Atacamite

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Contents

Description

A green mineral composed of copper oxychloride. Atacamite was named by D. de Fallizen in 1801 when he identified it as a mineral found in the Chilean Atacama Desert. It occurs naturally in the oxidation zones of copper deposits and has been found in Chile, China, Russia, Czech Republic, Arizona, and Australia. It ranges in color from a soft muted green to emerald to blackish green. Atacamite also occurs as a chloride corrosion product on copper and bronze objects. Its presence indicates bronze disease. Using this corrosion reaction, Theophilus gave a recipe for the synthetic preparation of atacamite (Naumova and Pisareva, 1992). Atacamite has been found as a green pigment on sculpture, manuscripts, maps, and frescoes painted in Asia, Russia, Persia and Europe.

Synonyms and Related Terms

copper oxychloride; Atacamit (Deut.); atacamite (Fr., It., Port.); atacamita (Esp.); atakamitis (Gr.); atacamiet (Ned.); wild patina; Mehlpatina; flour patina; peste du bronze; bronze disease; malignant patina; rogna; caries;

Raman

AtacamitUCL.jpg

Raman

Atacamiteitaly1.jpg

FTIR

MFA- Atacamite.jpg


Other Properties

Crystallizes as thin orthorhombic prisms; Brittle with conchoidal fracture; Luster = adamantine to vitreous; Streak = green; Transparent to translucent.

Composition Cu2Cl(OH)3
Mohs Hardness 3.0 - 3.5
Density 3.76-3.78
Molecular Weight 213.57
Refractive Index 1.831; 1.861; 1.880

Additional Information

M.Naumova, S.Pisareva,"A Note on the Use of Blue and Green Copper Compounds in Paintings" Studies in Conservation 39:277-283, 1994.

Sources Checked for Data in Record

  • Nicholas Eastaugh, Valentine Walsh, Tracey Chaplin, Ruth Siddall, Pigment Compendium, Elsevier Butterworth-Heinemann, Oxford, 2004
  • Dictionary of Building Preservation, Ward Bucher, ed., John Wiley & Sons, Inc., New York City, 1996
  • Pam Hatchfield, Pollutants in the Museum Environment, Archetype Press, London, 2002
  • External source or communication Comment: H. Otto, "X-ray fine structure investigation of patina samples" Freiberger Forschungshefte.B, 37, 1959, pp. 66-77.
  • G.S.Brady, Materials Handbook, McGraw-Hill Book Co., New York, 1971 Comment: p. 233
  • Van Nostrand's Scientific Encyclopedia, Douglas M. Considine (ed.), Van Nostrand Reinhold, New York, 1976
  • Random House, Webster's Encyclopedic Unabridged Dictionary of the English Language, Grammercy Book, New York, 1997

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