Sodium dithionite

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Description

Pale yellow powder that is used as a agent reducing agent in dyeing indigo and dye vat dyes. Sodium dithionite is also used to strip dyes from dyed textiles and reduce stain iron oxide stains to oxide ferrous oxide. Sodium dithionite was also used as a agent bleach for leather and wood pulp mechanical paper pulps but its use has declined in recent years due to poor color reversion properties (AIC Book and Paper Catalog).

Note: this is not the same compound as thiosulfate sodium thiosulfate (Na2S2O3; also called sodium hyposulfite) that is used for fixation in photography.

Synonyms and Related Terms

sodium thiosulfite; sodium hydrosulfite; sodium sulfoxylate

Chemical structure

Sodium dithionite.jpg


Other Properties

Soluble in water (pH = 6.0-7.5 for 1-6% solution). Insoluble in ethanol.

Composition Na2S2O4
CAS 7775-14-6
Melting Point 52-55
Density 2.19
Molecular Weight mol. wt. = 174.1

Hazards and Safety

Fire risk in contact with moisture and air. Use dry sand to extinguish fires. Flash point=90 C

Contact causes irritation

Mallinckrodt Baker: MSDS

Additional Information

AIC Book and Paper Catalog, p.

Authority

  • G.S.Brady, G.S.Brady, Materials Handbook, McGraw-Hill Book Co., New York, 1971 Comment: p. 786
  • Richard S. Lewis, Richard S. Lewis, Hawley's Condensed Chemical Dictionary, Van Nostrand Reinhold, New York, 10th ed., 1993
  • Matt Roberts, Don Etherington, Matt Roberts, Don Etherington, Bookbinding and the Conservation of Books: a Dictionary of Descriptive Terminology, U.S. Government Printing Office, Washington DC, 1982
  • Book and Paper Group, Book and Paper Group, Paper Conservation Catalog, AIC, 1984, 1989
  • The Dictionary of Paper, American Paper Institute, New York, Fourth Edition, 1980
  • Van Nostrand's Scientific Encyclopedia, Douglas M. Considine (ed.), Van Nostrand Reinhold, New York, 1976
  • The Merck Index, Martha Windholz (ed.), Merck Research Labs, Rahway NJ, 10th edition, 1983 Comment: entry 8771

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