Difference between revisions of "Methyl red"
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== Description == | == Description == | ||
| − | A reddish-violet powder that was formerly used as an acid-base [http://cameo.mfa.org/materials/fullrecord.asp?name=indicator | + | A reddish-violet powder that was formerly used as an acid-base [http://cameo.mfa.org/materials/fullrecord.asp?name=indicator%20dye indicator]. Methyl red is a monoazo dye that was discovered by E. Rupp and R. Loose in 1908. When mixed as a 0.1% alcoholic solution, methyl red has a red color below pH 4.4 and yellow above pH 6.2. It has been used for titrating [http://cameo.mfa.org/materials/fullrecord.asp?name=ammonium%20hydroxide ammonia] and weak organic bases, but it is not suitable for titrating acids. Currently, methyl red is rarely used because it is easily reduced to a colorless form. |
== Synonyms and Related Terms == | == Synonyms and Related Terms == | ||
| − | Acid Red 2; CI 13020; 2-[[(4-dimethylamino)phenyl]-azo]benzoic acid; 4'-dimethylaminoazobenzene-2-carboxylic acid; rojo de metilo (Esp.); rouge | + | Acid Red 2; CI 13020; 2-[[(4-dimethylamino)phenyl]-azo]benzoic acid; 4'-dimethylaminoazobenzene-2-carboxylic acid; rojo de metilo (Esp.); rouge méthyle (Fr.); vermelho de metilo (Port.) |
[[[SliderGallery rightalign|methyl red.jpg~Chemical structure]]] | [[[SliderGallery rightalign|methyl red.jpg~Chemical structure]]] | ||
| Line 40: | Line 40: | ||
== Authority == | == Authority == | ||
| − | * | + | * G.S.Brady, ''Materials Handbook'', McGraw-Hill Book Co., New York, 1971 Comment: p. 184 |
| − | * | + | * Richard S. Lewis, ''Hawley's Condensed Chemical Dictionary'', Van Nostrand Reinhold, New York, 10th ed., 1993 |
| − | * | + | * Random House, ''Webster's Encyclopedic Unabridged Dictionary of the English Language'', Grammercy Book, New York, 1997 |
* ''The Merck Index'', Martha Windholz (ed.), Merck Research Labs, Rahway NJ, 10th edition, 1983 Comment: entry 6199 | * ''The Merck Index'', Martha Windholz (ed.), Merck Research Labs, Rahway NJ, 10th edition, 1983 Comment: entry 6199 | ||
| − | * | + | * S.R.Trotman, E.R. Trotman, ''Textile Analysis'', J.B. Lippincott Company, Philadelphia, 1932 |
* Colour Index International online at www.colour-index.org | * Colour Index International online at www.colour-index.org | ||
Revision as of 06:50, 24 July 2013
Description
A reddish-violet powder that was formerly used as an acid-base indicator. Methyl red is a monoazo dye that was discovered by E. Rupp and R. Loose in 1908. When mixed as a 0.1% alcoholic solution, methyl red has a red color below pH 4.4 and yellow above pH 6.2. It has been used for titrating ammonia and weak organic bases, but it is not suitable for titrating acids. Currently, methyl red is rarely used because it is easily reduced to a colorless form.
Synonyms and Related Terms
Acid Red 2; CI 13020; 2-[[(4-dimethylamino)phenyl]-azo]benzoic acid; 4'-dimethylaminoazobenzene-2-carboxylic acid; rojo de metilo (Esp.); rouge méthyle (Fr.); vermelho de metilo (Port.)
Other Properties
Soluble in ethanol and acetic acid. Insoluble in water.
| Composition | (CH3)2NC6H4NNC6H4COOH |
|---|---|
| CAS | 493-52-7 |
| Melting Point | 181-182 |
| Molecular Weight | mol. wt. = 269.29 |
Hazards and Safety
Toxic by ingestion and inhalation. Contact may cause irritation
Potential carcinogen.
Flammable. Flash point = 12 C
Fisher Scientific: MSDS
Authority
- G.S.Brady, Materials Handbook, McGraw-Hill Book Co., New York, 1971 Comment: p. 184
- Richard S. Lewis, Hawley's Condensed Chemical Dictionary, Van Nostrand Reinhold, New York, 10th ed., 1993
- Random House, Webster's Encyclopedic Unabridged Dictionary of the English Language, Grammercy Book, New York, 1997
- The Merck Index, Martha Windholz (ed.), Merck Research Labs, Rahway NJ, 10th edition, 1983 Comment: entry 6199
- S.R.Trotman, E.R. Trotman, Textile Analysis, J.B. Lippincott Company, Philadelphia, 1932
- Colour Index International online at www.colour-index.org