Difference between revisions of "Calcium nitrate"

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A white, deliquescent solid that is a strong oxidizing agent.  Calcium nitrate was first produced commercially in Notodden, Norway in 1905.  It is used in pyrotechnics, explosives, and match heads. Calcium nitrate has been identified as a deleterious accretion in wall paintings (Piqué et al 1992).  The efflorescence also occurs when manure or other nitrogeneous compounds contact limestone in a dry environment.
 
A white, deliquescent solid that is a strong oxidizing agent.  Calcium nitrate was first produced commercially in Notodden, Norway in 1905.  It is used in pyrotechnics, explosives, and match heads. Calcium nitrate has been identified as a deleterious accretion in wall paintings (Piqué et al 1992).  The efflorescence also occurs when manure or other nitrogeneous compounds contact limestone in a dry environment.
 
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[[[SliderGallery rightalign|Calcium nitrate.TIF~FTIR (MFA)]]]
 
== Synonyms and Related Terms ==
 
== Synonyms and Related Terms ==
  
 
calcium dinitrate; lime nitrate; nitrocalcite; lime saltpeter; Norwegian saltpeter (Norgessalpeter); air saltpeter; calciumnitrat (Dan.); Kalksalpeter (Nor.); CalciNit
 
calcium dinitrate; lime nitrate; nitrocalcite; lime saltpeter; Norwegian saltpeter (Norgessalpeter); air saltpeter; calciumnitrat (Dan.); Kalksalpeter (Nor.); CalciNit
  
[[[SliderGallery rightalign|Calcium nitrate.TIF~FTIR (MFA)]]]
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==Risks==       
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* Fire risk in contact with organic compounds. 
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* Integrachem: [http://www.integrachem.com/msds/C094_25358_101.pdf SDS]
  
== Other Properties ==
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==Physical and Chemical Properties==
  
 
Soluble in water, methanol, ethanol, acetone. pH = 6.0 (5% solution)
 
Soluble in water, methanol, ethanol, acetone. pH = 6.0 (5% solution)
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|-
 
|-
 
! scope="row"| Melting Point
 
! scope="row"| Melting Point
| 42-45 (hydrated)
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| 42-45 C (hydrated)
 
|-
 
|-
! scope="row"| Density
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! scope="row"| Density (g/ml)
 
| 1.82 (hydrated); 2.36 (dry)
 
| 1.82 (hydrated); 2.36 (dry)
 
|-
 
|-
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|}
 
|}
  
== Hazards and Safety ==
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==Resources and Citations==
 
 
Fire risk in contact with organic compounds. 
 
 
 
Mallinckrodt Baker: [http://www.jtbaker.com/msds/englishhtml/c0451.htm MSDS]
 
 
 
== Additional Information ==
 
 
 
° F.Piqué, L.Dei, E.Ferroni "Physicochemical Aspects of the Deliquescence of Calcium Nitrate and Its Implications for Wall Painting Conservation" ''Studies in Conservation'' 37:217-227, 1992.
 
  
== Sources Checked for Data in Record ==
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*  F.Piqué, L.Dei, E.Ferroni "Physicochemical Aspects of the Deliquescence of Calcium Nitrate and Its Implications for Wall Painting Conservation" ''Studies in Conservation'' 37:217-227, 1992.
  
 
* Richard S. Lewis, ''Hawley's Condensed Chemical Dictionary'', Van Nostrand Reinhold, New York, 10th ed., 1993
 
* Richard S. Lewis, ''Hawley's Condensed Chemical Dictionary'', Van Nostrand Reinhold, New York, 10th ed., 1993
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* ''The Merck Index'', Martha Windholz (ed.), Merck Research Labs, Rahway NJ, 10th edition, 1983  Comment: entry 1729
 
* ''The Merck Index'', Martha Windholz (ed.), Merck Research Labs, Rahway NJ, 10th edition, 1983  Comment: entry 1729
  
* Wikipedia, the free encyclopedia, at http://www.wikipedia.com  Comment: http://en.wikipedia.org/wiki/Calcium_nitrate (Accessed Jan. 15, 2006)
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* Wikipedia: http://en.wikipedia.org/wiki/Calcium_nitrate (Accessed Jan. 15, 2006)
  
 
* ''The American Heritage Dictionary'' or ''Encarta'', via Microsoft Bookshelf 98, Microsoft Corp., 1998
 
* ''The American Heritage Dictionary'' or ''Encarta'', via Microsoft Bookshelf 98, Microsoft Corp., 1998

Latest revision as of 14:16, 18 May 2022

Description

A white, deliquescent solid that is a strong oxidizing agent. Calcium nitrate was first produced commercially in Notodden, Norway in 1905. It is used in pyrotechnics, explosives, and match heads. Calcium nitrate has been identified as a deleterious accretion in wall paintings (Piqué et al 1992). The efflorescence also occurs when manure or other nitrogeneous compounds contact limestone in a dry environment.

FTIR (MFA)

Calcium nitrate.TIF

Synonyms and Related Terms

calcium dinitrate; lime nitrate; nitrocalcite; lime saltpeter; Norwegian saltpeter (Norgessalpeter); air saltpeter; calciumnitrat (Dan.); Kalksalpeter (Nor.); CalciNit

Risks

  • Fire risk in contact with organic compounds.
  • Integrachem: SDS

Physical and Chemical Properties

Soluble in water, methanol, ethanol, acetone. pH = 6.0 (5% solution)

Composition Ca(NO3)2 - 4H2O
CAS 10124-37-5 (Anhydrous) 13477-34-4 (Tetrahydrate)
Melting Point 42-45 C (hydrated)
Density (g/ml) 1.82 (hydrated); 2.36 (dry)
Molecular Weight mol. wt. = 236.15

Resources and Citations

  • F.Piqué, L.Dei, E.Ferroni "Physicochemical Aspects of the Deliquescence of Calcium Nitrate and Its Implications for Wall Painting Conservation" Studies in Conservation 37:217-227, 1992.
  • Richard S. Lewis, Hawley's Condensed Chemical Dictionary, Van Nostrand Reinhold, New York, 10th ed., 1993
  • Susan E. Schur, Conservation Terminology: A review of Past & Current Nomenclature of Materials, Technology and Conservation, Spring (p.34-39); Summer (p.35-38); Fall (p.25-36), 1985
  • The Merck Index, Martha Windholz (ed.), Merck Research Labs, Rahway NJ, 10th edition, 1983 Comment: entry 1729
  • The American Heritage Dictionary or Encarta, via Microsoft Bookshelf 98, Microsoft Corp., 1998