Difference between revisions of "Copper acetate, basic"
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== Description == | == Description == | ||
| − | A blue green crystalline powder called [http://cameo.mfa.org/materials/fullrecord.asp?name=verdigris verdigris]. Basic copper acetate has been prepared since ancient times by exposing copper to vapors of fermenting grape skin solutions. It is a complex compound that contains cupric acetate, cupric hydroxide and water in varying proportions. Common verdigris, or green verdigris, has the proportions of 2:1:5 (cupric acetate: cupric hydroxide:water) while French verdigris, or blue verdigris, has the proportions of 1:1:5, respectively. When combined with terpenoid resins, such as [http://cameo.mfa.org/materials/fullrecord.asp?name=Venice | + | A blue green crystalline powder called [http://cameo.mfa.org/materials/fullrecord.asp?name=verdigris verdigris]. Basic copper acetate has been prepared since ancient times by exposing copper to vapors of fermenting grape skin solutions. It is a complex compound that contains cupric acetate, cupric hydroxide and water in varying proportions. Common verdigris, or green verdigris, has the proportions of 2:1:5 (cupric acetate: cupric hydroxide:water) while French verdigris, or blue verdigris, has the proportions of 1:1:5, respectively. When combined with terpenoid resins, such as [http://cameo.mfa.org/materials/fullrecord.asp?name=Venice%20turpentine Venice turpentine], verdigris forms [http://cameo.mfa.org/materials/fullrecord.asp?name=copper%20resinate copper resinate]. Verdigris is also used as a pesticide, fungicide, catalyst, textile dye and pigment for paints, ceramics. |
Note: The term verdigris is also commonly, but incorrectly, applied to any blue-green patina formed on outdoor copper. | Note: The term verdigris is also commonly, but incorrectly, applied to any blue-green patina formed on outdoor copper. | ||
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== Synonyms and Related Terms == | == Synonyms and Related Terms == | ||
| − | verdigris, acetato | + | verdigris, acetato básico de cobre (Esp.); cardenillo (Esp.); acetate de cuivre (Fr.); acetato di rame basico (It.); acetato básico de cobre (Port.); copper subacetate; common verdigris; green verdigris; French verdigris; blue verdigris |
== Other Properties == | == Other Properties == | ||
| Line 30: | Line 30: | ||
== Authority == | == Authority == | ||
| − | * | + | * Richard S. Lewis, ''Hawley's Condensed Chemical Dictionary'', Van Nostrand Reinhold, New York, 10th ed., 1993 |
* ''The Merck Index'', Martha Windholz (ed.), Merck Research Labs, Rahway NJ, 10th edition, 1983 Comment: entry #2691 | * ''The Merck Index'', Martha Windholz (ed.), Merck Research Labs, Rahway NJ, 10th edition, 1983 Comment: entry #2691 | ||
| − | * | + | * R. J. Gettens, G.L. Stout, ''Painting Materials, A Short Encyclopaedia'', Dover Publications, New York, 1966 |
* ''Dictionary of Building Preservation'', Ward Bucher, ed., John Wiley & Sons, Inc., New York City, 1996 | * ''Dictionary of Building Preservation'', Ward Bucher, ed., John Wiley & Sons, Inc., New York City, 1996 | ||
| − | * | + | * Susan E. Schur, Conservation Terminology: A review of Past & Current Nomenclature of Materials, ''Technology and Conservation'', Spring (p.34-39); Summer (p.35-38); Fall (p.25-36), 1985 |
[[Category:Materials database]] | [[Category:Materials database]] | ||
Revision as of 06:49, 24 July 2013
Description
A blue green crystalline powder called verdigris. Basic copper acetate has been prepared since ancient times by exposing copper to vapors of fermenting grape skin solutions. It is a complex compound that contains cupric acetate, cupric hydroxide and water in varying proportions. Common verdigris, or green verdigris, has the proportions of 2:1:5 (cupric acetate: cupric hydroxide:water) while French verdigris, or blue verdigris, has the proportions of 1:1:5, respectively. When combined with terpenoid resins, such as Venice turpentine, verdigris forms copper resinate. Verdigris is also used as a pesticide, fungicide, catalyst, textile dye and pigment for paints, ceramics.
Note: The term verdigris is also commonly, but incorrectly, applied to any blue-green patina formed on outdoor copper.
Synonyms and Related Terms
verdigris, acetato básico de cobre (Esp.); cardenillo (Esp.); acetate de cuivre (Fr.); acetato di rame basico (It.); acetato básico de cobre (Port.); copper subacetate; common verdigris; green verdigris; French verdigris; blue verdigris
Other Properties
Soluble in acids and ammonia. Slightly soluble in ethanol, water.
| Composition | Cu(C2H3O2).CuO(OH)2 |
|---|---|
| Refractive Index | 1.53; 1.56 |
Hazards and Safety
Toxic by ingestion.
May turn brown or black in contact with air.
Authority
- Richard S. Lewis, Hawley's Condensed Chemical Dictionary, Van Nostrand Reinhold, New York, 10th ed., 1993
- The Merck Index, Martha Windholz (ed.), Merck Research Labs, Rahway NJ, 10th edition, 1983 Comment: entry #2691
- R. J. Gettens, G.L. Stout, Painting Materials, A Short Encyclopaedia, Dover Publications, New York, 1966
- Dictionary of Building Preservation, Ward Bucher, ed., John Wiley & Sons, Inc., New York City, 1996
- Susan E. Schur, Conservation Terminology: A review of Past & Current Nomenclature of Materials, Technology and Conservation, Spring (p.34-39); Summer (p.35-38); Fall (p.25-36), 1985