Difference between revisions of "Perchloroethylene"

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Colorless chlorinated hydrocarbon with an ether-like odor. Perchloroethylene is used as a dry-cleaning [[solvent|solvent]] and as a vapor-degreaser for [[metal|metals]].
 
Colorless chlorinated hydrocarbon with an ether-like odor. Perchloroethylene is used as a dry-cleaning [[solvent|solvent]] and as a vapor-degreaser for [[metal|metals]].
 
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[[[SliderGallery rightalign|perchloroethylene.jpg~Chemical structure]]]
 
== Synonyms and Related Terms ==
 
== Synonyms and Related Terms ==
  
 
tetrachloroethylene; TCE; tetrachloroethene; ethylene tetrachloride; Perclene; Vaclene [DuPont]
 
tetrachloroethylene; TCE; tetrachloroethene; ethylene tetrachloride; Perclene; Vaclene [DuPont]
  
[[[SliderGallery rightalign|perchloroethylene.jpg~Chemical structure]]]
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== Risks ==
  
== Other Properties ==
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* Irritating to eyes and skin. 
 +
* Potential carcinogen. 
 +
* Nonflammable, but may decompose in the presence of flames, hot surfaces or UV light to form toxic and corrosive fumes (hydrogen chloride, phosgene, chlorine).
 +
* Decomposes slowly on contact with moisture producing trichloroacetic acid and hydrochloric acid.
 +
* Cisco: [http://www.ciscochem.com/assets/perchloroethylene-sds.pdf SDS]
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==Physical and Chemical Properties==
  
 
Miscible in ethanol, ether, chloroform, benzene. Insoluble in water.
 
Miscible in ethanol, ether, chloroform, benzene. Insoluble in water.
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|-
 
|-
 
! scope="row"| Melting Point
 
! scope="row"| Melting Point
| 22
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| 22 C
 
|-
 
|-
 
! scope="row"| Density
 
! scope="row"| Density
| 1.6230
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| 1.6230 g/ml
 
|-
 
|-
 
! scope="row"| Molecular Weight
 
! scope="row"| Molecular Weight
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|-
 
|-
 
! scope="row"| Boiling Point
 
! scope="row"| Boiling Point
| 121
+
| 121 C
 
|}
 
|}
  
== Hazards and Safety ==
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==Resources and Citations==
 
 
Irritating to eyes and skin.  Potential carcinogen.  Nonflammable, but may decompose in the presence of flames, hot surfaces or UV light to form toxic and corrosive fumes (hydrogen chloride, phosgene, chlorine). Decomposes slowly on contact with moisture producing trichloroacetic acid and hydrochloric acid. 
 
 
 
[http://www.cdc.gov/niosh/ipcsneng/neng0076.html International Chemical Safety Card]
 
 
 
== Sources Checked for Data in Record ==
 
  
 
* ''The Merck Index'', Susan Budavari (ed.), Merck Research Labs, Whitehouse Station, NJ, 12th Edition, 1996
 
* ''The Merck Index'', Susan Budavari (ed.), Merck Research Labs, Whitehouse Station, NJ, 12th Edition, 1996

Latest revision as of 14:34, 10 August 2022

Description

Colorless chlorinated hydrocarbon with an ether-like odor. Perchloroethylene is used as a dry-cleaning Solvent and as a vapor-degreaser for metals.

Chemical structure

Perchloroethylene.jpg

Synonyms and Related Terms

tetrachloroethylene; TCE; tetrachloroethene; ethylene tetrachloride; Perclene; Vaclene [DuPont]

Risks

  • Irritating to eyes and skin.
  • Potential carcinogen.
  • Nonflammable, but may decompose in the presence of flames, hot surfaces or UV light to form toxic and corrosive fumes (hydrogen chloride, phosgene, chlorine).
  • Decomposes slowly on contact with moisture producing trichloroacetic acid and hydrochloric acid.
  • Cisco: SDS

Physical and Chemical Properties

Miscible in ethanol, ether, chloroform, benzene. Insoluble in water.

Composition Cl2C:CCl2
CAS 127-18-4
Melting Point 22 C
Density 1.6230 g/ml
Molecular Weight mol. wt. = 165.8
Refractive Index 1.5055
Boiling Point 121 C

Resources and Citations

  • The Merck Index, Susan Budavari (ed.), Merck Research Labs, Whitehouse Station, NJ, 12th Edition, 1996
  • Michael McCann, Artist Beware, Watson-Guptill Publications, New York City, 1979
  • Richard S. Lewis, Hawley's Condensed Chemical Dictionary, Van Nostrand Reinhold, New York, 10th ed., 1993
  • Hoechst Celanese Corporation, Dictionary of Fiber & Textile Technology (older version called Man-made Fiber and Textile Dictionary, 1965), Hoechst Celanese Corporation, Charlotte NC, 1990