes.  Inhalation is toxic. Suspected human carcinogen. Highly flammable and explosive. Flash point = -85 C 
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Airgas: [https://www.airgas.com/msds/001008.pdf SDS]
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== Physical and Chemical Properties ==
  
 
Soluble in alcohols, ether, petroleum solvents, carbon tetrachloride. Insoluble in water.
 
Soluble in alcohols, ether, petroleum solvents, carbon tetrachloride. Insoluble in water.
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! scope="row"| Melting Point
 
! scope="row"| Melting Point
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| -108.9
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| -108.9 C
 
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! scope="row"| Density
 
! scope="row"| Density
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| 0.64 (liquid)
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| 0.64 g/ml (liquid)
 
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|-
 
! scope="row"| Molecular Weight
 
! scope="row"| Molecular Weight
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! scope="row"| Boiling Point
 
! scope="row"| Boiling Point
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| -4.41
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| -4.41 C
 
|}
 
|}
  
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== Hazards and Safety ==
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== Resources and Citations ==
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Contact can cause frostbite and irritation to membranes.  Inhalation is toxic. Suspected human carcinogen. Highly flammable and explosive. Flash point = -85 C 
 
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LINK: [http://www.cdc.gov/niosh/ipcsneng/neng0017.html International Chemical Safety Card]
 
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== Authority ==
 
  
 
* ''The Merck Index'', Martha Windholz (ed.), Merck Research Labs, Rahway NJ, 10th edition, 1983  Comment: entry 1534
 
* ''The Merck Index'', Martha Windholz (ed.), Merck Research Labs, Rahway NJ, 10th edition, 1983  Comment: entry 1534
  
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* Wikipedia, the free encyclopedia, at http://www.wikipedia.com  Comment: http://en.wikipedia.org/wiki/Butadiene (Accessed Mar. 20, 2006)
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* Wikipedia: http://en.wikipedia.org/wiki/Butadiene (Accessed Mar. 20, 2006)
  
 
* G.S.Brady, ''Materials Handbook'', McGraw-Hill Book Co., New York, 1971  Comment: p. 126
 
* G.S.Brady, ''Materials Handbook'', McGraw-Hill Book Co., New York, 1971  Comment: p. 126

Latest revision as of 08:14, 11 May 2022

Description

A colorless, flammable gas obtained from Petroleum, Acetylene or from ethanol. Butadiene polymerizes readily in the presence of Oxygen to form a rubbery polymer. It was first polymerized in Russia by Sergei Lebedev in 1910. By the 1930s, many countries developed butadiene production capabilities as a replacement for natural rubber. Currently, butadiene is primarily used as a starting material for synthetic elastomers.

See Buna, ABS resin, Neoprene, and Polybutadiene.

Synonyms and Related Terms

1,3-butadiene; bivinyl; divinyl B; erythrene; vinyl ethylene; biethylene; pyrrollylene; methylallene; Butadien (Deut.); butadieen (Ned.)

Risks

Contact can cause frostbite and irritation to membranes. Inhalation is toxic. Suspected human carcinogen. Highly flammable and explosive. Flash point = -85 C

Airgas: SDS

Physical and Chemical Properties

Soluble in alcohols, ether, petroleum solvents, carbon tetrachloride. Insoluble in water.

Composition H2C:CHHC:CH2
CAS 106-99-0
Melting Point -108.9 C
Density 0.64 g/ml (liquid)
Molecular Weight mol. wt. = 54.1
Boiling Point -4.41 C

Resources and Citations

  • The Merck Index, Martha Windholz (ed.), Merck Research Labs, Rahway NJ, 10th edition, 1983 Comment: entry 1534
  • G.S.Brady, Materials Handbook, McGraw-Hill Book Co., New York, 1971 Comment: p. 126
  • Theodore J. Reinhart, 'Glossary of Terms', Engineered Plastics, ASM International, 1988
  • Richard S. Lewis, Hawley's Condensed Chemical Dictionary, Van Nostrand Reinhold, New York, 10th ed., 1993
  • Random House, Webster's Encyclopedic Unabridged Dictionary of the English Language, Grammercy Book, New York, 1997
  • The American Heritage Dictionary or Encarta, via Microsoft Bookshelf 98, Microsoft Corp., 1998

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