Realgar

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Realgar

Description

A bright orange-red mineral composed of arsenic disulfide. Realgar occurs naturally in the Czech Republic, Romania, Macedonia, Japan, and the United States (Utah, Nevada, Wyoming, California) in lead and silver ores along with orpiment (arsenic trisulfide). Realgar was once widely used as a pigment because of its bright rich color, but perhaps less so than its mineral congener, orpiment. Early occurrences are known for works of art from China, India, Central Asia, and Egypt. In European painting, apart from fairly regular use in Venice in the 16th-century, the pigment occurs occasionally until about the middle of the 18th-century. It is a usual choice for the bright orange flowers depicted in Dutch 17th-century paintings, and enjoyed moderately regular use in British 17th- century and 18th-century painting, including as a pastel color. However, it is extremely toxic, which has had an effect on its range of application and availability. Realgar is not particularly stable and can undergo a transformation to a polymorph, pararealgar, AsS; it can also deteriorate badly in oil paint films, resulting in rupturing, cracking and chalking, the pigment itself can fade under the action of light. Arsenic disulfide was made synthetically in the 18th century and sold as arsenic orange. The synthetic variety was purer and less expensive, but is no longer used because of its toxicity.

realgar

Synonyms and Related Terms

arsenic disulfide; Pigment Yellow 39; CI 77085; realgar (Eng., Esp., Gr., It., Ned., Port.); Realgar (Deut.); rejalgar (Esp.); réalgar (Fr.); yuo (Jap.); Schwefelarsenik (Deut.); Sandarack (Deut.); Rauschrot (Deut.); red arsenic sulfide; arsenic orange; red orpiment; burnt orpiment; ruby sulfur; risalgallo; oropimente quemado; jalde; roseaker

Raman

RealgarUCL.jpg

SEM

F212sem.jpg

EDS

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Other Properties

Isotropic crystals with good cleavage in one direction. Burns with blue flame. Darkens with heat. Changes to red crystalline form at 170C.

Soluble in alkaline sulfide solutions and nitric acid. Insoluble in water and hydrochloric acid.

Fracture = conchoidal. Luster = resinous to adamantine. Streak = orange-yellow

Pigment particles are pleochroic with high birefringence and straight extinction

Composition AsS or As4S4
Mohs Hardness 1.5 - 2.0
Melting Point 307-320
Density 3.56-3.59
Refractive Index 2.538, 2.684, 2.704
Boiling Point 565

Hazards and Safety

Turns black in contact with copper and lead containing pigments.

Toxic by inhalation and ingestion.

Additional Information

° E.West FitzHugh, "Orpiment and Realgar", Artists Pigments, Volume 3, E. West FitzHugh (ed.), Oxford University Press: Oxford, 1997.

° Mineralogy Database: RealgarRecord content reviewed by EU-Artech, November 2007.

Authority (list of all sources checked for information on this subject

  • Nicholas Eastaugh, Valentine Walsh, Tracey Chaplin, Ruth Siddall, Pigment Compendium, Elsevier Butterworth-Heinemann, Oxford, 2004
  • External source or communication Comment: Submitted information: Ashok Roy, November 2007
  • G.S.Brady, Materials Handbook, McGraw-Hill Book Co., New York, 1971 Comment: p. 69
  • Encyclopedia Britannica, http://www.britannica.com Comment: "Realgar." Encyclopædia Britannica. 2004. Encyclopædia Britannica Premium Service. 12 May 2004 .
  • Artists' Pigments: A Handbook of their History and Characteristics, Elisabeth West FitzHugh, Oxford University Press, Oxford, Vol. 3, 1997 Comment: E.West FitzHugh, "Orpiment and Realgar"
  • R. J. Gettens, G.L. Stout, Painting Materials, A Short Encyclopaedia, Dover Publications, New York, 1966 Comment: density = 3.56 and ref. index = 2.46; 2.61; 2.59
  • Ralph Mayer, A Dictionary of Art Terms and Techniques, Harper and Row Publishers, New York, 1969 (also 1945 printing)
  • C.W.Chesterman, K.E.Lowe, Audubon Society Field Guide to North American Rocks and Minerals, Alfred A. Knopf, New York, 1979
  • Thomas B. Brill, Light Its Interaction with Art and Antiquities, Plenum Press, New York City, 1980
  • Susan E. Schur, Conservation Terminology: A review of Past & Current Nomenclature of Materials, Technology and Conservation, Spring (p.34-39); Summer (p.35-38); Fall (p.25-36), 1985