Difference between revisions of "Malachite Green"
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== Description == | == Description == | ||
| − | A synthetic organic dye that was named for the mineral because of its color hue. Malachite Green is an aniline based dyestuff (a triphenylmethane salt) made by Dobner and Fisher in 1877. Both the chloride and the oxalate salt are known by the same name. In a neutral aqueous solution, its green crystals give an absorption maximum at 616.9 nm. Malachite Green is used for the direct dying of [ | + | A synthetic organic dye that was named for the mineral because of its color hue. Malachite Green is an aniline based dyestuff (a triphenylmethane salt) made by Dobner and Fisher in 1877. Both the chloride and the oxalate salt are known by the same name. In a neutral aqueous solution, its green crystals give an absorption maximum at 616.9 nm. Malachite Green is used for the direct dying of [[silk|silk]], [[wool|wool]], [[jute|jute]], and [[leather|leather]]. It is also used to dye [[cotton|cotton]] after mordanting. Malachite Green can be used in spot chemical tests for the detection of sulfurous acid and [[cerium|cerium]]. It is used as an acid-base indicator with the following color ranges: yellow at pH 0, green at pH 2.0, cyan at pH 11.6, and colorless at pH 14. Malachite Green is also used to kill parasites, mold, and [[fungus|fungi]] in fish tanks. |
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[[[SliderGallery rightalign| Slide17 F386.PNG~XRF|Malachite.Green_abs.jpg~Absorption spectrum]]] | [[[SliderGallery rightalign| Slide17 F386.PNG~XRF|Malachite.Green_abs.jpg~Absorption spectrum]]] | ||
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malachite green chloride; Basic Green 4; CI 42000; viktoriavihreä (Fin.); Viktoriagrün (Deut.); Braunschweigergrün (Deut.); vert malachite (Fr.); viktoriagrönt (Sven.); verde malaquite (Port.); benzaldehyde green; | malachite green chloride; Basic Green 4; CI 42000; viktoriavihreä (Fin.); Viktoriagrün (Deut.); Braunschweigergrün (Deut.); vert malachite (Fr.); viktoriagrönt (Sven.); verde malaquite (Port.); benzaldehyde green; | ||
| − | + | Commercial names: Victoria Green B; China Green; Diamond Green B; Light Green N; Benzal Green; Fast Green | |
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| + | == Risks == | ||
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| + | * Toxic by ingestion. | ||
| + | * Contact may cause irritation. | ||
| + | * Fisher Scientific: [https://fscimage.fishersci.com/msds/13533.htm MSDS] | ||
| − | == | + | == Physical and Chemical Properties == |
Soluble in water and ethanol, methanol and amyl alcohol. | Soluble in water and ethanol, methanol and amyl alcohol. | ||
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| − | == | + | ==Resources and Citations== |
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* Richard S. Lewis, ''Hawley's Condensed Chemical Dictionary'', Van Nostrand Reinhold, New York, 10th ed., 1993 | * Richard S. Lewis, ''Hawley's Condensed Chemical Dictionary'', Van Nostrand Reinhold, New York, 10th ed., 1993 | ||
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* ''The Merck Index'', Martha Windholz (ed.), Merck Research Labs, Rahway NJ, 10th edition, 1983 Comment: entry 5739 | * ''The Merck Index'', Martha Windholz (ed.), Merck Research Labs, Rahway NJ, 10th edition, 1983 Comment: entry 5739 | ||
| − | * ''Encyclopedia Britannica'', http://www.britannica.com Comment: "malachite green." | + | * ''Encyclopedia Britannica'', http://www.britannica.com Comment: "malachite green." Accessed 7 Apr. 2005. |
| − | * Website | + | * Website: www.straw.com/sig/dyehist |
| − | * Website | + | * Website: http://www.coloria.net/varita.htm - foreign language equivalent terms |
* ''The Dictionary of Art'', Grove's Dictionaries Inc., New York, 1996 | * ''The Dictionary of Art'', Grove's Dictionaries Inc., New York, 1996 | ||
Latest revision as of 08:30, 17 October 2022
Description
A synthetic organic dye that was named for the mineral because of its color hue. Malachite Green is an aniline based dyestuff (a triphenylmethane salt) made by Dobner and Fisher in 1877. Both the chloride and the oxalate salt are known by the same name. In a neutral aqueous solution, its green crystals give an absorption maximum at 616.9 nm. Malachite Green is used for the direct dying of Silk, Wool, Jute, and Leather. It is also used to dye Cotton after mordanting. Malachite Green can be used in spot chemical tests for the detection of sulfurous acid and Cerium. It is used as an acid-base indicator with the following color ranges: yellow at pH 0, green at pH 2.0, cyan at pH 11.6, and colorless at pH 14. Malachite Green is also used to kill parasites, mold, and fungi in fish tanks.
Synonyms and Related Terms
malachite green chloride; Basic Green 4; CI 42000; viktoriavihreä (Fin.); Viktoriagrün (Deut.); Braunschweigergrün (Deut.); vert malachite (Fr.); viktoriagrönt (Sven.); verde malaquite (Port.); benzaldehyde green;
Commercial names: Victoria Green B; China Green; Diamond Green B; Light Green N; Benzal Green; Fast Green
Risks
- Toxic by ingestion.
- Contact may cause irritation.
- Fisher Scientific: MSDS
Physical and Chemical Properties
Soluble in water and ethanol, methanol and amyl alcohol.
| Composition | C23H25ClN2 |
|---|---|
| CAS | 569-64-2 |
| Molecular Weight | mol. wt. = 364.92 |
Resources and Citations
- Richard S. Lewis, Hawley's Condensed Chemical Dictionary, Van Nostrand Reinhold, New York, 10th ed., 1993
- The Merck Index, Martha Windholz (ed.), Merck Research Labs, Rahway NJ, 10th edition, 1983 Comment: entry 5739
- Encyclopedia Britannica, http://www.britannica.com Comment: "malachite green." Accessed 7 Apr. 2005.
- Website: www.straw.com/sig/dyehist
- Website: http://www.coloria.net/varita.htm - foreign language equivalent terms
- The Dictionary of Art, Grove's Dictionaries Inc., New York, 1996
- Colour Index International online at www.colour-index.org