Orpiment

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Orpiment crystals

Description

A soft, yellow mineral composed of arsenic trisulfide. Orpiment occurs naturally in volcanic fumaroles, hydrothermal veins, hot springs, and as a decomposition product of realgar. Deposits are found in the Czech Republic, Romania (Copalnic), Germany (Andreas-Berg ), Switzerland (Valais), Turkey (Çölemerik), Macedonia, Japan and the United States (Utah, Nevada, Wyoming). Orpiment ranges in color from a bright lemon yellow to orange. It changes to the red crystalline form at 170C. Orpiment was used in many early civilizations at various times, such as Egypt, Syria, Persia, India, and China. It was used as a pigment in European painting from quite early times, including in manuscript illumination and polychrome sculpture, and became almost a standard material on the palette in Venice in the 16th-century. Elsewhere it occurs in Dutch 17th-century painting, particularly flowerpieces, and British and French 18th-century paintings. Its use continued almost up until the present day, though it is no longer commonly used due to its toxicity. Orpiment has good tinting strength but is not considered permanent as it reacts with copper pigments as well as some lead pigments to produce dark copper or lead sulfides. It is a poor drier for oil paints and has a sulfurous odor. It can be rather light sensitive, losing its color on prolonged exposure to light, particularly in aqueous media. Arsenic trisulfide was made synthetically in the 18th-century and sold as king's yellow. The synthetic variety was purer and less expensive.

Orpiment, powdered

Synonyms and Related Terms

arsenic trisulfide; Pigment Yellow 39; CI 77085, 77086; orpiment (Eng., Fr., Gr., Ned.); Auripigment (Deut.); Rauschgelb (Deut.); Konigsgelb (Deut.); jaune royal (Fr.); oropimente (Esp.); orpimento (It.); ouropigmento (Port.); arsenous sulfide; king's yellow; arsenic yellow; auripigmentum; Chinese yellow; sunflower yellow

Raman

OrpimentUCL.jpg

XRD

PIG334.jpg

SEM

F334sem.jpg

EDS

F334edsbw.jpg

Chemical structure

Orpiment.jpg

XRF

Slide4 FC334.PNG


Other Properties

Decomposes slowly in water; soluble in acids and alkalis.

Unstable when mixed with alkaline pigments such as in buon fresco or in combinations with lime white. Both orpiment and realgar lose color on exposure to light. Orpiment oxidizes to form translucent or white oxides of arsenic.

Luster = pearly to resinous. Streak = lemon-yellow.

In PPL, orpiment has a strong yellow color and exhibits very high relief. Crystals are coarse-grained (up to 70 microns reported) with perfect cleavage (Eastaugh describes as 'bladed crystals', and 'splinters'), and often a distinct 'cross-hatching' pattern is visible on larger particles. Some particles are fibrous, acicular and/or elongated, and earthy aggregates are also reported. In XPL, particles exhibit high birefringence with pink and green interference colors. Extinction is straight and acicular particles are length-fast. Synthetic orpiment can be differentiated from the naturally occurring mineral form due to its smaller particle size (reported as fine to medium). The synthetic form is also reported to be contaminated with arsenic (III) oxide.

Composition As2S3
CAS 1303-33-9
Mohs Hardness 1.5 - 2.0
Melting Point 300
Density 3.43
Molecular Weight mol. wt. = 246.04
Refractive Index 2.40; 3.02; 2.81

Hazards and Safety

Turns black in contact with copper and lead containing pigments.

Toxic by inhalation and ingestion.

Fisher Scientific: MSDS

Additional Information

° E.West FitzHugh, "Orpiment and Realgar", Artists Pigments, Volume 3, E. West FitzHugh (ed.), Oxford University Press: Oxford, 1997.

° Mineralogy Database: Orpiment

° Carolin Rötter, ‘Auripigment’, Restauro, 6 2003, 408-413.

Additional Images


Sources Checked for Data in Record

  • Nicholas Eastaugh, Valentine Walsh, Tracey Chaplin, Ruth Siddall, Pigment Compendium, Elsevier Butterworth-Heinemann, Oxford, 2004
  • External source or communication Comment: Submitted information: Ashok Roy, November 2007
  • Submitted information: Helen Howard, November 2007
  • External source or communication Comment: Submitted information: Ashok Roy, Helen Howard, November 2007
  • Artists' Pigments: A Handbook of their History and Characteristics, Elisabeth West FitzHugh, Oxford University Press, Oxford, Vol. 3, 1997 Comment: E.West FitzHugh, "Orpiment and Realgar"
  • R. J. Gettens, G.L. Stout, Painting Materials, A Short Encyclopaedia, Dover Publications, New York, 1966
  • Ralph Mayer, A Dictionary of Art Terms and Techniques, Harper and Row Publishers, New York, 1969 (also 1945 printing)
  • R.D. Harley, Artists' Pigments c. 1600-1835, Butterworth Scientific, London, 1982
  • Dictionary of Building Preservation, Ward Bucher, ed., John Wiley & Sons, Inc., New York City, 1996
  • R.Feller, M.Curran, C.Bailie, 'Identification of Traditional Organic Colorants Employed in Japanese Prints and Determination of their Rates of Fading', Japanese Woodblock Prints, Allen Memorial Art Museum, Oberlin College, Oberlin, 1984 Comment: Jap. name kio and sekio and stone yellow
  • G.S.Brady, Materials Handbook, McGraw-Hill Book Co., New York, 1971 Comment: p. 69
  • Richard S. Lewis, Hawley's Condensed Chemical Dictionary, Van Nostrand Reinhold, New York, 10th ed., 1993
  • Encyclopedia Britannica, http://www.britannica.com Comment: "orpiment." Encyclopædia Britannica. 2005. Encyclopædia Britannica Premium Service 7 Apr. 2005 .
  • Book and Paper Group, Paper Conservation Catalog, AIC, 1984, 1989
  • Van Nostrand's Scientific Encyclopedia, Douglas M. Considine (ed.), Van Nostrand Reinhold, New York, 1976
  • Random House, Webster's Encyclopedic Unabridged Dictionary of the English Language, Grammercy Book, New York, 1997
  • The American Heritage Dictionary or Encarta, via Microsoft Bookshelf 98, Microsoft Corp., 1998
  • Thomas B. Brill, Light Its Interaction with Art and Antiquities, Plenum Press, New York City, 1980

Record content reviewed by EU-Artech, November 2007.