Rubber (natural, vulcanized)

MFA Acc. #: 97.160

Description

A natural hydrocarbon polymer formed from the latex of Euphorbiaceae trees, such as Hevea brasiliensis or Parthenium argentatum. To prepare natural rubber, the latex is collected from a cut in the bark, precipitated with acid, then washed and dried. Rubber is very elastic and was used for bowls, shoe soles, adhesives and bouncy balls. However, when cooled, rubber becomes brittle and when warmed it becomes sweaty and tacky. Prior to the development of synthetic resins, unvulcanized rubber was used for adhesive tapes and crepe shoe soles.

In 1839, Charles Goodyear discovered that rubber can be hardened with the Vulcanization process in which Sulfur is used to initiate crosslinking of the hydrocarbon strands. Higher sulfur content produces a harder, denser material. Vulcanized rubber is used to make rubber bands, foams, fabric coatings, small objects, combs, pens and musical instruments. Vulcanized rubber, however, will emit sulfur when exposed to light or heat causing the rubber to degrade and become brittle. Since the 19th century, small amounts of Wax have been added to the rubber during vulcanization. The wax slowly migrates to the surface and provides a thin layer of protection from Oxidation.

See also Rubber, synthetic

Synonyms and Related Terms

caucho (Esp.); caoutchouc naturel (Fr.); gomma naturale (It.); borracha natural (Port.); Vulcanite; Ebonite; natural rubber; Hevea brasiliensis; Parthenium argentatum

FTIR(MFA)

Applications

Historical applications ex. gasketing, shock mounts

Physical and Chemical Properties

• Burns with dark yellow, sooty flame; smells of burnt rubber
• Nonvulcanized rubber becomes brittle at cold temperatures (-34 C) and weakens when heated (66 C).
• Vulcanized rubber degrades at temperatures above 93 C.
• Density = 0.92-1.0
• Spot test for vulcanized rubber: Iodine/sodium azide reagent for presence of reducible sulfur compounds - positive reaction generates bubbles (Daniels and Ward, 1982)

Collection Risks

Vulcanized rubber may emit sulfur fumes that will tarnish metals and stain organic materials.

Resources and Citations

• M.Baker, E.McManus, "History, Care and Handling of America's Spacesuits" JAIC 31:77-85 1992 ° V.Daniels, S.Ward, "A Rapid Test for the Detection of Substances which will Tarnish Silver" Studies in Conservation 27:58-60, 1982.

• G.S.Brady, Materials Handbook, McGraw-Hill Book Co., New York, 1971 Comment: p. 674

• Encyclopedia Britannica, http://www.britannica.com Comment: "rubber" Encyclopædia Britannica [Accessed February 13, 2002]

• Pam Hatchfield, Pollutants in the Museum Environment, Archetype Press, London, 2002

• Marjorie Shelley, The Care and Handling of Art Objects, The Metropolitan Museum, New York, 1987

• Rosalie Rosso King, Textile Identification, Conservation, and Preservation, Noyes Publications, Park Ridge, NJ, 1985

• Michael McCann, Artist Beware, Watson-Guptill Publications, New York City, 1979

• Edward Reich, Carlton J. Siegler, Consumer Goods: How to Know and Use Them, American Book Company, New York City, 1937

• M. Baker, E. McManus, 'History, Care and Handling of America's Spacesuits', JAIC, 31, 77-85, 1992

• Theodore J. Reinhart, 'Glossary of Terms', Engineered Plastics, ASM International, 1988

• Art and Architecture Thesaurus Online, http://www.getty.edu/research/tools/vocabulary/aat/, J. Paul Getty Trust, Los Angeles, 2000

• Website address 1 Comment: www.nswpmith.com.au/historyofplastics.html