Difference between revisions of "Manganese dioxide"

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== Description ==
 
== Description ==
  
A dense, black powder that occurs in nature as the mineral [http://cameo.mfa.org/materials/fullrecord.asp?name=pyrolusite pyrolusite]. Manganese dioxide ore is the primary source for manganese metal. Synthetically produced manganese dioxide has a brownish tone. Both natural and synthetic manganese dioxide have been used for paint pigments and as a colorant in mortar. Manganese dioxide is used to make amethyst glass and to counteract the yellowish green color of iron oxide in glass. It is used as a black glaze and for painting on porcelain, faience, and majolica, and as a [http://cameo.mfa.org/materials/fullrecord.asp?name=drier drier] for oil paints.
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A dense, black powder that occurs in nature as the mineral [[pyrolusite|pyrolusite]]. Manganese dioxide ore is the primary source for manganese metal. Synthetically produced manganese dioxide has a brownish tone. Both natural and synthetic manganese dioxide have been used for paint pigments and as a colorant in mortar. Manganese dioxide is used to make amethyst glass and to counteract the yellowish green color of iron oxide in glass. It is used as a black glaze and for painting on porcelain, faience, and majolica, and as a [[drier|drier]] for oil paints.
  
 
== Synonyms and Related Terms ==
 
== Synonyms and Related Terms ==
  
manganese black; manganese brown; Pigment Black 14; CI  77728; dixido de manganeso (Esp.); dioxyde de manganse (Fr.); dixido de mangans (Port.); black oxide of manganese; manganese binoxide; battery manganese
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manganese black; manganese brown; Pigment Black 14; CI  77728; dióxido de manganeso (Esp.); dioxyde de manganèse (Fr.); dióxido de manganês (Port.); black oxide of manganese; manganese binoxide; battery manganese
  
[[[SliderGallery rightalign|manganese dioxide.jpg~Chemical structure]]]
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== Risks ==
  
== Other Properties ==
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* Toxic.
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* Inhalation or ingestion of manganese can cause a nervous system disorder.
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* Strong oxidizer and should not be heated or rubbed with organic matter. 
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* ThermoFisher: [https://www.fishersci.com/store/msds?partNumber=M108500&productDescription=MANGANESE+DIOXIDE+CERTIF+500G&vendorId=VN00033897&countryCode=US&language=en SDS]
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==Physical and Chemical Properties==
  
 
Slowly dissolves in hydrochloric acid. Insoluble in water, nitric and sulfuric acid
 
Slowly dissolves in hydrochloric acid. Insoluble in water, nitric and sulfuric acid
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! scope="row"| Density
 
! scope="row"| Density
| 3.125
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| 3.125 g/ml
 
|-
 
|-
 
! scope="row"| Molecular Weight
 
! scope="row"| Molecular Weight
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== Hazards and Safety ==
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==Resources and Citations==
  
Toxic. Inhalation or ingestion of manganese can cause a nervous system disorder. Strong oxidizer and should not be heated or rubbed with organic matter. 
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* Richard S. Lewis, ''Hawley's Condensed Chemical Dictionary'', Van Nostrand Reinhold, New York, 10th ed., 1993
 
 
Mallinckrodt Baker: [http://www.jtbaker.com/msds/englishhtml/m0715.htm MSDS]
 
 
 
== Authority ==
 
 
 
* Richard S. Lewis, Richard S. Lewis, ''Hawley's Condensed Chemical Dictionary'', Van Nostrand Reinhold, New York, 10th ed., 1993
 
  
 
* ''The Merck Index'', Martha Windholz (ed.), Merck Research Labs, Rahway NJ, 10th edition, 1983  Comment: entry 5770
 
* ''The Merck Index'', Martha Windholz (ed.), Merck Research Labs, Rahway NJ, 10th edition, 1983  Comment: entry 5770
  
* Michael McCann, Michael McCann, ''Artist Beware'', Watson-Guptill Publications, New York City, 1979
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* Michael McCann, ''Artist Beware'', Watson-Guptill Publications, New York City, 1979
  
 
* ''Dictionary of Building Preservation'', Ward Bucher, ed., John Wiley & Sons, Inc., New York City, 1996
 
* ''Dictionary of Building Preservation'', Ward Bucher, ed., John Wiley & Sons, Inc., New York City, 1996
  
* Susan E. Schur, Susan E. Schur, Conservation Terminology: A review of Past & Current Nomenclature of Materials, ''Technology and Conservation'', Spring (p.34-39); Summer (p.35-38); Fall (p.25-36), 1985
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* Susan E. Schur, Conservation Terminology: A review of Past & Current Nomenclature of Materials, ''Technology and Conservation'', Spring (p.34-39); Summer (p.35-38); Fall (p.25-36), 1985
  
* Pam Hatchfield, Pam Hatchfield, ''Pollutants in the Museum Environment'', Archetype Press, London, 2002
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* Pam Hatchfield, ''Pollutants in the Museum Environment'', Archetype Press, London, 2002
  
  
  
 
[[Category:Materials database]]
 
[[Category:Materials database]]

Latest revision as of 13:12, 1 October 2022

Description

A dense, black powder that occurs in nature as the mineral Pyrolusite. Manganese dioxide ore is the primary source for manganese metal. Synthetically produced manganese dioxide has a brownish tone. Both natural and synthetic manganese dioxide have been used for paint pigments and as a colorant in mortar. Manganese dioxide is used to make amethyst glass and to counteract the yellowish green color of iron oxide in glass. It is used as a black glaze and for painting on porcelain, faience, and majolica, and as a Drier for oil paints.

Synonyms and Related Terms

manganese black; manganese brown; Pigment Black 14; CI 77728; dióxido de manganeso (Esp.); dioxyde de manganèse (Fr.); dióxido de manganês (Port.); black oxide of manganese; manganese binoxide; battery manganese

Risks

  • Toxic.
  • Inhalation or ingestion of manganese can cause a nervous system disorder.
  • Strong oxidizer and should not be heated or rubbed with organic matter.
  • ThermoFisher: SDS

Physical and Chemical Properties

Slowly dissolves in hydrochloric acid. Insoluble in water, nitric and sulfuric acid

Composition MnO2
CAS 1313-13-9
Density 3.125 g/ml
Molecular Weight mol. wt. = 86.94

Resources and Citations

  • Richard S. Lewis, Hawley's Condensed Chemical Dictionary, Van Nostrand Reinhold, New York, 10th ed., 1993
  • The Merck Index, Martha Windholz (ed.), Merck Research Labs, Rahway NJ, 10th edition, 1983 Comment: entry 5770
  • Michael McCann, Artist Beware, Watson-Guptill Publications, New York City, 1979
  • Dictionary of Building Preservation, Ward Bucher, ed., John Wiley & Sons, Inc., New York City, 1996
  • Susan E. Schur, Conservation Terminology: A review of Past & Current Nomenclature of Materials, Technology and Conservation, Spring (p.34-39); Summer (p.35-38); Fall (p.25-36), 1985
  • Pam Hatchfield, Pollutants in the Museum Environment, Archetype Press, London, 2002