Saran film

Polyvinylidene chloride film

Description

[SC Johnson] Originally a Dow Chemical tradename for thermoplastic film copolymer of vinylidene chloride and small amounts of vinyl chloride or acrylonitrile. Polyvinylidene, or PVDC, was discovered by accident in 1933, by Ralph Wiley a college student working at Dow. The name Saran was trademarked by Dow Chemical in 1940, but has now become a commonly used name for thin plastic films used primarily to cover food. The PVDC films have a very low water permeability, is very inert and can withstand high temperatures. It has good chemical resistance to acids and alkalis and does not lose strength in sunlight. Saran plastic is used for fibers, packaging films and acid-resistant pipes.

In 1998, the SC Johnson bought Saran Wrap from Dow. In 2004, due to environmental conserns, SCJ decided to remove chorine from all of their products. As a result, 'Saran wrap' was reformulated as a linear low density Polyethylene (LLDPE) film that is modified to contain some Polybutylene as a cling agent. The polybutylene also allows the polyethylene to withstand higher temperatures, such as those produced by steam in a microwave. The reformulated product does not perform as well as PVDC, and the company lost significant sales due to the change, but the SJC CEO siad it was the right thing to do (Link).

FTIR of PVDC

Synonyms and Related Terms

Saran wrap; plastic wrap

Alternate names for LLDPE product: Saran Premium Wrap, Glad Cling Wrap, Handi-Wrap

Applications

• PVDC was an efficient gas barrier and aa excellent barrier film against water vapor
• LLDPE has a limited lifetime, especially when stretched, and provides low gas barrier protection (Tetreault 2017)

Personal Risks

Nonflammable.

Physical and Chemical Properties

Resistant to acids, alkalis. May be damaged by ketone, carbon tetrachloride, ethanol, perchloroethylene. Resistant to insects and bacteria.

For 1 mil film:

• Oxygen transmission = 12-16 ml/m2d
• Water vapor transmission = 3.8 g/m2d
• Melting Point = 160--177 C
• Density = 1.17

Resources and Citations

• SC Johnson: Website
• The History of Saran Wrap: Website
• Jean Tetreault Products Used in Preventive Conservation CCI, December 2017. Link
• G.S.Brady, Materials Handbook, McGraw-Hill Book Co., New York, 1971 Comment: p. 850
• Rosalie Rosso King, Textile Identification, Conservation, and Preservation, Noyes Publications, Park Ridge, NJ, 1985
• Pam Hatchfield, Pollutants in the Museum Environment, Archetype Press, London, 2002
• Wikipedia: http://en.wikipedia.org/wiki/Saran_%28plastic%29 (Accessed Sept. 14, 2005)