Sulfite process

Softwood bleached sulfite fibers stained with Graff "C" Stain at 10x

Description

Hardwood sulfite pulp stained with Graff "C" stain at 40x

A chemical method of producing paper pulp from wood using high heat and Sulfur dioxide. The sulfite process was first patented in 1867, but not in wide use until improvements were made in the 1870s-1880s. To produce pulp, wood chips are cooked in a solution of sulfur dioxide dissolved in an alkaline solution (typically a calcium base). The cooking or steaming process produces bisulfite and then monosulfite, which dissolve lignin and hemicellulose. This method produces a bleachable pulp with a high yield, low cost, and high brightness. However, only limited wood species can be used and the waste recovery system is not as environmentally friendly as other methods. Softwood species such as Spruce, Balsam fir, Western hemlock are commonly used. This process is not appropriate for dense hardwoods, but can be used for Poplar and Birch. The sulfite process can produce high quality pulps, particularly when bleached. Since improvements to the Kraft process in the 1930s, the sulfite process has decreased in popularity. Since 1990, sulfite pulps account for less than 10% of production in the US.

Synonyms and Related Terms

Sulfite pulp; sulfite pulping; softwood bleached sulfite; softwood sulfite; hardwood bleached sulfite; hardwood sulfite

Physical and Chemical Properties

When stained with Graff "C" stain, sulfite pulp can appear in a range of colors depending on the wood type (softwood or hardwood) and the amount of bleaching. Unbleached sulfite pulps will appear yellow or grey. With increased bleaching, pulps will appear lighter and tend more toward red or purple when treated with stain. The stained color of sulfite pulp tends to be lighter than kraft pulp.

Additional Images

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  Softwood (larch) sulfite pulp stained with Graff "C" stain at 10x

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  Softwood (Red cedar) sulfite pulp stained with Graff "C" stain at 10x

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  Softwood (Spruce) sulfite pulp stained with Graff "C" stain at 10x

Resources and Citations

• J.R.G. Bryce.“Sulfite Pulping” and “Alkaline Pulping”. Pulp and Paper: Chemistry and Chemical Technology, Volume 1, Edition 3. John Wiley & Sons, 1980. James P. Casey Ed.
• Christopher Biermann. Essentials of Pulping and Papermaking. Academic Press, 1993.
• J. H. Graff "Color Atlas for Fiber Identification" The Institute of Paper Chemistry, Appleton, WI, 1940.
• Walter Rantanen. "Fiber ID Course." Integrated Paper Services. June 2013. Lecture.
• TAPPI Official Standard T401 om-08. Fiber analysis of paper and paperboard. 2008. http://www.tappi.org/Downloads/Test-Methods/UNTITLED-0104T401pdf.aspx